Magnesium oxide

Magnesium oxide (MgO), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions held together by ionic bonding. Magnesium hydroxide forms in the presence of water (MgO + H2O → Mg(OH)2), but it can be reversed by heating it to separate moisture.

Magnesium oxide
Names
Other names
Magnesia
Periclase
Identifiers
ChEMBL
ECHA InfoCard 100.013.793
EC Number
  • 215-171-9
E number E530 (acidity regulators, ...)
RTECS number
  • OM3850000
UNII
Properties
MgO
Molar mass 40.304 g/mol[1]
Appearance White powder
Odor Odorless
Density 3.6 g/cm3[1]
Melting point 2,852 °C (5,166 °F; 3,125 K)[1]
Boiling point 3,600 °C (6,510 °F; 3,870 K)[1]
Solubility Soluble in acid, ammonia
insoluble in alcohol
Band gap 7.8 eV[2]
−10.2·10−6 cm3/mol[3]
Thermal conductivity 45–60 W·m−1·K−1[4]
1.7355
6.2 ± 0.6 D
Structure
Halite (cubic), cF8
Fm3m, No. 225
a = 4.212Å
Octahedral (Mg2+); octahedral (O2−)
Thermochemistry
37.2 J/mol K[5]
26.95 ± 0.15 J·mol−1·K−1[6]
Std enthalpy of
formation (ΔfH⦵298)
 −601.6 ± 0.3 kJ·mol−1[6]
-569.3 kJ/mol[5]
Pharmacology
A02AA02 (WHO) A06AD02 (WHO), A12CC10 (WHO)
Hazards
Main hazards Metal fume fever, Irritant
Safety data sheet ICSC 0504
R-phrases (outdated) R36, R37, R38
NFPA 704 (fire diamond)
Flammability code 0: Will not burn. E.g. waterHealth code 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineReactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
0
1
0
Flash point Non-flammable
NIOSH (US health exposure limits):
PEL (Permissible)
 TWA 15 mg/m3 (fume)[7]
REL (Recommended)
 None designated[7]
IDLH (Immediate danger)
 750 mg/m3 (fume)[7]
Related compounds
Other anions
 Magnesium sulfide
Other cations
 Beryllium oxide
Calcium oxide
Strontium oxide
Barium oxide
Related compounds
 Magnesium hydroxide
Magnesium nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Magnesium oxide was historically known as magnesia alba (literally, the white mineral from Magnesia – other sources give magnesia alba as MgCO3), to differentiate it from magnesia negra, a black mineral containing what is now known as manganese.

While "magnesium oxide" normally refers to MgO, magnesium peroxide MgO2 is also known as a compound. According to evolutionary crystal structure prediction,[8] MgO2 is thermodynamically stable at pressures above 116 GPa (gigapascals), and a semiconducting suboxide Mg3O2 is thermodynamically stable above 500 GPa. Because of its stability, MgO is used as a model system for investigating vibrational properties of crystals.[9]

Production

Magnesium oxide is produced by the calcination of magnesium carbonate or magnesium hydroxide. The latter is obtained by the treatment of magnesium chloride solutions, typically seawater, with lime.[10]

Mg2+ + Ca(OH)2 → Mg(OH)2 + Ca2+

Calcining at different temperatures produces magnesium oxide of different reactivity. High temperatures 1500 – 2000 °C diminish the available surface area and produces dead-burned (often called dead burnt) magnesia, an unreactive form used as a refractory. Calcining temperatures 1000 – 1500 °C produce hard-burned magnesia, which has limited reactivity and calcining at lower temperature, (700–1000 °C) produces light-burned magnesia, a reactive form, also known as caustic calcined magnesia. Although some decomposition of the carbonate to oxide occurs at temperatures below 700 °C, the resulting materials appears to reabsorb carbon dioxide from the air.[11]

Applications

MgO is prized as a refractory material, i.e. a solid that is physically and chemically stable at high temperatures. It has two useful attributes: high thermal conductivity and low electrical conductivity. Filling the spiral Calrod range top heating elements on kitchen electric stoves is a major use. "By far the largest consumer of magnesia worldwide is the refractory industry, which consumed about 56 % of the magnesia in the United States in 2004, the remaining 44 % being used in agricultural, chemical, construction, environmental, and other industrial applications."[12] MgO is used as a basic refractory material for crucibles.

It is a principal fireproofing ingredient in construction materials. As a construction material, magnesium oxide wallboards have several attractive characteristics: fire resistance, termite resistance, moisture resistance, mold and mildew resistance, and strength.[13]

Niche uses

MgO is one of the components in Portland cement in dry process plants.

Magnesium oxide is used extensively in the soil and groundwater remediation, wastewater treatment, drinking water treatment, air emissions treatment, and waste treatment industries for its acid buffering capacity and related effectiveness in stabilizing dissolved heavy metal species.

Many heavy metals species, such as lead and cadmium are most soluble in water at acidic pH (below 6) as well as high pH (above 11). Solubility of metals affects bioavailability of the species and mobility soil and groundwater systems. Most metal species are toxic to humans at certain concentrations, therefore it is imperative to minimize metal bioavailability and mobility.

Granular MgO is often blended into metals-contaminated soil or waste material, which is also commonly of a low (acidic) pH, in order to drive the pH into the 8–10 range where most metals are at their lowest solubilities. Metal-hydroxide complexes have a tendency to precipitate out of aqueous solution in the pH range of 8–10. MgO is widely regarded as the most effective metals stabilization compound when compared to Portland cement, lime, kiln dust products, power generation waste products, and various proprietary products due to MgO's superior buffering capacity, cost effectiveness, and ease/safety of handling.

Most, if not all products that are marketed as metals stabilization technologies create very high pH conditions in aquifers whereas MgO creates an ideal aquifer condition with a pH of 8–10. Additionally, magnesium, an essential element to most biological systems, is provided to soil and groundwater microbial populations during MgO-assisted metals remediation as an added benefit.

Medical

Magnesium oxide is used for relief of heartburn and dyspepsia, as an antacid, magnesium supplement, and as a short-term laxative. It is also used to improve symptoms of indigestion. Side effects of magnesium oxide may include nausea and cramping.[14] In quantities sufficient to obtain a laxative effect, side effects of long-term use include enteroliths resulting in bowel obstruction.[15]

Other
Unpolished MgO crystal
  • Pressed MgO is used as an optical material. It is transparent from 0.3 to 7 µm. The refractive index is 1.72 at 1 µm and the Abbe number is 53.58. It is sometimes known by the Eastman Kodak trademarked name Irtran-5, although this designation is obsolete. Crystalline pure MgO is available commercially and has a small use in infrared optics.[20]
  • MgO is packed around transuranic waste at the Waste Isolation Pilot Plant, to control the solubility of radionuclides.[21]
  • MgO has an important place as a commercial plant fertilizer [22] and as animal feed.[23]
  • An aerosolized solution of MgO is used in library science and collections management for the deacidification of at-risk paper items. In this process, the alkalinity of MgO (and similar compounds) neutralizes the relatively high acidity characteristic of low-quality paper, thus slowing the rate of deterioration.[24]
  • MgO is also used as a protective coating in plasma displays.
  • Magnesium oxide is used as an oxide barrier in spin-tunneling devices. Owing to the crystalline structure of its thin films, which can be deposited by magnetron sputtering, for example, it shows characteristics superior to those of the commonly used amorphous Al2O3. In particular, spin polarization of about 85% has been achieved with MgO[25] versus 40–60 % with aluminium oxide.[26] The value of tunnel magnetoresistance is also significantly higher for MgO (600% at room temperature and 1,100 % at 4.2 K[27]) than Al2O3 (ca. 70% at room temperature[28]). MgO is thermally stable up to about 700 K, vs. 600 K for Al2O3.

Precautions

Inhalation of magnesium oxide fumes can cause metal fume fever.[29]

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See also

References
  1. Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.74. ISBN 1439855110.
  2. Taurian, O.E.; Springborg, M.; Christensen, N.E. (1985). "Self-consistent electronic structures of MgO and SrO" (PDF). Solid State Communications. 55 (4): 351–5. Bibcode:1985SSCom..55..351T. doi:10.1016/0038-1098(85)90622-2.
  3. Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.133. ISBN 1439855110.
  4. Application of magnesium compounds to insulating heat-conductive fillers Archived 2013-12-30 at the Wayback Machine. konoshima.co.jp
  5. Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 5.15. ISBN 1439855110.
  6. Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 5.2. ISBN 1439855110.
  7. NIOSH Pocket Guide to Chemical Hazards. "#0374". National Institute for Occupational Safety and Health (NIOSH).
  8. Zhu, Qiang; Oganov A.R.; Lyakhov A.O. (2013). "Novel stable compounds in the Mg-O system under high pressure" (PDF). Phys. Chem. Chem. Phys. 15 (20): 7696–7700. Bibcode:2013PCCP...15.7696Z. doi:10.1039/c3cp50678a. PMID 23595296.
  9. Mei, AB; O. Hellman; C. M. Schlepütz; A. Rockett; T.-C. Chiang; L. Hultman; I. Petrov; J. E. Greene (2015). "Reflection Thermal Diffuse X-Ray Scattering for Quantitative Determination of Phonon Dispersion Relations". Physical Review B. 92 (17): 174301. Bibcode:2015PhRvB..92q4301M. doi:10.1103/physrevb.92.174301.
  10. Margarete Seeger; Walter Otto; Wilhelm Flick; Friedrich Bickelhaupt; Otto S. Akkerman. "Magnesium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a15_595.pub2.
  11. Ropp, R C (2013-03-06). Encyclopedia of the alkaline earth compounds. Elsevier. p. 109. ISBN 9780444595508.
  12. Mark A. Shand (2006). The chemistry and technology of magnesia. John Wiley and Sons. ISBN 978-0-471-65603-6. Retrieved 10 September 2011.
  13. Mármol, Gonzalo; Savastano, Holmer (July 2017). "Study of the degradation of non-conventional MgO-SiO 2 cement reinforced with lignocellulosic fibers". Cement and Concrete Composites. 80: 258–267. doi:10.1016/j.cemconcomp.2017.03.015.
  14. Magnesium Oxide. MedlinePlus. Last reviewed 02/01/2009
  15. Tatekawa Y, Nakatani K, Ishii H, et al. (1996). "Small bowel obstruction caused by a medication bezoar: report of a case". Surgery Today. 26 (1): 68–70. doi:10.1007/BF00311997. PMID 8680127.
  16. "Compound Summary for CID 14792 – Magnesium Oxide". PubChem.
  17. Tellex, Peter A.; Waldron, Jack R. (1955). "Reflectance of Magnesium Oxide". JOSA. 45 (1): 19. doi:10.1364/JOSA.45.000019.
  18. Dymicky, M. (1989-02-01). "Preparation of Carbobenzoxy-L-Tyrosine Methyl and Ethyl Esters and of the Corresponding Carbobenzoxy Hydrazides". Organic Preparations and Procedures International. 21 (1): 83–90. doi:10.1080/00304948909356350. ISSN 0030-4948.
  19. Tan, C.Y.; Yaghoubi, A.; Ramesh, S.; Adzila, S.; Purbolaksono, J.; Hassan, M.A.; Kutty, M.G. (December 2013). "Sintering and mechanical properties of MgO-doped nanocrystalline hydroxyapatite" (PDF). Ceramics International. 39 (8): 8979–8983. doi:10.1016/j.ceramint.2013.04.098.
  20. Stephens, Robert E. & Malitson, Irving H. (1952). "Index of Refraction of Magnesium Oxide" (PDF). Journal of Research of the National Bureau of Standards. 49 (4): 249–252. doi:10.6028/jres.049.025.
  21. wipp.energy.gov Step-By-Step Guide for Waste Handling at WIPP. Waste Isolation Pilot Plant. wipp.energy.gov
  22. Nutrient Science. fertilizer101.org. Retrieved on 2017-04-26.
  23. Magnesium oxide for the Animal Feed Industry. lehvoss.de
  24. "Mass Deacidification: Saving the Written Word". Library of Congress. Retrieved 26 September 2011.
  25. Parkin, S. S. P.; Kaiser, C.; Panchula, A.; Rice, P. M.; Hughes, B.; Samant, M.; Yang, S. H. (2004). "Giant tunnelling magnetoresistance at room temperature with MgO (100) tunnel barriers". Nature Materials. 3 (12): 862–867. Bibcode:2004NatMa...3..862P. doi:10.1038/nmat1256. PMID 15516928.
  26. Monsma, D. J.; Parkin, S. S. P. (2000). "Spin polarization of tunneling current from ferromagnet/Al2O3 interfaces using copper-doped aluminum superconducting films". Applied Physics Letters. 77 (5): 720. Bibcode:2000ApPhL..77..720M. doi:10.1063/1.127097.
  27. Ikeda, S.; Hayakawa, J.; Ashizawa, Y.; Lee, Y. M.; Miura, K.; Hasegawa, H.; Tsunoda, M.; Matsukura, F.; Ohno, H. (2008). "Tunnel magnetoresistance of 604% at 300 K by suppression of Ta diffusion in CoFeB∕MgO∕CoFeB pseudo-spin-valves annealed at high temperature". Applied Physics Letters. 93 (8): 082508. Bibcode:2008ApPhL..93h2508I. doi:10.1063/1.2976435.
  28. Wang, D.; Nordman, C.; Daughton, J. M.; Qian, Z.; Fink, J.; Wang, D.; Nordman, C.; Daughton, J. M.; Qian, Z.; Fink, J. (2004). "70% TMR at Room Temperature for SDT Sandwich Junctions with CoFeB as Free and Reference Layers". IEEE Transactions on Magnetics. 40 (4): 2269. Bibcode:2004ITM....40.2269W. CiteSeerX 10.1.1.476.8544. doi:10.1109/TMAG.2004.830219.
  29. Magnesium Oxide. National Pollutant Inventory, Government of Australia.
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