Polycarbonate

Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code (RIC) and are identified as "Other", 7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A (BPA).

Polycarbonate
Repeating chemical structure unit of Polycarbonate made from bisphenol A Transmission spectrum of polycarbonate
Physical properties
Density (ρ)	1.20–1.22 g/cm^3
Abbe number (V)	34.0
Refractive index (n)	1.584–1.586
Flammability	V0-V2
Limiting oxygen index	25–27%
Water absorption—Equilibrium (ASTM)	0.16–0.35%
Water absorption—over 24 hours	0.1%
Radiation resistance	Fair
Ultraviolet (1–380 nm) resistance	Fair
Mechanical properties
Young's modulus (E)	2.0–2.4 GPa
Tensile strength (σt)	55–75 MPa
Elongation (ε) at break	80–150%
Compressive strength (σc)	>80 MPa
Poisson's ratio (ν)	0.37
Hardness—Rockwell	M70
Izod impact strength	600–850 J/m
Notch test	20–35 kJ/m^2
Abrasive resistance ASTM D1044	10–15 mg/1000 cycles
Coefficient of friction (μ)	0.31
Speed of sound	2270 m/s
Thermal properties
Glass transition temperature (Tg)	147 °C (297 °F)
Heat deflection temperature	0.45 MPa: 140 °C (284 °F) 1.8 MPa: 128–138 °C (262–280 °F)
Vicat softening point at 50 N	145–150 °C (293–302 °F)[1]
Upper working temperature	115–130 °C (239–266 °F)
Lower working temperature	−40 °C (−40 °F)[2]
Thermal conductivity (k) at 23 °C	0.19–0.22 W/(m·K)
Thermal diffusivity (a) at 25 °C	0.144 mm²/s[3]
Linear thermal expansion coefficient (α)	65–70 × 10^−6/K
Specific heat capacity (c)	1.2–1.3 kJ/(kg·K)
Electrical properties
Dielectric constant (εr) at 1 MHz	2.9
Permittivity (ε)	2.568 × 10^−11 F/m
Relative permeability (μr) at 1 MHz	0.866(2)
Permeability (μ) at 1 MHz	1.089(2) μN/A^2
Dissipation factor at 1 MHz	0.01
Surface resistivity	10^15 Ω/sq
Volume resistivity (ρ)	10^12–10^14 Ω·m
Chemical resistance
Acids—concentrated	Poor
Acids—dilute	Good
Alcohols	Good
Alkalis	Good-Poor
Aromatic hydrocarbons	Poor
Greases and oils	Good-fair
Halogenated hydrocarbons	Good-poor
Halogens	Poor
Ketones	Poor
Gas permeation at 20 °C
Nitrogen	10–25 cm^3·mm/(m^2·day·Bar)
Oxygen	70–130 cm^3·mm/(m^2·day·Bar)
Carbon dioxide	400–800 cm^3·mm/(m^2·day·Bar)
Water vapour	1–2 g·mm/(m^2·day) @ 85%–0% RH gradient
Economics
Price	2.6–2.8 €/kg[4]

Structure

Structure of dicarbonate (PhOC(O)OC₆H₄ )₂CMe₂ derived from bis(phenol-A) and two equivalents of phenol.[5] This molecule reflects a subunit of a typical polycarbonate derived from bis(phenol-A).

Carbonate esters have planar OC(OC)₂ cores, which confers rigidity. The unique O=C bond is short (1.173 Å in the depicted example), while the C-O bonds are more ether-like (the bond distances of 1.326 Å for the example depicted). Polycarbonates received their name because they are polymers containing carbonate groups (−O−(C=O)−O−). A balance of useful features, including temperature resistance, impact resistance and optical properties, positions polycarbonates between commodity plastics and engineering plastics.

Production

The main polycarbonate material is produced by the reaction of bisphenol A (BPA) and phosgene COCl
₂. The overall reaction can be written as follows:

The first step of the synthesis involves treatment of bisphenol A with sodium hydroxide, which deprotonates the hydroxyl groups of the bisphenol A.[6]

(HOC₆H₄)₂CMe₂ + 2 NaOH → Na₂(OC₆H₄)₂CMe₂ + 2 H₂O

The diphenoxide (Na₂(OC₆H₄)₂CMe₂) reacts with phosgene to give a chloroformate, which subsequently is attacked by another phenoxide. The net reaction from the diphenoxide is:

Na₂(OC₆H₄)₂CMe₂ + COCl₂ → 1/n [OC(OC₆H₄)₂CMe₂]_n + 2 NaCl

In this way, approximately one billion kilograms of polycarbonate is produced annually. Many other diols have been tested in place of bisphenol A, e.g. 1,1-bis(4-hydroxyphenyl)cyclohexane and dihydroxybenzophenone. The cyclohexane is used as a comonomer to suppress crystallisation tendency of the BPA-derived product. Tetrabromobisphenol A is used to enhance fire resistance. Tetramethylcyclobutanediol has been developed as a replacement for BPA.[6]

An alternative route to polycarbonates entails transesterification from BPA and diphenyl carbonate:

(HOC₆H₄)₂CMe₂ + (C₆H₅O)₂CO → 1/n [OC(OC₆H₄)₂CMe₂]_n + 2 C₆H₅OH

The diphenyl carbonate was derived in part from carbon monoxide, this route being greener than the phosgene method.[6]

Properties and processing

Polycarbonate is a durable material. Although it has high impact-resistance, it has low scratch-resistance. Therefore, a hard coating is applied to polycarbonate eyewear lenses and polycarbonate exterior automotive components. The characteristics of polycarbonate compare to those of polymethyl methacrylate (PMMA, acrylic), but polycarbonate is stronger and will hold up longer to extreme temperature. Polycarbonate is highly transparent to visible light, with better light transmission than many kinds of glass.

Polycarbonate has a glass transition temperature of about 147 °C (297 °F),[7] so it softens gradually above this point and flows above about 155 °C (311 °F).[8] Tools must be held at high temperatures, generally above 80 °C (176 °F) to make strain-free and stress-free products. Low molecular mass grades are easier to mold than higher grades, but their strength is lower as a result. The toughest grades have the highest molecular mass, but are much more difficult to process.

Unlike most thermoplastics, polycarbonate can undergo large plastic deformations without cracking or breaking. As a result, it can be processed and formed at room temperature using sheet metal techniques, such as bending on a brake. Even for sharp angle bends with a tight radius, heating may not be necessary. This makes it valuable in prototyping applications where transparent or electrically non-conductive parts are needed, which cannot be made from sheet metal. PMMA/Acrylic, which is similar in appearance to polycarbonate, is brittle and cannot be bent at room temperature.

Main transformation techniques for polycarbonate resins:

• extrusion into tubes, rods and other profiles including multiwall
• extrusion with cylinders (calenders) into sheets (0.5–20 mm (0.020–0.787 in)) and films (below 1 mm (0.039 in)), which can be used directly or manufactured into other shapes using thermoforming or secondary fabrication techniques, such as bending, drilling, or routing. Due to its chemical properties it is not conducive to laser-cutting.
• injection molding into ready articles

Polycarbonate may become brittle when exposed to ionizing radiation above 25 kGy (J/kg).[9]

A bottle made from polycarbonate

Applications

Electronic components

Polycarbonate is mainly used for electronic applications that capitalize on its collective safety features. Being a good electrical insulator and having heat-resistant and flame-retardant properties, it is used in various products associated with electrical and telecommunications hardware. It can also serve as a dielectric in high-stability capacitors.[6] However, commercial manufacture of polycarbonate capacitors mostly stopped after sole manufacturer Bayer AG stopped making capacitor-grade polycarbonate film at the end of year 2000.[10][11]

Construction materials

Polycarbonate sheeting in a greenhouse

The second largest consumer of polycarbonates is the construction industry, e.g. for domelights, flat or curved glazing, and sound walls.

Data storage

CDs and DVDs

A major application of polycarbonate is the production of Compact Discs, DVDs, and Blu-ray Discs. These discs are produced by injection molding polycarbonate into a mold cavity that has on one side a metal stamper containing a negative image of the disc data, while the other mold side is a mirrored surface. Typical products of sheet/film production include applications in advertisement (signs, displays, poster protection).[6]

Automotive, aircraft, and security components

In the automotive industry, injection-molded polycarbonate can produce very smooth surfaces that make it well-suited for sputter deposition or evaporation deposition of aluminium without the need for a base-coat. Decorative bezels and optical reflectors are commonly made of polycarbonate. Due to its low weight and high impact resistance, polycarbonate is the dominant material for making automotive headlamp lenses. However, automotive headlamps require outer surface coatings because of its low scratch resistance and susceptibility to ultraviolet degradation (yellowing). The use of polycarbonate in automotive applications is limited to low stress applications. Stress from fasteners, plastic welding and molding render polycarbonate susceptible to stress corrosion cracking when it comes in contact with certain accelerants such as salt water and plastisol. It can be laminated to make bullet-proof "glass", although "bullet-resistant" is more accurate for the thinner windows, such as are used in bullet-resistant windows in automobiles. The thicker barriers of transparent plastic used in teller's windows and barriers in banks are also polycarbonate.

So-called "theft-proof" large plastic packaging for smaller items, which cannot be opened by hand, is uniformly made from polycarbonate.

Lockheed Martin F-22 cockpit canopy

The cockpit canopy of the Lockheed Martin F-22 Raptor jet fighter is made from a piece of high optical quality polycarbonate, and is the largest piece of its type formed in the world.[12][13]

Niche applications

Polycarbonate, being a versatile material with attractive processing and physical properties, has attracted myriad smaller applications. The use of injection molded drinking bottles, glasses and food containers is common, but the use of BPA in the manufacture of polycarbonate has stirred concerns (see Potential hazards in food contact applications), leading to development and use of "BPA-free" plastics in various formulations.

Laboratory safety goggles

Polycarbonate is commonly used in eye protection, as well as in other projectile-resistant viewing and lighting applications that would normally indicate the use of glass, but require much higher impact-resistance. Polycarbonate lenses also protect the eye from UV light. Many kinds of lenses are manufactured from polycarbonate, including automotive headlamp lenses, lighting lenses, sunglass/eyeglass lenses, swimming goggles and SCUBA masks, and safety glasses/goggles/visors including visors in sporting helmets/masks and police riot gear (helmet visors, riot shields, etc.). Windscreens in small motorized vehicles are commonly made of polycarbonate, such as for motorcycles, ATVs, golf carts, and small airplanes and helicopters.

The light weight of polycarbonate as opposed to glass has led to development of electronic display screens that replace glass with polycarbonate, for use in mobile and portable devices. Such displays include newer e-ink and some LCD screens, though CRT, plasma screen and other LCD technologies generally still require glass for its higher melting temperature and its ability to be etched in finer detail.

As more and more governments are restricting the use of glass in pubs and clubs due to the increased incidence of glassings, polycarbonate glasses are becoming popular for serving alcohol because of their strength, durability, and glass-like feel.[14][15]

Other miscellaneous items include durable, lightweight luggage, MP3/digital audio player cases, ocarinas, computer cases, riot shields, instrument panels, tealight candle containers and food blender jars. Many toys and hobby items are made from polycarbonate parts, like fins, gyro mounts, and flybar locks in radio-controlled helicopters,[16] and transparent LEGO (ABS is used for opaque pieces).[17]

Standard Polycarbonate resins are not suitable for long term exposure to UV radiation. To overcome this the primary resin can have UV stabilisers added. These grades are sold as UV stabilized polycarbonate to injection moulding and extrusion companies. Other applications, including polycarbonate sheet, may have the anti-UV layer added as a special coating or a coextrusion for enhanced weathering resistance.

Polycarbonate is also used as a printing substrate for nameplate and other forms of industrial grade under printed products. The polycarbonate provides a barrier to wear, the elements, and fading.

Medical applications

Many polycarbonate grades are used in medical applications and comply with both ISO 10993-1 and USP Class VI standards (occasionally referred to as PC-ISO). Class VI is the most stringent of the six USP ratings. These grades can be sterilized using steam at 120 °C, gamma radiation, or by the ethylene oxide (EtO) method.[18] Dow Chemical strictly limits all its plastics with regard to medical applications.[19][20] Aliphatic polycarbonates have been developed with improved biocompatibility and degradability for nanomedicine applications.[21]

Phones

Some major smartphone manufacturers use polycarbonate. Nokia used polycarbonate in their phones starting with the N9's unibody case in 2011. This practice continued with various phones in the Lumia series. Samsung has started using polycarbonate with Galaxy S III's battery cover in 2012. This practice continues with various phones in the Galaxy series. Apple started using polycarbonate with the iPhone 5C's unibody case in 2013.

History

Polycarbonates were first discovered in 1898 by Alfred Einhorn, a German scientist working at the University of Munich.[22] However, after 30 years of laboratory research, this class of materials was abandoned without commercialization. Research resumed in 1953, when Hermann Schnell at Bayer in Uerdingen, Germany patented the first linear polycarbonate. The brand name "Makrolon" was registered in 1955.[23]

Also in 1953, and one week after the invention at Bayer, Daniel Fox at General Electric in Schenectady, New York, independently synthesized a branched polycarbonate. Both companies filed for U.S. patents in 1955, and agreed that the company lacking priority would be granted a license to the technology.[24][25]

Once patent priority was resolved, in Bayer's favor, Bayer began commercial production under the trade name Makrolon in 1958 and GE began production under the name Lexan in 1960, creating the GE Plastics division in 1973.[26]

After 1970, the brownish original polycarbonate tint was improved to "glass-clear."

Potential hazards in food contact applications

Main articles: Bisphenol A and Endocrine disruptor

The use of polycarbonate containers for the purpose of food storage is controversial. The basis of this controversy is their hydrolysis (degradation by water, often referred to as leaching) occurring at high temperature, releases bisphenol A:

1/n [OC(OC₆H₄)₂CMe₂]_n + H₂O → (HOC₆H₄)₂CMe₂ + CO₂

More than 100 studies have explored the bioactivity of bisphenol A derived from polycarbonates. Bisphenol A appeared to be released from polycarbonate animal cages into water at room temperature and it may have been responsible for enlargement of the reproductive organs of female mice.[27] However, the animal cages used in the research were fabricated from industrial grade polycarbonate, rather than FDA food grade polycarbonate.

An analysis of the literature on bisphenol A leachate low-dose effects by vom Saal and Hughes published in August 2005 seems to have found a suggestive correlation between the source of funding and the conclusion drawn. Industry-funded studies tend to find no significant effects whereas government-funded studies tend to find significant effects.[28]

Sodium hypochlorite bleach and other alkali cleaners catalyze the release of the bisphenol A from polycarbonate containers.[29][30] A chemical compatibility chart shows that polycarbonate is incompatible with ammonia and acetone because it dissolves in their presence.[31] Alcohol is one recommended organic solvent for cleaning grease and oils from polycarbonate.

Environmental impact

Disposal

Studies have shown that at temperatures above 70 °C, and high humidity, polycarbonate will hydrolyze to Bis-phenol A (BPA). This condition is similar to that observed in most incinerators. After about 30 days at 85°C / 96% RH, surface crystals are formed which for 70% consisted of BPA.[32] BPA is a compound that is currently on the list of potential environmental hazardous chemicals. It is on the watch list of many countries, such as United States and Germany.[33]

-(-OC₆H₄)₂C(CH₃)₂CO-)-_n + H₂O ${\displaystyle \longrightarrow }$ (CH₃)₂C(C₆H₄OH)₂ + CO₂

The leaching of BPA from polycarbonate can also occur at environmental temperature and normal pH (in landfills).The amount of leaching increases as the discs get older. A study found that the decomposition of BPA in landfills (under anaerobic conditions) will not occur.[33] It will therefore be persistent in landfills. Eventually, it will find its way into water bodies and contribute to aquatic pollution.[33][34]

Photo-oxidation of polycarbonate

In the presence of UV light, oxidation of this polymer yields compounds such as ketones, phenols, o-phenoxybenzoic acid, benzyl alcohol and other unsaturated compounds. This has been suggested through kinetic and spectral studies. The yellow color formed after long exposure to sun can also be related to further oxidation of phenolic end group[35]

(OC₆H₄)₂C(CH₃)₂CO )_n + O₂ , R* → (OC₆H₄)₂C(CH₃CH₂)CO)_n

This product can be further oxidized to form smaller unsaturated compounds. This can proceed via two different pathways, the products formed depends on which mechanism takes place.

Pathway A

(OC₆H₄)₂C(CH₃CH₂)CO + O₂, H* ${\displaystyle \longrightarrow }$ HO(OC₆H₄)OCO + CH₃COCH₂(OC₆H₄)OCO

Pathway B

(OC₆H₄)₂C(CH₃CH₂)CO)_n + O₂, H* ${\displaystyle \longrightarrow }$ OCO(OC₆H₄)CH₂OH + OCO(OC₆H₄)COCH₃

Photo-oxidation reaction.[36]

Photo-aging reaction

Photo-aging is another degradation route for polycarbonates. Polycarbonate molecules (such as the aromatic ring) absorb UV radiation. This absorbed energy causes cleavage of covalent bonds which initiates the photo-aging process. The reaction can be propagated via side chain oxidation, ring oxidation or photo-fries rearrangement. Products formed include phenyl salicylate, dihydroxybenzophenone groups, and hydroxydiphenyl ether groups.[35][37][38]

n(C₁₆H₁₄O₃) ${\displaystyle \longrightarrow }$ C₁₆H₁₇O₃ + C₁₃H₁₀O₃

Polycarbonate Phenyl salicylate 2,2-dihydroxybenzophenone

Thermal degradation

Waste polycarbonate will degrade at high temperatures to form solid, liquid and gaseous pollutants. A study showed that the products were about 40–50 wt.% liquid, 14–16 wt.% gases, while 34–43 wt.% remained as solid residue. Liquid products contained mainly phenol derivatives (∼75wt.%) and bisphenol (∼10wt.%) also present.[37] Therefore, burning of these discs is also not a viable method of disposal. Polycarbonate, however, can be safely recycled as a carbon source in steel-making industry.[39]

Phenol derivatives are environmental pollutants, classified as volatile organic compounds (VOC). Studies show they are likely to facilitate ground level ozone formation and increase photo-chemical smog.[40] In aquatic bodies, they can potentially accumulate in organisms. They are persistent in landfills, do not readily evaporate and would remain in the atmosphere.[41]

Effect of fungi

In 2001 a species of fungus in Belize, Geotrichum candidum, was found to consume the polycarbonate found in compact discs (CD).[42] This has prospects for bioremediation.

See also

• CR-39, allyl diglycol carbonate (ADC) used for eyeglasses
• Organic electronics
• Mobile phone accessories
• Thermoplastic polyurethane
• Vapor polishing

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