Disilene

Disilene /daɪsaɪliːn/ (systematically named disilicon tetrahydride) is an inorganic compound with the chemical formula Si
2H
4. The name disilene, referring to the structure of a particular prototropic tautomer of the molecule. It is the simplest silene.

Disilene
Identifiers
ChemSpider
Properties
Si
2H
4
Molar mass 60.2028 g mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Properties and bonding

Disilene is a molecule with one Si=Si bond, and four equivalent Si-H bonds.

Unlike ethylene, disilene is kinetically unstable with respect to tautomerisation. Disilene has two other tautomers, that are very close in energy: (μ2-H)disilene, and disilanylidene.[1]

Organodisilenes
Structure of tetramesityl disilene.

Disilenes bearing sterically bulky substituents are isolable and have been well characterized although they remain mainly of academic interest. The first stabilised disilene was tetramesityldisilene, (C6Me3H2)4Si2. The Si=Si distance in this molecule is 2.15 Å, about 10% shorter than a typical Si–Si single bond. The Si2C4 core is roughly planar.[2] Such species are typically prepared by reduction of organosilicon halides: 2 R2SiCl2 + 4 Na → R2Si=SiR2 + 4 NaCl An alternative synthesis involves photolysis of trisilacyclopropanes. When the R group is not bulky, cyclic or polymeric polysilanes are the products.

In one study[3] a disilene is prepared by an intramolecular coupling of a 1,1-dibromosilane with potassium graphite. The silicon double bond in the resulting compound has a bond length of 227 picometer (second largest ever found) with trans-bent angles 33° and 31° (by X-ray diffraction).

In addition to this the substituents around the Si-Si bond are twisted by 43°. The disilene isomerizes to a tetracyclic compound by heating at 110°C in xylene thereby releasing its strain energy.

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References
  1. McCarthy, M. C.; Yu, Z.; Sari, L.; Schaefer, H. F.; Thaddeus, P. (15 February 2006). "Monobridged Si2H4". The Journal of Chemical Physics. USA: American Institute of Physics. 124 (7). doi:10.1063/1.2168150.
  2. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  3. Fused Tricyclic Disilenes with Highly Strained Si-Si Double Bonds: Addition of a Si-Si Single Bond to a Si-Si Double Bond Ryoji Tanaka, Takeaki Iwamoto, and Mitsuo Kira Angewandte Chemie International Edition Volume 45, Issue 38 , Pages 6371 - 6373 2006 doi:10.1002/anie.200602214
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