Strain energy

In physics, strain energy is the energy stored by a system undergoing deformation. For linearly elastic materials, strain energy is:
${\displaystyle U={\frac {1}{2}}V\sigma \epsilon ={\frac {1}{2}}VE\epsilon ^{2}={\frac {1}{2}}{\frac {V}{E}}\sigma ^{2}}$
where σ is stress, ε is strain, V is volume, and E is Young's modulus:
${\displaystyle E={\frac {\sigma }{\epsilon }}}$

For strain energy of structures, see Energy principles in structural mechanics. For strain energy of solids, see Strain energy density function.

Molecular Strain

In a molecule, strain energy is released when the constituent atoms are allowed to rearrange themselves in a chemical reaction.[1] The external work done on an elastic member in causing it to distort from its unstressed state is transformed into strain energy which is a form of potential energy. The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work.

For example, the heat of combustion of cyclopropane (696 kJ/mol) is higher than that of propane (657 kJ/mol) for each additional CH₂ unit. Compounds with unusually large strain energy include tetrahedranes, propellanes, cubane-type clusters, fenestranes and cyclophanes.

References

1. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, Michael B. Smith & Jerry March, Wiley-Interscience, 5th edition, 2001, ISBN 0-471-58589-0