Charcoal

Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) so as to drive off all water and other volatile constituents. In the traditional version of this pyrolysis process, called charcoal burning, the heat is supplied by burning part of the starting material itself, with a limited supply of oxygen. Charcoal can also be produced by heating the material in a closed retort.

For other uses, see Charcoal (disambiguation).

Charcoal burning
Wood pile before covering it with turf or soil, and firing it (circa 1890)

This process also happens while burning wood, as in a fireplace or wood stove. The visible flame in that case is actually due to combustion of the volatiles given off as the wood turns into charcoal. The soot and smoke commonly given off by wood fire result from incomplete combustion of those volatiles. Charcoal itself burns at a higher temperature than wood, with hardly a visible flame, and gives off practically no smoke, soot, or unburnt volatiles.

History
Further information: Fusain and Fossil record of fire

The production of wood charcoal in locations where there is an abundance of wood dates back to ancient times. It generally begins with piling billets of wood on their ends to form a conical pile. Openings are left at the bottom to admit air, with a central shaft serving as a flue. The whole pile is covered with turf or moistened clay. The firing is begun at the bottom of the flue, and gradually spreads outwards and upwards. The success of the operation depends upon the rate of the combustion. Under average conditions wood yields about 60% charcoal by volume, or 25% by weight; small-scale production methods often yield only about 50% by volume, while large-scale methods enabled higher yields of about 90% by the 17th century. The operation is so delicate that it was generally left to colliers (professional charcoal burners). They often lived alone in small huts to tend their wood piles. For example, in the Harz Mountains of Germany, charcoal burners lived in conical huts called Köten which are extant today.

An abandoned charcoal kiln near Walker, Arizona, USA.

The massive production of charcoal (at its height employing hundreds of thousands, mainly in Alpine and neighbouring forests) was a major cause of deforestation, especially in Central Europe. In England, many woods were managed as coppices, which were cut and regrown cyclically, so that a steady supply of charcoal was available. Complaints (as early as the Stuart period) about shortages may relate to the results of temporary over-exploitation or the impossibility of increasing production to match growing demand. The increasing scarcity of easily harvested wood was a major factor behind the switch to fossil fuel equivalents, mainly coal and brown coal for industrial use.

The modern process of carbonizing wood, either in small pieces or as sawdust in cast iron retorts, is extensively practiced where wood is scarce, and also for the recovery of valuable byproducts (wood spirit, pyroligneous acid, wood tar), which the process permits. The question of the temperature of the carbonization is important; according to J. Percy, wood becomes brown at 220 °C (428 °F), a deep brown-black after some time at 280 °C (536 °F), and an easily powdered mass at 310 °C (590 °F).[1] Charcoal made at 300 °C (572 °F) is brown, soft and friable, and readily inflames at 380 °C (716 °F); made at higher temperatures it is hard and brittle, and does not fire until heated to about 700 °C (1,292 °F).

In Finland and Scandinavia, the charcoal was considered the by-product of wood tar production. The best tar came from pine, thus pinewoods were cut down for tar pyrolysis. The residual charcoal was widely used as substitute for metallurgical coke in blast furnaces for smelting. Tar production led to rapid local deforestation. The end of tar production at the end of the 19th century resulted in rapid re-forestation of affected areas.

The charcoal briquette was first invented and patented by Ellsworth B. A. Zwoyer of Pennsylvania in 1897[2] and was produced by the Zwoyer Fuel Company. The process was further popularized by Henry Ford, who used wood and sawdust byproducts from automobile fabrication as a feedstock. Ford Charcoal went on to become the Kingsford Company.

Production methods
Charcoal under a microscope.

Charcoal has been made by various methods. The traditional method in Britain used a clamp.[3] This is essentially a pile of wooden logs (e.g. seasoned oak) leaning in a circle against a chimney. The chimney consists of 4 wooden stakes held up by some rope. The logs are completely covered with soil and straw allowing no air to enter. It must be lit by introducing some burning fuel into the chimney; the logs burn very slowly and transform into charcoal in a period of 5 days' burning. If the soil covering gets torn or cracked by the fire, additional soil is placed on the cracks. Once the burn is complete, the chimney is plugged to prevent air from entering. The true art of this production method is in managing the sufficient generation of heat, by combusting part of the wood material, and its transfer to wood parts in the process of being carbonised. A strong disadvantage of this production method is the huge amount of emissions that are harmful to human health and the environment (emissions of unburnt methane).[4] As a result of the partial combustion of wood material, the efficiency of the traditional method is low.

Modern methods employ retorting technology, in which process heat is recovered from, and solely provided by, the combustion of gas released during carbonisation.[5] Yields of retorting are considerably higher than those of kilning, and may reach 35%-40%.

The properties of the charcoal produced depend on the material charred. The charring temperature is also important. Charcoal contains varying amounts of hydrogen and oxygen as well as ash and other impurities that, together with the structure, determine the properties. The approximate composition of charcoal for gunpowders is sometimes empirically described as C7H4O. To obtain a coal with high purity, source material should be free of non-volatile compounds.

Wood charcoal is obtained as the residue by destructive distillation of wood such that the products are:

Types
Binchōtan, Japanese high grade charcoal made from ubame oak
Ogatan, charcoal briquettes made from sawdust
  • Common charcoal is made from peat, coal, wood, coconut shell, or petroleum.
  • Sugar charcoal is obtained from the carbonization of sugar and is particularly pure. It is purified by boiling with acids to remove any mineral matter and is then burned for a long time in a current of chlorine to remove the last traces of hydrogen.[7] It was used by Henri Moissan in his early attempt to create synthetic diamonds.
  • Activated charcoal is similar to common charcoal but is manufactured especially for medical use. To produce activated charcoal, common charcoal is heated to about 900 °C (1,650 °F) in the presence of a gas (usually steam), causing the charcoal to develop many internal spaces, or "pores", which help the activated charcoal to trap chemicals. Impurities on the surface of the charcoal are also removed during this process, greatly increasing its adsorption capacity.
  • Lump charcoal is a traditional charcoal made directly from hardwood material. It usually produces far less ash than briquettes.
  • Japanese charcoal has had pyroligneous acid removed during the charcoal making; it therefore produces almost no smell or smoke when burned. The traditional charcoal of Japan is classified into two types:
    • White charcoal (Binchōtan) is very hard and produces a metallic sound when struck.
    • Black charcoal
    • Ogatan is a more recent type made from hardened sawdust.
  • Pillow shaped briquettes are made by compressing charcoal, typically made from sawdust and other wood by-products, with a binder and other additives. The binder is usually starch. Briquettes may also include brown coal (heat source), mineral carbon (heat source), borax, sodium nitrate (ignition aid), limestone (ash-whitening agent), raw sawdust (ignition aid), and other additives.
  • Sawdust briquette charcoal is made by compressing sawdust without binders or additives. It is the preferred charcoal in Taiwan, Korea, Greece, and the Middle East. It has a round hole through the center, with a hexagonal intersection. It is used primarily for barbecue as it produces no odour, no smoke, little ash, high heat, and long burning hours (exceeding 4 hours).
  • Extruded charcoal is made by extruding either raw ground wood or carbonized wood into logs without the use of a binder. The heat and pressure of the extruding process hold the charcoal together. If the extrusion is made from raw wood material, the extruded logs are subsequently carbonized.

Uses
Grill charcoal made from coconut shell

Charcoal has been used since earliest times for a large range of purposes including art and medicine, but by far its most important use has been as a metallurgical fuel. Charcoal is the traditional fuel of a blacksmith's forge and other applications where an intense heat is required. Charcoal was also used historically as a source of black pigment by grinding it up. In this form charcoal was important to early chemists and was a constituent of formulas for mixtures such as black powder. Due to its high surface area charcoal can be used as a filter, and as a catalyst or as an adsorbent.

Metallurgical fuel

Charcoal burns at temperatures exceeding 1,100 degrees Celsius (2,010 degrees Fahrenheit).[8] By comparison the melting point of iron is approximately 1,200 to 1,550 °C (2,190 to 2,820 °F). Due to its porosity, it is sensitive to the flow of air and the heat generated can be moderated by controlling the air flow to the fire. For this reason charcoal is still widely used by blacksmiths. Charcoal has been used for the production of iron since Roman times and steel in modern times where it also provided the necessary carbon. Charcoal briquettes can burn up to approximately 1,260 °C (2,300 °F) with a forced air blower forge.[9]

In the 16th century, England had to pass laws to prevent the country from becoming completely denuded of trees due to production of iron. In the 19th century charcoal was largely replaced by coke in steel production due to cost.

Industrial fuel

Historically, charcoal was used in great quantities for smelting iron in bloomeries and later blast furnaces and finery forges. This use was replaced by coal in the 19th Century as part of the Industrial Revolution.

Cooking fuel

Prior to the Industrial Revolution, charcoal was occasionally used as a cooking fuel. Modern "charcoal briquettes", widely used for outdoor cooking, are made with charcoal but may also include coal as an energy source as well as accelerants, binders and filler.

Reducing agent

Certain types of charcoal, such as wood charcoal, are used for reducing heated metallic oxides to their respective metals:

  • ZnO + C → Zn + CO
  • Fe2O3 + 3C → 2Fe + 3CO

Charcoal can also be used to reduce super heated steam to hydrogen (along with the formation of carbon monoxide):

Syngas production, automotive fuel

Like many other sources of carbon, charcoal can be used for the production of various syngas compositions; i.e., various CO + H2 + CO2 + N2 mixtures. The syngas is typically used as fuel, including automotive propulsion, or as a chemical feedstock.

In times of scarce petroleum, automobiles and even buses have been converted to burn wood gas (a gas mixture consisting primarily of diluting atmospheric nitrogen, but also containing combustible gasses, mostly carbon monoxide) released by burning charcoal or wood in a wood gas generator. In 1931 Tang Zhongming developed an automobile powered by charcoal, and these cars were popular in China until the 1950s and in occupied France during World War II (called gazogènes).

Pyrotechnics

Charcoal is used in the production of black powder, which is used extensively in the production of fireworks. It is usually ground into a fine powder, with airfloat grade being the finest particle size available commercially. When used in black powder compositions, it is often ball-milled with other ingredients so that they are intimately mixed together. Certain charcoals perform better when used to make black powder, these include spruce, willow, paulownia and grapevine among others. Charcoal produces fine dark orange/golden sparks. Usually, powder with a mesh size from 10 to 325 is used to obtain showers of golden sparks in pyrotechnic compositions.[10]

Cosmetic use of bamboo charcoal

Charcoal is also incorporated in multiple cosmetic products.[11] It can be produced a.o. from regular bamboo cut into small pieces and boiled in water to remove soluble compounds.[11] Raw bamboo charcoal is obtained after drying and carbonization in an oven at elevated temperature.[11] The role of charcoal in cosmetics is based on its highly effective absorbing properties at a microscopic-scale.[11]

Carbon source

Charcoal may be used as a source of carbon in chemical reactions. One example of this is the production of carbon disulphide through the reaction of sulfur vapors with hot charcoal. In that case the wood should be charred at high temperature to reduce the residual amounts of hydrogen and oxygen that lead to side reactions.

Purification and filtration
Activated carbon

Charcoal may be activated to increase its effectiveness as a filter. Activated charcoal readily adsorbs a wide range of organic compounds dissolved or suspended in gases and liquids. In certain industrial processes, such as the purification of sucrose from cane sugar, impurities cause an undesirable color, which can be removed with activated charcoal. It is also used to absorb odors and toxins in gases, such as air. Charcoal filters are also used in some types of gas masks. The medical use of activated charcoal is mainly the absorption of poisons.[12] Activated charcoal is available without a prescription, so it is used for a variety of health-related applications. For example, it is often used to reduce discomfort and embarrassment due to excessive gas (flatulence) in the digestive tract.[13]

Animal charcoal or bone black is the carbonaceous residue obtained by the dry distillation of bones. It contains only about 10% carbon, the remaining being calcium and magnesium phosphates (80%) and other inorganic material originally present in the bones. It is generally manufactured from the residues obtained in the glue and gelatin industries. Its decolorizing power was applied in 1812 by Derosne to the clarification of the syrups obtained in sugar refining; but its use in this direction has now greatly diminished, owing to the introduction of more active and easily managed reagents. It is still used to some extent in laboratory practice. The decolorizing power is not permanent, becoming lost after using for some time; it may be revived, however, by washing and reheating. Wood charcoal also to some extent removes coloring material from solutions, but animal charcoal is generally more effective.

Art
Four sticks of vine charcoal and four sticks of compressed charcoal
Two charcoal pencils in paper sheaths that are unwrapped as the pencil is used, and two charcoal pencils in wooden sheaths
Main article: Charcoal (art)

Charcoal is used in art for drawing, making rough sketches in painting and is one of the possible media for making a parsemage. It must usually be preserved by the application of a fixative. Artists generally utilize charcoal in three forms:

  • Vine charcoal is created by burning grape vines.
  • Willow charcoal is created by burning sticks.
  • Powdered charcoal is often used to "tone" or cover large sections of a drawing surface. Drawing over the toned areas darkens it further, but the artist can also lighten (or completely erase) within the toned area to create lighter tones.
  • Compressed charcoal charcoal powder mixed with gum binder compressed into round or square sticks. The amount of binder determines the hardness of the stick.[14] Compressed charcoal is used in charcoal pencils.

Horticulture
Main article: Biochar

One additional use of charcoal was rediscovered recently in horticulture. Although American gardeners have been using charcoal for a short while, research on Terra preta soils in the Amazon has found the widespread use of biochar by pre-Columbian natives to turn unproductive soil into carbon rich soil. The technique may find modern application, both to improve soils and as a means of carbon sequestration.[15]

Animal husbandry

Charcoal is mixed with feed, added to litter, or used in the treatment of the manure.[16] Poultry benefits from using charcoal in this manner.[17][18]

A concern that activated charcoal might be used unscrupulously to allow livestock to tolerate low quality feed contaminated with aflatoxins resulted in the Association of American Feed Control Officials banning it in 2012 from use in commercial livestock feeds.[19]

Medicine
See also: Activated charcoal (medication)
Charcoal pile

Charcoal was consumed in the past as dietary supplement for gastric problems in the form of charcoal biscuits. Now it can be consumed in tablet, capsule or powder form, for digestive effects.[20] Research regarding its effectiveness is controversial.[21]

Charcoal has been used in combination with saccharin in research to measure mucociliary transport time.[22]

Charcoal has also been incorporated in toothpaste formulas; however, there is no evidence to determine its safety and effectiveness.[23]

Red colobus monkeys in Africa have been observed eating charcoal for the purposes of self-medication. Their leafy diets contain high levels of cyanide, which may lead to indigestion. So they learned to consume charcoal, which absorbs the cyanide and relieves indigestion. This knowledge about supplementing their diet is transmitted from mother to infant.[24]

Environmental sustainability

Production and utilisation of charcoal, like any use of woody biomass as fuel, typically results in emissions and can contribute to deforestation.

The use of charcoal as a smelting fuel has been experiencing a resurgence in South America resulting in severe environmental, social and medical problems.[25][26] Charcoal production at a sub-industrial level is one of the causes of deforestation. Charcoal production is now usually illegal and nearly always unregulated as in Brazil where charcoal production is a large illegal industry for making pig iron.[27][28][29]

Massive forest destruction has been documented in areas such as Virunga National Park in the Democratic Republic of Congo, where it is considered a primary threat to the survival of the mountain gorillas.[30] Similar threats are found in Zambia.[31] In Malawi, illegal charcoal trade employs 92,800 workers and is the main source of heat and cooking fuel for 90 percent of the nation's population.[32] Some experts, such as Duncan MacQueen, Principal Researcher–Forest Team, International Institute for Environment and Development (IIED), argue that while illegal charcoal production causes deforestation, a regulated charcoal industry that required replanting and sustainable use of the forests "would give their people clean efficient energy – and their energy industries a strong competitive advantage".[32]

Recent assessments of charcoal imported to Europe have shown that many charcoal products are produced from tropical wood, often of undeclared origin. In an analysis of barbecue charcoal marketed in Germany, the World Wildlife Fund finds that most products contain tropical wood. As a notable exception, reference is made to barbecue charcoal imports from Namibia, where charcoal is typically produced from surplus biomass resulting from bush encroachment.[33][34]

The last section of the film Le Quattro Volte (2010) gives a good and long, if poetic, documentation of the traditional method of making charcoal.[35] The Arthur Ransome children's series Swallows and Amazons (particularly the second book, Swallowdale) features carefully drawn vignettes of the lives and the techniques of charcoal burners at the start of the 20th century, in the Lake District of the UK. Antonín Dvořák's opera King and Charcoal Burner is based on a Czech legend about a king who gets lost in a forest and is rescued by a charcoal burner.

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See also

References
  1. Chisolm, Hugh (1910). Encyclopædia Britannica, Eleventh Edition, Volume V. New York.
  2. "Barbeque – History of Barbecue". Inventors.about.com. 15 June 2010. Retrieved 28 December 2011.
  3. "Geoarch". Geoarch. 31 May 1999. Archived from the original on 15 March 2004. Retrieved 20 May 2012.
  4. "Roland.V. Siemons, Loek Baaijens, An Innovative Carbonisation Retort: Technology and Environmental Impact, TERMOTEHNIKA, 2012, XXXVIII, 2, 131‡138 131" (PDF).
  5. "Kilning vs. Retorting: the cause of emissions of unburnt gases".
  6. "Pyroligneous Acid or Wood Vinegar". Scientific American. 14 November 1857. Retrieved 14 March 2020.
  7. Chisholm, Hugh, ed. (1911). "Carbon" . Encyclopædia Britannica. 5 (11th ed.). Cambridge University Press. pp. 305–307.
  8. Updated April 26, 2018 By Gabriella Munoz (26 April 2018). "How Hot Is a Bonfire?". Sciencing. Retrieved 13 November 2019.
  9. Cheng, Zhilong; Yang, Jian; Zhou, Lang; Liu, Yan; Wang, Qiuwang (1 January 2016). "Characteristics of charcoal combustion and its effects on iron-ore sintering performance". Applied Energy. 161: 364–374. doi:10.1016/j.apenergy.2015.09.095. ISSN 0306-2619.
  10. Kenneth L. Kosanke; Bonnie J. Kosanke (1999), "Pyrotechnic Spark Generation", Journal of Pyrotechnics: 49–62, ISBN 978-1-889526-12-6, archived from the original on 16 December 2017
  11. Ahmad, N; Isa, S.S.M.; Ramli, M.M.; Hambali, N.A.M.A.; Kasjoo, S.R.; Isa, M.M.; Nor, N.I.M.; Khalid, N. (2016). "Adsorption properties and potential applications of bamboo charcoal: A Review" (PDF). MATEC Web of Conferences. 78: 1–7. Archived from the original (PDF) on 24 July 2018. Retrieved 3 February 2018 – via edp sciences.
  12. Dawson, Andrew (1997). "Activated charcoal: a spoonful of sugar". Australian Prescriber. 20: 14–16. doi:10.18773/austprescr.1997.008.
  13. "Treating flatulence". NHS. NHS UK. Retrieved 27 May 2012.
  14. "charcoal: powdered, compressed, willow and vine". Muse Art and Design. Muse Art and Design. 7 September 2011. Archived from the original on 31 August 2012. Retrieved 27 May 2012.
  15. Johannes Lehmann, ed. (2009). Biochar for Environmental Management: Science and Technology. Stephen Joseph. Earthscan. ISBN 978-1-84407-658-1. Retrieved 30 December 2013.
  16. Gerlach, Achim; Schmidt, Hans-Peter (2014), "The use of biochar in cattle farming", The Biochar Journal, Arbaz, Switzerland, ISSN 2297-1114
  17. Yarrow, David (March 2015). "Biochar: Helping Everything from Soil Fertility to Odor Reduction". Acres U.S.A. Archived from the original on 9 June 2019. Retrieved 7 March 2019. Cite journal requires |journal= (help)
  18. Schupska Site=CAES News, Stephanie (10 March 2011). "Charcoal supplemented diet reduces ammonia in chickens' litter".
  19. Damerow, Gail (2015). The Chicken Health Handbook, 2nd Edition: A Complete Guide to Maximizing Flock Health and Dealing with Disease. p. 391. ISBN 978-1612120133.
  20. Stearn, Margaret (2007). Warts and all: straight talking advice on life's embarrassing problems. London: Murdoch Books. p. 333. ISBN 978-1-921259-84-5. Retrieved 3 May 2009.
  21. Am J Gastroenterology 2005 Feb 100(2)397–400 and 1999 Jan 94(1) 208-12
  22. Passali, Desiderio (1984). "Experiences in the determination of nasal mucociliary transport time". Acta Otolaryngol. 97 (3–4): 319–23. doi:10.3109/00016488409130995. PMID 6539042.
  23. Brooks, John K.; Bashirelahi, Nasir; Reynolds, Mark A. (7 June 2017). "Charcoal and charcoal-based dentifrices: A literature review". Journal of the American Dental Association. 148 (9): 661–670. doi:10.1016/j.adaj.2017.05.001. ISSN 1943-4723. PMID 28599961.
  24. "Clever Monkeys: Monkeys and Medicinal Plants". PBS. 13 September 2011. Retrieved 20 May 2012.
  25. Michael Smith; David Voreacos (21 January 2007). "Brazil: Enslaved workers make charcoal used to make basic steel ingredient". Seattle Times. Retrieved 16 September 2012.
  26. M. Kato1, D. M. DeMarini, A. B. Carvalho, M. A. V. Rego, A. V. Andrade1, A. S. V. Bonfim and D. Loomis (2004). "World at work: Charcoal producing industries in northeastern Brazil". Occupational and Environmental Medicine. 62 (2): 128–132. doi:10.1136/oem.2004.015172. PMC 1740946. PMID 15657196. Archived from the original on 22 November 2012. Retrieved 16 September 2012.CS1 maint: multiple names: authors list (link)
  27. "U.S. car manufacturers linked to Amazon destruction, slave labor". News.mongabay.com. 14 May 2012. Retrieved 20 May 2012.
  28. "Driving Destruction in the Amazon: How steel production is throwing the forest into the furnace". Greenpeace. 11 May 2012. Archived from the original on 20 May 2012. Retrieved 20 May 2012.
  29. The documentary film The Charcoal People (2000) shows in detail the deforestation in Brazil, the poverty of the laborers and their families, and the method of constructing and using a clamp for burning the wood.
  30. "Virunga National Park". Gorilla.cd. Archived from the original on 3 October 2008. Retrieved 20 May 2012.
  31. "Living on Earth: Zambia's Vanishing Forests". Loe.org. 4 March 1994. Retrieved 28 December 2011.
  32. "Is charcoal the key to sustainable energy consumption in Malawi?". UNEARTH News. July 2013. Archived from the original on 11 August 2013. Retrieved 10 August 2013.
  33. Zahnen, Johannes. "Market Analysis Barbecue Charcoal 2018 - The Dirty Business of Barbecue Charcoal" (PDF). WWF. Retrieved 27 May 2020.
  34. "From Bush to Charcoal: the Greenest Charcoal Comes from Namibia". Forest Stewardship Council. 17 March 2020. Retrieved 27 May 2020.
  35. "Le quattro volte (2010)". Retrieved 16 September 2012.
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