NDP-glucose—starch glucosyltransferase

In enzymology, a NDP-glucose—starch glucosyltransferase (EC 2.4.1.242) is an enzyme that catalyzes the chemical reaction

NDP-glucose + (1,4-alpha-D-glucosyl)n NDP + (1,4-alpha-D-glucosyl)n+1
NDP-glucose-starch glucosyltransferase
Identifiers
EC number2.4.1.242
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum

Thus, the two substrates of this enzyme are NDP-glucose and (1,4-alpha-D-glucosyl)n, whereas its two products are NDP and (1,4-alpha-D-glucosyl)n+1.

This enzyme belongs to the family of glycosyltransferases, specifically the hexosyltransferases. The systematic name of this enzyme class is NDP-glucose:1,4-alpha-D-glucan 4-alpha-D-glucosyltransferase. Other names in common use include granule-bound starch synthase, starch synthase II (ambiguous), waxy protein, starch granule-bound nucleoside diphosphate glucose-starch, glucosyltransferase, granule-bound starch synthase I, GBSSI, granule-bound starch synthase II, GBSSII, GBSS, and NDPglucose-starch glucosyltransferase.

References

    • Tsai CY (1974). "The function of the waxy locus in starch synthesis in maize endosperm". Biochem. Genet. 11 (2): 83–96. doi:10.1007/BF00485766. PMID 4824506.
    • Nakamura T, Vrinten P, Hayakawa K, Ikeda J (1998). "Characterization of a granule-bound starch synthase isoform found in the pericarp of wheat". Plant Physiol. 118 (2): 451–9. doi:10.1104/pp.118.2.451. PMC 34820. PMID 9765530.
    • Fujita N, Taira T (1998). "A 56-kDa protein is a novel granule-bound starch synthase existing in the pericarps, aleurone layers, and embryos of immature seed in diploid wheat (Triticum monococcum L.)". Planta. 207 (1): 125–32. doi:10.1007/s004250050464. PMID 9951718.
    • Murai J, Taira T, Ohta D (1999). "Isolation and characterization of the three Waxy genes encoding the granule-bound starch synthase in hexaploid wheat". Gene. 234 (1): 71–9. doi:10.1016/S0378-1119(99)00178-X. PMID 10393240.
    • Nelson OE (1968). "The waxy locus in maize. II The location of the controlling element alleles". Genetics. 60 (3): 507–524. PMC 1212058. PMID 17248421.


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