Montmorillonite

Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, is a 2:1 clay, meaning that it has two tetrahedral sheets of silica sandwiching a central octahedral sheet of alumina. The particles are plate-shaped with an average diameter around 1 μm and a thickness of 0.96 nm; magnification of about 25,000 times, using an electron microscope, is required to "see" individual clay particles. Members of this group include, amongst others, saponite, nontronite, beidellite, and hectorite.

Montmorillonite
A sample of montmorillonite
General
Category	Phyllosilicates Smectite group
Formula (repeating unit)	(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2·nH2O
Crystal system	Monoclinic
Crystal class	Prismatic 2/m) (same H-M symbol)
Space group	C2/m
Unit cell	a = 5.19 Å, b = 9.02 Å, c = 12.4 Å; β = 94°; Z = 2
Identification
Color	White, pale pink, blue, yellow, red, green
Crystal habit	compact masses of lamellar or globular microcrystalline aggregates
Cleavage	{001} perfect
Fracture	Uneven
Mohs scale hardness	1–2
Luster	Dull, earthy
Diaphaneity	Translucent
Specific gravity	1.7-2
Optical properties	Biaxial (-)
Refractive index	nα = 1.485–1.535 nβ = 1.504–1.550 nγ = 1.505–1.550
Birefringence	δ = 0.020
2V angle	Measured: 5° to 30°
References	[1][2][3][4]

Montmorillonite is a subclass of smectite, a 2:1 phyllosilicate mineral characterized as having greater than 50% octahedral charge; its cation exchange capacity (CEC) is due to isomorphous substitution of Mg for Al in the central alumina plane. The substitution of lower valence cations in such instances leaves the nearby oxygen atoms with a net negative charge that can attract cations. In contrast, beidellite is smectite with greater than 50% tetrahedral charge originating from isomorphous substitution of Al for Si in the silica sheet.

The individual crystals of montmorillonite clay are not tightly bound hence water can intervene, causing the clay to swell. The water content of montmorillonite is variable and it increases greatly in volume when it absorbs water. Chemically, it is hydrated sodium calcium aluminium magnesium silicate hydroxide (Na,Ca)_0.33(Al,Mg)₂(Si₄O₁₀)(OH)₂·nH₂O. Potassium, iron, and other cations are common substitutes, and the exact ratio of cations varies with source. It often occurs intermixed with chlorite, muscovite, illite, cookeite, and kaolinite.

Cave conditions

Montmorillonite can be concentrated and transformed within cave environments. The natural weathering of the cave can leave behind concentrations of aluminosilicates which were contained within the bedrock. Montmorillonite can form slowly in solutions of aluminosilicates. High HCO₃ ⁻ concentrations and long periods of time can aid in its formation. Montmorillonite can then transform to palygorskite under dry conditions and to halloysite-10Å (endellite) in acidic conditions (pH 5 or lower). Halloysite-10Å can further transform into halloysite-7Å by drying.[5]

Uses

Structure of montmorillonite

Montmorillonite is used in the oil drilling industry as a component of drilling mud, making the mud slurry viscous, which helps in keeping the drill bit cool and removing drilled solids. It is also used as a soil additive to hold soil water in drought-prone soils, used in the construction of earthen dams and levees, and to prevent the leakage of fluids. It is also used as a component of foundry sand and as a desiccant to remove moisture from air and gases.

Montmorillonite clays have been extensively used in catalytic processes. Cracking catalysts have used montmorillonite clays for over 60 years. Other acid-based catalysts use acid-treated montmorillonite clays.[6]

Similar to many other clays, montmorillonite swells with the addition of water. Montmorillonites expand considerably more than other clays due to water penetrating the interlayer molecular spaces and concomitant adsorption. The amount of expansion is due largely to the type of exchangeable cation contained in the sample. The presence of sodium as the predominant exchangeable cation can result in the clay swelling to several times its original volume. Hence, sodium montmorillonite has come to be used as the major constituent in nonexplosive agents for splitting rock in natural stone quarries in an effort to limit the amount of waste, or for the demolition of concrete structures where the use of explosive charges is unacceptable.

This swelling property makes montmorillonite-containing bentonite useful also as an annular seal or plug for water wells and as a protective liner for landfills. Other uses include as an anticaking agent in animal feed, in papermaking to minimize deposit formation, and as a retention and drainage aid component. Montmorillonite has also been used in cosmetics.[7]

In a fine powder form, it can also be used as a flocculant in ponds. Tossed on the surface as it drops into the water, making the water "clouded", it attracts minute particles in the water and then settles to the bottom, cleaning the water. Koi and goldfish (carp) then actually feed on the "clump" which can aid in the digestion of the fish. It is sold in pond supply shops.

Sodium montmorillonite is also used as the base of some cat litter products, due to its adsorbent and clumping properties.

Calcined clay products

Montmorillonite can be calcined to produce arcillite, a porous material. This calcined clay is sold as a soil conditioner for playing fields and other soil products such as for use as bonsai soil as an alternative to akadama.

Medicine and pharmacology

Montmorillonite is effective as an adsorptive of heavy metals.[8]

For external use, montmorillonite has been used to treat contact dermatitis.[9]

Skin care and body care

Calcium Montmorillonite or nutrient-rich clay is effective for balancing ph levels on the skin and inside the body. Some types of Montmorillonite that come from California, United States, contain 57 beneficial trace minerals and are widely used in skin and body care products.[10]

Pet food

Montmorillonite clay is added to some dog and cat foods as an anti-caking agent and because it may provide some resistance to environmental toxins, though research on the subject is not yet conclusive.[11]

Discovery

Montmorillonite was first described in 1847 for an occurrence in Montmorillon in the department of Vienne, France,[3] more than 50 years before the discovery of bentonite in the US. It is found in many locations worldwide and known by other names. Recently, a new source of Montmorillonite has been explored in Sulaiman Mountains of Pakistan.

See also

• Dispersion (soil)
• Emulsion dispersion
• Sodification

References

1. "Mineralienatlas - Fossilienatlas". mineralienatlas.de. Archived from the original on 23 April 2018. Retrieved 23 April 2018.
2. Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1995). "Montmorillonite" (PDF). Handbook of Mineralogy. II (Silica, Silicates). Chantilly, VA, USA: Mineralogical Society of America. ISBN 0962209716. OCLC 895497384. Archived (PDF) from the original on 2012-02-05. Retrieved 2017-06-22.
3. Montmorillonite Archived 2012-05-24 at the Wayback Machine. Mindat.org
4. Montmorillonite Archived 2011-06-07 at the Wayback Machine. Webmineral
5. Hill, Carol; Paolo Forti (1997). "Deposition and Stability of asdSilicate Minerals". Cave Minerals of the World (Second ed.). National Speleological Society. p. 177. ISBN 1-879961-07-5.
6. Lloyd, Lawrie (2011). Handbook of Industrial Catalysts. New York: Springer. pp. 181–182. ISBN 978-0387246826.
7. Nirwan, J. S.; Farhaj, S.; Chaudhary, M. M.; Khizer, Z.; Hasan, S. S.; Angelis-Dimakis, A.; Gill, A.; Rasheed, H.; Abbas, N.; Arshad, M. S.; Hussain, T.; Shahzad, Y.; Yousaf, A. M.; Chohan, T. A.; Hussain, T.; Merchant, H. A.; Akram, M. R.; Khan, T. M.; Ashraf, M.; Conway, B. R.; Ghori, M. U. (17 January 2020). "Exploration of a New Source of Sustainable Nanomaterial from the Koh-e-Suleiman Mountain Range of Pakistan for Industrial Applications". Scientific Reports. 10 (1): 577. doi:10.1038/s41598-020-57511-y. PMC 6969096. PMID 31953500.
8. Bhattacharyya, Krishna Gopal; Gupta, Susmita Sen (August 2008). "Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review". Advances in Colloid and Interface Science. 140 (2): 114–131. doi:10.1016/j.cis.2007.12.008. PMID 18319190.
9. Saary, Joan; Qureshi, Roohi; Palda, Valerie; DeKoven, Joel; Pratt, Melanie; Skotnicki-Grant, Sandy; Holness, Linn (November 2005). "A systematic review of contact dermatitis treatment and prevention". Journal of the American Academy of Dermatology. 53 (5): 845.e1–845.e13. doi:10.1016/j.jaad.2005.04.075. PMID 16243136.
10. "Zion Health and Adama Minerals clay dry, natural, aluminium-free, sulfate-free, and paraben-free skincare products". Adama Minerals. Zion Health.
11. "Montmorillonite Clay Benefits, Uses in Cat / Dog Food, Structure & Properties". DurableHealth. Archived from the original on 4 November 2015. Retrieved 12 October 2015.

• Papke, Keith G. Montmorillonite, Bentonite and Fuller’s Earth Deposits in Nevada, Nevada Bureau of Mines Bulletin 76, Mackay School of Mines, University of Nevada-Reno, 1970.
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