Potassium selenate
Potassium selenate, K
2SeO
4, is an odorless, white solid that forms as the potassium salt of selenic acid. It is used in photography.
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ECHA InfoCard | 100.029.286 |
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Properties | |
K 2SeO 4 | |
Molar mass | 221.2 g/mol[1] |
Appearance | colorless crystals hygroscopic |
Odor | odorless |
Density | 3.07 g/cm3[2] |
1.07 g/ml (0 °C) 1.11 g/ml (20 °C) 1.22 g/ml (100 °C) | |
Refractive index (nD) |
1.539 |
Structure | |
orthorhombic | |
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NFPA 704 (fire diamond) | |
Related compounds | |
Other anions |
Potassium sulfate |
Other cations |
Sodium selenate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Preparation
Potassium selenate is produced by the reaction of selenium trioxide and potassium hydroxide.
- SeO3 + 2 KOH → K2SeO4 + H2O
Alternatively, it can be made by reacting selenous acid with potassium hydroxide, and then oxidizing the resulting potassium selenite with bromine.[3]
- H2SeO3 + 2 KOH → K2SeO3 + 2 H2O
- K2SeO3 + 2 KOH + Br2 → K2SeO4 + 2 KBr + H2O
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References
- "Potassium Selenate K2SeO4 Molecular Weight". EndMemo. Retrieved 2019-09-03.
- "Potassium Selenate". American Elements. Retrieved 2019-09-03.
- Rosenfeld, Irene; Beath, Orville A. (2013). Selenium: Geobotany, Biochemistry, Toxicity, and Nutrition. Elsevier Science. p. 305. ISBN 978-1-4832-7590-1.
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