Potassium silicate

Potassium silicate is the name for a family of inorganic compounds. The most common potassium silicate has the formula K₂SiO₃, samples of which contain varying amounts of water. These are white solids or colorless solutions.[1]

Potassium silicate

Names
Preferred IUPAC name Potassium metasilicate
Other names Liquid glass Waterglass
Identifiers
CAS Number	1312-76-1^Y
3D model (JSmol)	Interactive image
ChemSpider	59585^Y
ECHA InfoCard	100.029.989
EC Number	233-001-1
E number	E560 (acidity regulators, ...)
PubChem CID	66200
UNII	J86L1GUL6K^Y
CompTox Dashboard (EPA)	DTXSID20893092
InChI InChI=1S/2K.O3Si/c;;1-4(2)3/q2*+1;-2^Y Key: NNHHDJVEYQHLHG-UHFFFAOYSA-N^Y InChI=1/2K.O3Si/c;;1-4(2)3/q2*+1;-2 Key: NNHHDJVEYQHLHG-UHFFFAOYAP
SMILES [K+].[K+].[O-][Si]([O-])=O
Properties
Chemical formula	K2O3Si
Molar mass	154.279 g·mol^−1
Appearance	White crystals
Hazards
EU classification (DSD) (outdated)	Corrosive (C), Irritant (Xi)
R-phrases (outdated)	R34, R37
S-phrases (outdated)	(S1/2), S13, S24/25, S36/37/39, S45
NFPA 704 (fire diamond)	0 1 0
Related compounds
Other anions	Potassium carbonate Potassium germanate Potassium stannate Potassium plumbate
Other cations	Sodium silicate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is ^YN ?)
Infobox references

Synthesis, structure, reactions

Potassium silicate can be synthesized in the laboratory by treating silica with potassium hydroxide, according to this idealized equation:

${\displaystyle {\ce {{\mathit {n}}{SiO2}+2KOH->K2O.{\mathit {n}}{SiO2}+H2O}}}$

These solutions are highly alkaline. Addition of acids causes the reformation of silica.

K₂SiO₃ adopts a chain or cyclic structures with interlinked SiO₃²⁻ monomers. Each Si is tetrahedral.

Uses

Woodwork protection against fire

Impregnation of wood with a potassium silicate solution is an easy and low cost way for rendering the woodwork of houses secure against catching fire. The woodwork is first saturated with a diluted and nearly neutral solution of potash silicate. After drying, one or two coats of a more concentrated solution are usually applied.[2]

Horticulture

In horticulture, potassium silicate is used as a soluble source of potassium and silicon. It makes the growing medium more alkaline.

It is also used as a supplement (in conjunction with normal fertilizer) for the numerous benefits that increasing the availability of silicon compounds has. Silicon-containing compounds are valuable to a plant, and serve to support the plant. Stems thicken, the plant becomes more tolerant to drought and resists wilting, and the plant gets larger leaves and fruit (because the stem can support more weight).[3] The thicker cell walls of the plant also provides an added mechanical resistance to sap sucking insects (e.g. spider mite) and various pathogenic fungi (e.g. powdery mildew).

Industrial uses

Some metal cleaning formulations use potassium silicate, which also serves as a corrosion inhibitor.[4] It also finds various uses in the fabrication of welding rods or even of cosmetics.

Safety

Potassium silicate is strongly alkaline.

See also

• Sodium silicate

References

1. Gerard Lagaly, Werner Tufar, A. Minihan, A. Lovell "Silicates" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, 2005. doi:10.1002/14356007.a23_661
2. Cobleigh, Rolfe (1909). Handy farm devices and how to make them. Part II: Worth knowing to render wood fireproof. New York: Orange Judd.
3. S. Y. Wang & G. J. Galletta (1998) Foliar application of potassium silicate induces metabolic changes in strawberry plants, Journal of Plant Nutrition, 21:1, 157-167, doi:10.1080/01904169809365390
4. Elmore AR (2005). "Final report on the safety assessment of potassium silicate, sodium metasilicate, and sodium silicate". Int. J. Toxicol. 24 (Suppl 1): 103–17. doi:10.1080/10915810590918643. PMID 15981734.

External links