Isotopes of bromine
Bromine (35Br) has two stable isotopes, 79Br and 81Br, and 30 known radioisotopes, the most stable of which is 77Br, with a half-life of 57.036 hours.
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Standard atomic weight Ar, standard(Br) |
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List of isotopes
Nuclide [n 1] |
Z | N | Isotopic mass (Da) [n 2][n 3] |
Half-life |
Decay mode [n 4] |
Daughter isotope [n 5][n 6] |
Spin and parity [n 7][n 8] |
Natural abundance (mole fraction) | |
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Excitation energy | Normal proportion | Range of variation | |||||||
68Br[2] | 35 | 33 | 67.95836(28)# | ~50 ns | p | 67Se | 3+# | ||
69Br | 35 | 34 | 68.95011(11)# | <24 ns | p | 68Se | 1/2−# | ||
70Br | 35 | 35 | 69.94479(33)# | 79.1(8) ms | β+ | 70Se | 0+# | ||
70mBr | 2292.2(8) keV | 2.2(2) s | β+ | 70Se | (9+) | ||||
IT | 70Br | ||||||||
71Br | 35 | 36 | 70.93874(61) | 21.4(6) s | β+ | 71Se | (5/2)− | ||
72Br | 35 | 37 | 71.93664(6) | 78.6(24) s | β+ | 72Se | 1+ | ||
72mBr | 100.92(3) keV | 10.6(3) s | IT (>99.9%) | 72Br | 1− | ||||
β+ (<0.1%) | 72Se | ||||||||
73Br | 35 | 38 | 72.93169(5) | 3.4(2) min | β+ | 73Se | 1/2− | ||
74Br | 35 | 39 | 73.929891(16) | 25.4(3) min | β+ | 74Se | (0−) | ||
74mBr | 13.58(21) keV | 46(2) min | β+ | 74Se | 4(+#) | ||||
75Br | 35 | 40 | 74.925776(15) | 96.7(13) min | β+ | 75Se | 3/2− | ||
76Br | 35 | 41 | 75.924541(10) | 16.2(2) h | β+ | 76Se | 1− | ||
76mBr | 102.58(3) keV | 1.31(2) s | IT (99.4%) | 76Br | (4)+ | ||||
β+ (0.6%) | 76Se | ||||||||
77Br | 35 | 42 | 76.921379(3) | 57.036(6) h | β+ | 77Se | 3/2− | ||
77mBr | 105.86(8) keV | 4.28(10) min | IT | 77Br | 9/2+ | ||||
78Br | 35 | 43 | 77.921146(4) | 6.46(4) min | β+ (99.99%) | 78Se | 1+ | ||
β− (0.01%) | 78Kr | ||||||||
78mBr | 180.82(13) keV | 119.2(10) µs | (4+) | ||||||
79Br | 35 | 44 | 78.9183371(22) | Stable | 3/2− | 0.5069(7) | |||
79mBr | 207.61(9) keV | 4.86(4) s | IT | 79Br | (9/2+) | ||||
80Br | 35 | 45 | 79.9185293(22) | 17.68(2) min | β− (91.7%) | 80Kr | 1+ | ||
β+ (8.3%) | 80Se | ||||||||
80mBr | 85.843(4) keV | 4.4205(8) h | IT | 80Br | 5− | ||||
81Br | 35 | 46 | 80.9162906(21) | Stable | 3/2− | 0.4931(7) | |||
81mBr | 536.20(9) keV | 34.6(28) µs | 9/2+ | ||||||
82Br | 35 | 47 | 81.9168041(21) | 35.282(7) h | β− | 82Kr | 5− | ||
82mBr | 45.9492(10) keV | 6.13(5) min | IT | 82Br | 2− | ||||
β− | 82Kr | ||||||||
83Br | 35 | 48 | 82.915180(5) | 2.40(2) h | β− | 83Kr | 3/2− | ||
83mBr | 3068.8(6) keV | 700(100) ns | (19/2−) | ||||||
84Br | 35 | 49 | 83.916479(16) | 31.80(8) min | β− | 84Kr | 2− | ||
84m1Br | 320(10) keV | 6.0(2) min | β− | 84Kr | 6− | ||||
84m2Br | 408.2(4) keV | <140 ns | 1+ | ||||||
85Br | 35 | 50 | 84.915608(21) | 2.90(6) min | β− | 85Kr | 3/2− | ||
86Br | 35 | 51 | 85.918798(12) | 55.1(4) s | β− | 86Kr | (2−) | ||
87Br | 35 | 52 | 86.920711(19) | 55.65(13) s | β− (97.48%) | 87Kr | 3/2− | ||
β−, n (2.52%) | 86Kr | ||||||||
88Br | 35 | 53 | 87.92407(4) | 16.29(6) s | β− (93.42%) | 88Kr | (2−) | ||
β−, n (6.48%) | 87Kr | ||||||||
88mBr | 272.7(3) keV | 5.4(7) µs | |||||||
89Br | 35 | 54 | 88.92639(6) | 4.40(3) s | β− (86.2%) | 89Kr | (3/2−,5/2−) | ||
β−, n (13.8%) | 88Kr | ||||||||
90Br | 35 | 55 | 89.93063(8) | 1.91(1) s | β− (74.8%) | 90Kr | |||
β−, n (25.2%) | 89Kr | ||||||||
91Br | 35 | 56 | 90.93397(8) | 541(5) ms | β− (80%) | 91Kr | 3/2−# | ||
β−, n (20%) | 90Kr | ||||||||
92Br | 35 | 57 | 91.93926(5) | 0.343(15) s | β− (66.9%) | 92Kr | (2−) | ||
β−, n (33.1%) | 91Kr | ||||||||
93Br | 35 | 58 | 92.94305(32)# | 102(10) ms | β− (89%) | 93Kr | 3/2−# | ||
β−, n (11%) | 92Kr | ||||||||
94Br | 35 | 59 | 93.94868(43)# | 70(20) ms | β− (70%) | 94Kr | |||
β−, n (30%) | 93Kr | ||||||||
95Br | 35 | 60 | 94.95287(54)# | 50# ms [>300 ns] | 3/2−# | ||||
96Br | 35 | 61 | 95.95853(75)# | 20# ms [>300 ns] | |||||
97Br | 35 | 62 | 96.96280(86)# | 10# ms [>300 ns] | 3/2−# |
- mBr – Excited nuclear isomer.
- ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
-
Modes of decay:
IT: Isomeric transition n: Neutron emission p: Proton emission - Bold italics symbol as daughter – Daughter product is nearly stable.
- Bold symbol as daughter – Daughter product is stable.
- ( ) spin value – Indicates spin with weak assignment arguments.
- # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
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References
- Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- Wimmer, K.; et al. (2019). "Discovery of 68Br in secondary reactions of radioactive beams". Physics Letters B. 795: 266–270. arXiv:1906.04067. doi:10.1016/j.physletb.2019.06.014.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.
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