Galvanization

Galvanization or galvanizing (also spelled galvanisation or galvanising)[1] is the process of applying a protective zinc coating to steel or iron, to prevent rusting. The most common method is hot-dip galvanizing, in which the parts are submerged in a bath of molten hot zinc.

"Galvanize" and "Galvanized" redirect here. For other uses, see Galvanize (disambiguation).
Not to be confused with Galvanism or Electrogalvanization.
A street lamp in Singapore showing the characteristic spangle of hot-dip galvanization

Protective action

Galvanizing protects the underlying iron or steel in the following main ways:

  • The zinc coating, when intact, prevents corrosive substances from reaching the underlying steel or iron.
  • The zinc protects iron by corroding first. For better results, application of chromates over zinc is also seen as an industrial trend.
  • In the event the underlying metal becomes exposed, protection can continue as long as there is zinc close enough to be electrically coupled. After all of the zinc in the immediate area is consumed, localized corrosion of the base metal can occur.

History and etymology
Galvanized nails

The earliest known example of galvanized iron was encountered by Europeans on 17th-century Indian armour in the Royal Armouries Museum collection.[2]

The etymology of galvanisation is via French from the name of Italian scientist Luigi Galvani. However this is an obscure back-formation; Galvani had no involvement in zinc coating.

The earliest use of the term was in late 18th-century scientific research and medical practice by Galvani and meant the stimulation of a muscle by the application of an electric current. Although Galvani was the first to study this, it was Alessandro Volta who then developed a better understanding of its cause and effect. Galvani's explanation of 'animal electricity' as a cause was replaced by Volta's invention of the electric battery and its use to stimulate animal tissue. Despite the superseding of his experimental results, it was Galvani's name rather than Volta's which became associated with the field.

The term "galvanized" continues to be used metaphorically of any stimulus which results in activity by a person or group of people[3], such as to "galvanize into action" meaning stimulating a complacent person or group to take action.

In modern usage, the term "galvanizing" has largely come to be associated with zinc coatings, to the exclusion of other metals. Galvanic paint, a precursor to hot-dip galvanizing, was patented by Stanislas Sorel, of Paris, in December 1837, as an adoption of a term from a highly fashionable field of contemporary science, despite having no evident relation to it.[4]

Methods

Hot-dip galvanizing deposits a thick, robust layer of zinc iron alloys on the surface of a steel item. In the case of automobile bodies, where additional decorative coatings of paint will be applied, a thinner form of galvanizing is applied by electrogalvanizing. The hot-dip process generally does not reduce strength on a measurable scale, with the exception of high-strength steels (>1100 MPa) where hydrogen embrittlement can become a problem.[5] This deficiency is a consideration affecting the manufacture of wire rope and other highly stressed products.

The protection provided by hot-dip galvanizing is insufficient for products that will be constantly exposed to corrosive materials such as acids, including acid rain in outdoor uses. For these applications, more expensive stainless steel is preferred. Some nails made today are galvanized. Nonetheless, electroplating is used on its own for many outdoor applications because it is cheaper than hot-dip zinc coating and looks good when new. Another reason not to use hot-dip zinc coating is that for bolts and nuts of size M10 (US 3/8") or smaller, the thick hot-dipped coating fills in too much of the threads, which reduces strength (because the dimension of the steel prior to coating must be reduced for the fasteners to fit together). This means that for cars, bicycles, and many other light mechanical products, the practical alternative to electroplating bolts and nuts is not hot-dip zinc coating, but making the fasteners from stainless steel or titanium.

Galvanized surface with visible spangle

The size of crystallites (grains) in galvanized coatings is a visible and aesthetic feature, known as "spangle". By varying the number of particles added for heterogeneous nucleation and the rate of cooling in a hot-dip process, the spangle can be adjusted from an apparently uniform surface (crystallites too small to see with the naked eye) to grains several centimetres wide. Visible crystallites are rare in other engineering materials, even though they are usually present.

Thermal diffusion galvanizing, or Sherardizing, provides a zinc diffusion coating on iron- or copper-based materials.[6][7] Parts and zinc powder are tumbled in a sealed rotating drum. Around 300 °C (572 °F), zinc will diffuse into the substrate to form a zinc alloy. The advance surface preparation of the goods can be carried out by shot blasting. The process is also known as "dry galvanizing", because no liquids are involved; this can avoid possible problems caused by hydrogen embrittlement. The dull-grey crystal structure of the zinc diffusion coating has a good adhesion to paint, powder coatings, or rubber. It is a preferred method for coating small, complex-shaped metals, and for smoothing rough surfaces on items formed with sintered metal.

Eventual corrosion
Rusted corrugated steel roof

Although galvanizing will inhibit attack of the underlying steel, rusting will be inevitable after some decades' exposure to weather, especially if exposed to acidic conditions. For example, corrugated iron sheet roofing will start to degrade within a few years despite the protective action of the zinc coating. Marine and salty environments also lower the lifetime of galvanized iron because the high electrical conductivity of sea water increases the rate of corrosion, primarily through converting the solid zinc to soluble zinc chloride which simply washes away. Galvanized car frames exemplify this; they corrode much faster in cold environments due to road salt, though they will last longer than unprotected steel.

Galvanized steel can last for many decades if other supplementary measures are maintained, such as paint coatings and additional sacrificial anodes. The rate of corrosion in non-salty environments is caused mainly by levels of sulfur dioxide in the air.[8] In the most benign natural environments, such as inland low population areas, galvanized steel can last without rust for over 100 years.

Galvanized construction steel

This is the most common use for galvanized metal, and hundreds of thousands of tons of steel products are galvanized annually worldwide. In developed countries most larger cities have several galvanizing factories, and many items of steel manufacture are galvanized for protection. Typically these include: street furniture, building frameworks, balconies, verandahs, staircases, ladders, walkways, and more. Hot dip galvanized steel is also used for making steel frames as a basic construction material for steel frame buildings.

Galvanized piping
See also: Galvanic corrosion, Pipe (fluid conveyance), and Piping

In the early 20th century, galvanized piping replaced previously-used cast iron and lead in cold-water plumbing. Typically, galvanized piping rusts from the inside out, building up layers of plaque on the inside of the piping, causing both water pressure problems and eventual pipe failure. These plaques can flake off, leading to visible impurities in water and a slight metallic taste. The life expectancy of galvanized piping is about 70 years, but it may vary by region due to impurities in the water supply and the proximity of electrical grids for which interior piping acts as a pathway (the flow of electricity can accelerate chemical corrosion). Pipe longevity also depends on the thickness of zinc in the original galvanizing, which ranges on a scale from G40 to G210, and whether the pipe was galvanized on both the inside and outside, or just the outside.

Since World War 2, copper and plastic piping have replaced galvanized piping for interior drinking water service, but galvanized steel pipes are still used in outdoor applications requiring steel's superior mechanical strength. The use of galvanized pipes lends some truth to the urban myth that water purity in outdoor water faucets is lower, but the actual impurities (iron, zinc, calcium) are harmless.

The presence of galvanized piping detracts from the appraised value of housing stock because piping can fail, increasing the risk of water damage. Galvanized piping will eventually need to be replaced if housing stock is to outlast a 50 to 70 year life expectancy, and some jurisdictions require galvanized piping to be replaced before sale. One option to extend the life expectancy of existing galvanized piping is to line it with an epoxy resin.

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See also

References
  1. "Galvanize". Cambridge English Dictionary. Retrieved 10 November 2019.
  2. Summary of XRF analysis conducted on or about 30 September 1999 by the Royal Armouries Museum in Leeds and written up as part of a thesis by Helen Bowstead Stallybrass at the Department of Archaeological Sciences, Bradford University.
  3. James A. H. Murray; et al., eds. (1989). The Oxford English Dictionary. VI (2 ed.). Oxford University Press. p. 340. ISBN 0 19 861218-4.
  4. Process for protecting articles made of Iron or Steel from oxidation." Specification of patent granted to M. Sorel, of Paris, France, December, 1837. Journal of the Franklin Institute (Philadelphia, Pa.), Published by Pergamon Press, 1838, via Google Book Search.
  5. "Steel Selection". American Galvanizers Association. Retrieved 3 April 2015.
  6. Porter, Frank C. (1991). Zinc Handbook. CRC Press. ISBN 978-0-8247-8340-2.
  7. Natrup, F.; Graf, W. (21 November 2014). "20 - Sherardizing: corrosion protection of steels by zinc diffusion coatings". In Mittemeijer, Eric J.; Somers, Marcel A. J. (eds.). Thermochemical Surface Engineering of Steels: Improving Materials Performance. Elsevier Science. p. 737. ISBN 978-0-85709-652-4.
  8. "Atmospheric Resistance". Galvanising Association (UK). Archived from the original on 2014-02-22.
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