Bisphenol

The bisphenols (/ˈbɪsfɪnɒl/) are a group of chemical compounds with two hydroxyphenyl functionalities. Most of them are based on diphenylmethane. The exceptions are bisphenol S, P, and M. "Bisphenol" is a common name; the letter following refers to one of the reactants. Bisphenol A is the most popular representative of this group, often simply called "bisphenol."[1]

List

Structural formula Name CAS Reactants
Bisphenol A80-05-7PhenolAcetone
Bisphenol AP1571-75-1PhenolAcetophenone
Bisphenol AF1478-61-1PhenolHexafluoroacetone
Bisphenol B77-40-7PhenolButanone
Bisphenol BP1844-01-5PhenolBenzophenone
Bisphenol C79-97-0o-cresolAcetone
Bisphenol C 214868-03-2PhenolChloral
Bisphenol E2081-08-5 PhenolEthanal
Bisphenol F620-92-8PhenolFormaldehyde
Bisphenol G127-54-82-IsopropylphenolAcetone
Bisphenol M13595-25-0
Bisphenol S80-09-1PhenolSulfur trioxide
Bisphenol P2167-51-3
Bisphenol PH24038-68-42-PhenylphenolAcetone
Bisphenol TMC129188-99-4Phenol3,3,5-Trimethylcyclohexanone
Bisphenol Z843-55-0PhenolCyclohexanone
Dinitrobisphenol A5329-21-5Bisphenol ANitric acid
Tetrabromobisphenol A79-94-7Bisphenol ABromine

Health effects

Bisphenols A (BPA) and S (BPS) have been shown to be endocrine disruptors.[2][3] Due to its high production volumes, BPA has been characterised as a "pseudo-persistent" chemical,[4] leading to its spreading and potential accumulation in a variety of environmental matrices, even though it has a fairly short half-life.[5]

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References

  1. Helmut Fiege, Heinz-Werner Voges, Toshikazu Hamamoto, Sumio Umemura, Tadao Iwata, Hisaya Miki, Yasuhiro Fujita, Hans-Josef Buysch, Dorothea Garbe, Wilfried Paulus (2002). "Phenol Derivatives". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_313. ISBN 978-3527306732.CS1 maint: uses authors parameter (link).
  2. "BPA-Free Plastic Containers May Be Just as Hazardous". Scientific American. Retrieved 8 August 2015.
  3. "Bisphenol A (BPA) & Bisphenol S (BPS)". SaferChemicals.org. Retrieved 8 August 2015.
  4. Pivnenko, K.; Pedersen, G. A.; Eriksson, E.; Astrup, T. F. (2015-10-01). "Bisphenol A and its structural analogues in household waste paper". Waste Management. 44: 39–47. doi:10.1016/j.wasman.2015.07.017. PMID 26194879.
  5. See Bisphenol A#Environmental effects for extensive discussion
  • For additional examples and alternate names, see: Alger, Mark (2017). Polymer Science Dictionary. Springer. p. 77. ISBN 9789402408935.
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