(S)-beta-macrocarpene synthase
(S)-beta-macrocarpene synthase (EC 5.5.1.17, TPS6, TPS11) is an enzyme with systematic name (S)-beta-macrocarpene lyase (decyclizing).[1] This enzyme catalyses the following chemical reaction
- (S)-beta-bisabolene (S)-beta-macrocarpene
| (S)-beta-macrocarpene synthase | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifiers | |||||||||
| EC number | 5.5.1.17 | ||||||||
| Databases | |||||||||
| IntEnz | IntEnz view | ||||||||
| BRENDA | BRENDA entry | ||||||||
| ExPASy | NiceZyme view | ||||||||
| KEGG | KEGG entry | ||||||||
| MetaCyc | metabolic pathway | ||||||||
| PRIAM | profile | ||||||||
| PDB structures | RCSB PDB PDBe PDBsum | ||||||||
| |||||||||
The synthesis of (S)-beta-macrocarpene from (2E,6E)-farnesyl diphosphate proceeds in two steps.
References
- Köllner TG, Schnee C, Li S, Svatos A, Schneider B, Gershenzon J, Degenhardt J (July 2008). "Protonation of a neutral (S)-beta-bisabolene intermediate is involved in (S)-beta-macrocarpene formation by the maize sesquiterpene synthases TPS6 and TPS11". The Journal of Biological Chemistry. 283 (30): 20779–88. doi:10.1074/jbc.m802682200. PMC 3258946. PMID 18524777.
External links
- (S)-beta-macrocarpene+synthase at the US National Library of Medicine Medical Subject Headings (MeSH)
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