S-linalool synthase
In enzymology, a S-linalool synthase (EC 4.2.3.25) is an enzyme that catalyzes the chemical reaction
- geranyl diphosphate + H2O (3S)-linalool + diphosphate
| S-linalool synthase | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifiers | |||||||||
| EC number | 4.2.3.25 | ||||||||
| Databases | |||||||||
| IntEnz | IntEnz view | ||||||||
| BRENDA | BRENDA entry | ||||||||
| ExPASy | NiceZyme view | ||||||||
| KEGG | KEGG entry | ||||||||
| MetaCyc | metabolic pathway | ||||||||
| PRIAM | profile | ||||||||
| PDB structures | RCSB PDB PDBe PDBsum | ||||||||
| |||||||||
Thus, the two substrates of this enzyme are geranyl diphosphate and H2O, whereas its two products are (3S)-linalool and diphosphate.
This enzyme belongs to the family of lyases, specifically those carbon-oxygen lyases acting on phosphates. The systematic name of this enzyme class is geranyl-diphosphate diphosphate-lyase [(3S)-linalool-forming]. Other names in common use include LIS, Lis, and 3S-linalool synthase.
References
- Pichersky E, Lewinsohn E, Croteau R (1995). "Purification and characterization of S-linalool synthase, an enzyme involved in the production of floral scent in Clarkia breweri". Arch. Biochem. Biophys. 316 (2): 803–7. doi:10.1006/abbi.1995.1107. PMID 7864636.
- Luecker J; Bouwmeester, HJ; Schwab, W; Blaas, J; Van Der Plas, LH; Verhoeven, HA (2001). "Expression of Clarkia S-linalool synthase in transgenic petunia plants results in the accumulation of S-linalyl-beta-D-glucopyranoside". Plant J. 27 (4): 315–24. doi:10.1046/j.1365-313x.2001.01097.x. PMID 11532177.
- Dudareva N, Cseke L, Blanc VM, Pichersky E (1996). "Evolution of floral scent in Clarkia: novel patterns of S-linalool synthase gene expression in the C. breweri flower". Plant Cell. 8 (7): 1137–48. doi:10.1105/tpc.8.7.1137. PMC 161191. PMID 8768373.
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