White liquor

White liquor is a strongly alkaline solution mainly of sodium hydroxide and sodium sulfide. It is used in the first stage of the Kraft process in which lignin and hemicellulose are separated from cellulose fiber for the production of pulp.[1] The white liquor breaks the bonds between lignin and cellulose. It is called white liquor due to its white opaque colour.

For home-made high-proof distilled spirits also known as white liquor, see moonshine.

Composition

White liquor consists mainly of sodium hydroxide and sodium sulfide in water and is the active component in Kraft pulping.[1] White liquor also contains minor amounts of sodium carbonate, sodium sulfate, sodium thiosulfate, sodium chloride, calcium carbonate and other accumulated salts and non-process elements. These additional components are considered inert in the Kraft process, except sodium carbonate that contributes to a lesser extent.

The chemical composition and properties of the white liquor are calculated as total alkali, active alkali, effective alkali, sulfidity, causticity and reduction.

Total alkali All Na− compounds
Active alkali (AA) NaOH + Na2S g NaOH equivalents, or % on dry wood
Effective alkali (EA) NaOH + ½ Na2S g NaOH equivalents, or % on dry wood
Sulfidity Na2S / AA %
Causticity NaOH / (NaOH + Na2CO3) %
Reduction Na2S / (Na2S + Na2SO4) %

Application
Main article: Kraft process

The Kraft cooking liquor (white) is used to extract the lignin and break down the cellulose composition of wood chips into usable pulp. The white (cooking) liquor becomes black liquor and is sent to the recovery process.

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See also
  • Pulp & Paper chemicals

References
  1. Gullichsen, Johan; Carl-Johan Fogelholm (2000). Papermaking science and Technology: 6A. Chemical Pulping. Finland: Tappi Press. pp. 41–42. ISBN 952-5216-06-3.
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