Vanadium(V) oxytrifluoride

Vanadium(V) oxytrifluoride is a chemical compound with the formula VOF3. It is one of several vanadium(V) oxyhalides. VOF3 is a yellowish orange powder that is sensitive to moisture.[1] Characteristic of early metal fluorides, the structure is polymeric in the solid state. The solid adopts a layered structure but upon evaporation, the species becomes dimeric. In contrast VOCl3 and VOBr3 remain tetrahedral in all states, being volatile liquids at room temperature.[2]

Vanadium(V) oxytrifluoride
Names
Other names
Vanadium oxyfluoride, trifluorooxovanadium
Identifiers
ECHA InfoCard 100.033.849
Properties
F3OV
Molar mass 123.9599 g/mol
Appearance yellowish orange powder
Density 2.4590 g/cm3
Melting point 300 °C (572 °F; 573 K)
Boiling point 480 °C (896 °F; 753 K)
insoluble
Hazards
not listed
NFPA 704 (fire diamond)
Flammability (red): no hazard codeHealth code 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasReactivity (yellow): no hazard codeSpecial hazards (white): no code
3
Related compounds
Related compounds
VF5
VOCl3
VO2F
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

In organic synthesis, VOF3 is often used for the oxidative coupling of phenolic rings, for example in the syntheses of vancomycin and its analogues.[3] For these applications VOF3 is typically dissolved in trifluoroacetic acid.

References

  1. Perry, Dale L. (2011). Handbook of Inorganic Compounds. CRC Press. ISBN 978-1-4398-1461-1.
  2. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
  3. Vanasse, Benoit; O'Brien, Michael K. (2001). "Vanadyl Trifluoride". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rv005. ISBN 0471936235.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.