Nevil Sidgwick

Nevil Vincent Sidgwick FRS[1] (8 May 1873 – 15 March 1952) was an English theoretical chemist who made significant contributions to the theory of valency and chemical bonding.[2][3]

Nevil Sidgwick
Born8 May 1873
Oxford, England
Died15 March 1952 (1952-03-16) (aged 78)
Oxford, England
NationalityEnglish
Alma materChrist Church, Oxford, University of Tübingen
Known forvalency
AwardsRoyal Medal (1937)
Longstaff Prize (1945)
Fellow of the Royal Society[1]
Scientific career
FieldsChemistry
InstitutionsUniversity of Oxford
Doctoral advisorHans von Pechmann (University of Tübingen)

After a few years at Rugby School, Sidgwick pursued undergraduate studies at Christ Church, Oxford, and a doctorate at the University of Tübingen.[4] He received the MA from Lincoln College, Oxford, in October 1901,[5] and spent almost his entire career in the city of his birth, becoming a Fellow of the college in 1901, and Professor of Chemistry from 1935 to 1945.[6]

Sidgwick became absorbed by the study of atomic structure and its importance in chemical bonding. He explained the bonding in coordination compounds (complexes), with a convincing account of the significance of the dative bond. Together with his students he demonstrated the existence and wide-ranging importance of the hydrogen bond.

In 1927, he proposed the inert pair effect which describes the stability of heavier p-block atoms in an oxidation state two less than the maximum. In 1940 his Bakerian lecture with Herbert Marcus Powell correlated molecular geometry with the number of valence electrons on a central atom.[7] These ideas were later developed into the VSEPR theory by Gillespie and Nyholm.

His works include The Organic Chemistry of Nitrogen (1910), The Electronic Theory of Valency (1927), Some Physical Properties of the Covalent Link in Chemistry (1933), and the definitive The Chemical Elements and their Compounds (1950).

He was made a Fellow of the Royal Society in 1922[1] and died in Oxford on 15 March 1952.

Appointments Include:
Baker Lecturer at Cornell University, Ithaca, NY, USA]] (1931)
President of the Faraday Society (1932-1934)
Vice President of the Royal Society (1935-1937)
President of the Chemical Society (1935-1937)

The Sidgwick Laboratory in the Dyson Perrins Laboratory for organic chemistry and Sidgwick Close in front of the Inorganic Chemistry Laboratory at the University of Oxford were named after him.[8]

References
  1. Tizard, H. T. (1954). "Nevil Vincent Sidgwick. 1873-1952". Obituary Notices of Fellows of the Royal Society. 9: 236. doi:10.1098/rsbm.1954.0016. JSTOR 769209.
  2. Sidgwick, N. V. (1937). "Molecules". Science. 86 (2233): 335–340. doi:10.1126/science.86.2233.335. PMID 17751230.
  3. Sidgwick, N. V. (1931). "The Relation of Physics to Chemistry". Science. 73 (1889): 269–276. doi:10.1126/science.73.1889.269. PMID 17756018.
  4. "Genealogy Database Entry: Sidgwick, Nevil Vincent" (PDF). Genealogy Database. University of Illinois. Archived from the original (PDF) on June 12, 2010. Retrieved January 25, 2012.
  5. "University intelligence". The Times (36589). London. 18 October 1901. p. 4.
  6. "Nevil Vincent Sidgwick (1873 – 1952)". Famous Alumni. Lincoln College, Oxford. Retrieved January 25, 2012.
  7. Sidgwick, N. V.; Powell, H. M. (1940). "Bakerian Lecture. Stereochemical Types and Valency Groups". Proceedings of the Royal Society of London. 176 (965): 153–180. doi:10.1098/rspa.1940.0084.
  8. Oxford FAQ
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