Baddeleyite
Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. See etymology below.
| Baddeleyite | |
|---|---|
 Baddeleyite from Phalaborwa, South Africa | |
| General | |
| Category | Oxide mineral |
| Formula (repeating unit) | Zirconium dioxide (ZrO2) |
| Strunz classification | 4.DE.35 |
| Dana classification | 04.04.14.01 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | P21/c |
| Unit cell | a = 5.1505 Å, b = 5.2116 Å, c = 5.3173 Å, β = 99.23°; Z = 4 |
| Identification | |
| Color | Colorless to yellow, green, greenish or reddish brown, brown, iron-black |
| Crystal habit | Tabular prismatic, radially fibrous in botryoidal masses |
| Twinning | Ubiquitous polysynthetic on {100} and {110} |
| Cleavage | {001} distinct |
| Fracture | Irregular uneven to subconchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 6.5 |
| Luster | Greasy to vitreous |
| Streak | White |
| Diaphaneity | Transparent to translucent |
| Specific gravity | 5.5–6 |
| Optical properties | Biaxial (–) |
| Refractive index | nα = 2.130 nβ = 2.190 nγ = 2.200 |
| Birefringence | δ = 0.070 |
| Pleochroism | X = yellow, reddish brown, oil-green; Y = oil-green, reddish brown; Z = brown, light brown |
| 2V angle | Measured: 30° to 31° |
| Dispersion | r > v, rather strong |
| Other characteristics | Blue-green cathodoluminescence |
| References | [1][2][3] |
Baddeleyite is a refractory mineral, with a melting point of 2700 °C. Hafnium is a substituting impurity and may be present in quantities ranging from 0.1 to several percent.
It can be found in igneous rocks containing potassium feldspar and plagioclase. Baddeleyite is commonly not found with zircon (ZrSiO4), because it forms in silica-undersaturated rocks, such as mafic rocks. This is because, when silica is free in the system (silica-saturated/oversaturated), zircon is the dominating phase, not baddeleyite. It belongs to the monoclinic-prismatic class, of the P21/c crystal system. It has been used for geochronology.[4]
Geologic occurrence
Baddeleyite was first found in Sri Lanka in 1892. It can be found in numerous terrestrial and extraterrestrial rocks. Some of these terrestrial rocks are carbonatite, kimberlite, alkaline syenite, some rocks of layered mafic intrusions, diabase dikes, gabbroid sills and anorthosite.[4] Some examples of extraterrestrial rocks are tektites, meteorites and lunar basalt. Studies have shown that zircon and baddeleyite can be recovered from some anorthositic rocks in Proterozoic anorthosite complexes.[5] Places where these Proterozoic anorthosite complexes can be found are: the Laramie Anorthosite Complex in Wyoming, the Nain and Grenville provinces of Canada, the Vico Volcanic Complex in Italy,[6] and Minas Gerais and Jacupiranga, São Paulo, Brazil. Baddeleyite forms in igneous rocks low in silica, it can be found in rocks containing potassium feldspar and plagioclase. It has been observed in thin section that baddeleyite forms within plagioclase grains. Associated minerals include ilmenite, zirkelite, apatite, magnetite, perovskite, fluorite, nepheline, pyrochlore and allanite.[1]
Because of their refractory nature and stability under diverse conditions, baddeleyite grains, along with zircon, are used for uranium-lead radiometric age determinations.
Structure
There has been some dispute in the structure of baddeleyite. Originally, the mineral was assigned to the 8-fold coordination by Naray Szabo. This structure was ruled out due to the inaccuracy of the data used to establish it.
Baddeleyite has the group symmetry P21/c with four ZrO2 in the unit cell. It has unit cell dimensions of: a = 5.169 b = 5.232 c = 5.341 Å (all ± 0.008 Å), β = 99˚15ˊ ± 10ˊ.
The coordination number for ZrO2 has been found to be 7. The mineral has two types of separations. The first being the seven shortest Zr-O, ranging from 2.04 to 2.26 Å, and the second Zr-O separation is 3.77 Å. Because of this, the coordination of baddeleyite was determined to be sevenfold. Baddeleyite's structure is a combination of tetrahedrally coordinated oxide ions parallel to (100) with triangular coordinated oxide ions. This explains baddeleyite's tendency to twin along the (100) planes. It has been observed that baddeleyite without twinning is extremely rare.[8]
Composition
Baddeleyite belongs to the oxide group, having a composition of ZrO2. Similar minerals belonging to the same group are the rutile group: rutile (TiO2), pyrolusite (MnO2), cassiterite (SnO2), uraninite (UO2) and thorianite (ThO2). Baddeleyite is chemically homogeneous, but it may contain impurities such as Ti, Hf, and Fe.[9] Higher concentrations of Ti and Fe are restricted to mafic-ultramafic rocks.
Physical properties
Baddeleyite is black in color with a submetallic lustre. It has a 6.5 hardness, and a brownish-white streak. Baddeleyite can also be brown, brownish black, green, and greenish brown. Its streak is white, or brownish white. It has a distinct cleavage along {001} and tends to twin along (100). It belongs to the monoclinic system and is part of the P21/c group.[10]
Origin of the name
It was named for Joseph Baddeley. The mineral was discovered in Rakwana, Ceylon, now known as Sri Lanka. Baddeley was a superintendent of a railroad project in Rakwana. As redacted by J. J. H. Teall, Director of the British Geological Survey in the early 1900s, Baddeleyite was discovered thanks to the discovery of Geikielite. Baddeley happened to send specimens of several pebbles to the Museum of Practical Geology in London, where Mr. Pringle examined them and attempted to classify them. According to Teall, the specimens were submitted to him by Pringle after he failed to assign them and compare them to other species, such as spinel, ilmenite, and so on. After analyzing the specimens, Teall concluded that the mineral was mainly composed of titanic acid and magnesia, with a very small percentage of protoxide of iron. Geikielite has the composition of MgTiO3. Concluding the various analyses, Teall and Pringle decided to name the new mineral Geikielite, taking the name after the Director General of the Geological Survey, Sir Archibald Geikie. Baddeley then decided to send more specimens to Teall in order to determine a proper specimen to be put in display at the Museum of Practical Geology. While trying to find the best specimen for display, as Teall relates, he noticed that one of the specimens was different from the rest. This new mineral as described was black in color, with a submetallic lustre and a hardness of 6.5. After analyzing the mineral, it was determined that its composition was not MgTiO3, as geikielite's, but it was ZrO2. Teall proposed that the new mineral should be named baddeleyite, after Joseph Baddeley to honor the man who brought two new minerals to notice.[10]
References
- Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Baddeleyite". Handbook of Mineralogy (PDF). III (Halides, Hydroxides, Oxides). Chantilly, VA, US: Mineralogical Society of America. ISBN 0962209724. Retrieved December 5, 2011.
- Baddeleyite. Webmineral
- Baddeleyite. Mindat
- Bayanova, T.B. (2006). "Baddeleyite: A promising geochronometer for alkaline and basic magmatism". Petrology. 14 (2): 187. doi:10.1134/S0869591106020032.
- Scoates, James & Kevin Chamberlain (1995). "Baddeleyite (ZrOr) and zircon (ZrSiO) from anorthositic rocks of the Laramie anorthosite complex, Wyoming: Petrologic consequences and U-Pb ages" (PDF). American Mineralogist. 80: 1317–1327. Bibcode:1995AmMin..80.1317S. doi:10.2138/am-1995-11-1222.
- Bellatreccia, Fabio; Giancarlo Della Ventura; Gian Carlo Parodi & Terry Williams (1998). "Baddeleyite from the vico volcanic complex, latium Italy" (PDF). Rendiconti Lincei. 9: 27. doi:10.1007/BF02904453. Archived from the original (PDF) on 2007-12-12.
- Drabińska, A.; Grodecki, K.; Strupiński, W.; Bożek, R.; Korona, K. P.; Wysmołek, A.; Stępniewski, R.; Baranowski, J. M. (2010). "Growth kinetics of epitaxial graphene on SiC substrates". Physical Review B. 81 (24): 245410. Bibcode:2010PhRvB..81x5410D. doi:10.1103/PhysRevB.81.245410.
- McCullough, J. D. & Trueblood, K. N. (1959). "The crystal structure of baddeleyite (monoclinic ZrO2)". Acta Crystallographica. 12 (7): 507. doi:10.1107/S0365110X59001530.
- Lumpkin, G.R. (1999). "Physical and chemical characteristics of baddeleyite (monoclinic zirconia) in natural environments: An overview and case study". Journal of Nuclear Materials. 274: 206. Bibcode:1999JNuM..274..206L. doi:10.1016/S0022-3115(99)00066-5.
- Fletcher, L. (1892). "On Baddeleyite (native zirconia), a new Mineral, from Rakwana, Ceylon" (PDF). Mineralogy Magazine and Journal of the Mineralogical Society: 149–161.