I too had this question. In my research I found that CentOS keeps the ldap configuration file in /etc/raddb/modules/ldap.
In my setup I am using PEAP so my LDAP server stores LM hashes. A short mention of how to set this up is here: http://vuksan.com/linux/dot1x/802-1x-LDAP.html#PEAP_with_OpenLDAP
Once I found the ldap config file and read through everything in that file, setup was fairly simple. The only tough part that I ran into was having to use the sambaLMPassword but that was easily over come with a little googling.
Edit: This link: Setting up RADIUS + LDAP for WPA2 on Ubuntu also helped out a ton on getting everything working.