Captain Avatar and The Avateers/YMMV

Adorkable: Every scene with Kuei.
Jerkass Woobie: Zhao has moments, but mostly he's just the Butt Monkey
Tear Jerker: Zuko collapsing in front of Jee's door when he's sick, so much. And Sokka and Katara's Mom's death. Also, when Sokka uses Heart on Azula.
Woobie: Just about everybody gets this treatment, but Zuko especially.

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