Wilhelm Ostwald

Friedrich Wilhelm Ostwald (2 September [O.S. 21 August] 1853 – 4 April 1932) was a Baltic German chemist and philosopher. He received the Nobel Prize in Chemistry in 1909 for his scientific contributions to the fields of catalysis, chemical equilibria and reaction velocities.[1] Ostwald, Jacobus Henricus van 't Hoff, Walther Nernst, and Svante Arrhenius are credited with being the founders of the field of physical chemistry.[2]

Wilhelm Ostwald
Wilhelm Ostwald by Nicola Perscheid
Born2 September [O.S. 21 August] 1853
Died4 April 1932(1932-04-04) (aged 78)
Großbothen, Amtshauptmannschaft Grimma, Saxony, Weimar Republic
NationalityBaltic German
Alma materImperial University of Dorpat
Known forCatalysis
Coining the term 'Mole'
HSL and HSV
Liesegang rings
Ostwald dilution law
Ostwald process
Ostwald ripening
Ostwald's rule
Ostwald viscometer
Ostwald-Folin Pipette
Ostwald–Freundlich equation
AwardsFaraday Lectureship Prize (1904)
Nobel Prize for Chemistry (1909)
Scientific career
FieldsPhysical chemistry
InstitutionsImperial University of Dorpat
Riga Polytechnical Institution
Leipzig University
Doctoral advisorCarl Schmidt
Doctoral studentsArthur Amos Noyes
Georg Bredig
Paul Walden
Frederick George Donnan

Following his 1906 retirement from academic life, Ostwald became much involved in philosophy, art, and politics. He made significant contributions to each of these fields.[3] Ostwald has been described as a polymath.[4]

Early life and education

Ostwald was born ethnically Baltic German in Riga, to master-cooper Gottfried Wilhelm Ostwald (1824–1903) and Elisabeth Leuckel (1824–1903). He was the middle child of three, born after Eugen (1851–1932) and before Gottfried (1855–1918).[5] Ostwald developed an interest in science as a child and conducted experiments at his home, particularly related to fireworks and photography.[4]

Ostwald graduated from the University of Dorpat, Estonia, (now Tartu) in 1875.[1] During his time at Dorpat, Ostwald had significant exposure to the humanities, which became a focus of his endeavors after his 1906 retirement from academia.[3]

Academic career

Ostwald began his career as an independent investigator in 1875 while at the University of Dorpat. He completed his Ph.D. at the University of Dorpat in 1878, with Carl Schmidt as his thesis advisor. He also studied in the university's physics institute with Arthur von Oettingen.[1] Johann Lemberg was a contemporary of Ostwald in Schmidt's laboratory. Lemberg taught Ostwald many of the basics of the analysis of inorganic compounds and measurements of equilibria and chemical reaction rates. Lemberg also taught Ostwald the chemical basis of many geologic phenomena. These endeavors formed part of the subjects of Ostwald's later research efforts.[3]

Beginning during this time period, Ostwald also taught at Co-Arc from 1875 to 1881 and subsequently at Riga Polytechnicum from 1881 to 1887.[5] His doctoral thesis was entitled, "Volumetric and Optical-Chemical Studies".[4]

Ostwald's initial research focused on the mass action, chemical affinity, electrochemistry, and chemical dynamics. He continued this research in 1877 as an unpaid investigator at the University of Dorpat, working in the Physics Institute and the Chemistry Laboratory at the university.[1]

In 1881, Ostwald was initially a Professor of Chemistry at the Polytechnicum in Riga. Subsequently, in 1887, he became Professor of Physical Chemistry at Leipzig University. Ostwald remained on the faculty at Leipzig University until his retirement in 1906. He also served as the first "exchange professor" at Harvard University in 1904 and 1905.[6][1]

During Ostwald's academic career, he had many research students who became accomplished scientists in their own rite. These included future Nobel Laureates Svante Arrhenius, Jacobus Henricus van 't Hoff, and Walther Nernst. Other students included Arthur Noyes and Willis Rodney Whitney. All of these students became notable for their contributions to physical chemistry.[1]

In 1901, Albert Einstein applied for a research position in Ostwald's laboratory. This was four years before Einstein's publication on special relativity. Ostwald rejected Einstein's application, although later the two developed strong mutual respect.[7] Subsequently, Ostwald nominated Einstein for the Nobel Prize in 1910 and again in 1913.[8]

Following his 1906 retirement, Ostwald became active in philosophy, politics, and other humanities.[1] At the time of his retirement, he moved to a country estate near Groβbothen, Saxony, which he named "Landhans Energie". He lived at the country estate for most of the remainder of his life.[9]

During the course of his academic career, Ostwald published more than 500 original research papers for the scientific literature and approximately 45 books.[9]

Scientific contributions

Nitric acid process

Ostwald invented a process for the inexpensive manufacture of nitric acid by oxidation of ammonia. He was awarded patents for this process.[10] Ostwald's patent made use of a catalyst and described conditions under which the yield of nitric acid was near the theoretical limit. Aspects of the basic process had also been patented some 64 years earlier by Kuhlmann.[11] Kuhlmann's process did not become industrially significant, likely due to the lack of an inexpensive source of ammonia. Shortly after Ostwald's finding, inexpensive ammonia became available as a result of Haber and Bosch's invention of a process for nitrogen fixing process (completed by 1911 or 1913) for ammonia synthesis. The combination of these two breakthroughs soon led to more economical and larger-scale production of fertilizers and explosives, of which Germany was in short supply during World War I.[12][13] The process is often referred to as the Ostwald Process.[13] The process remains in widespread use in contemporary times for manufacture of nitric acid.[14]

Jacobus van 't Hoff (left) and Wilhelm Ostwald

Ostwald's dilution law

Ostwald also conducted significant research on dilution theory leading to his conceptualization of the law of dilution which at times is referred to as "Ostwald's Dilution Law". This theory holds that the behavior of a weak electrolyte follows the principles of mass action, being extensively dissociated at infinite dilution. This characteristic of weak electrolytes can be observed experimentally, such as by electrochemical determinations.[15]

Catalysis

Through his research on chemical reaction rates and velocities and his studies of acids and bases, Ostwald found that the concentration of acid or the concentration of base in a solution of certain chemical reactants can have a strong influence of the rate of chemical processes. He realized that this is manifestation of the concept of chemical catalysis first articulated by Berzelius. Ostwald articulated the idea that a catalyst is a substance that accelerates the rate of a chemical reaction without being a part of either the reactants or the products. Ostwald's advances in the understanding of chemical catalysis were widely applicable in biological processes such as enzymatic catalysis and also in many industrial processes. A catalyst is used in the nitric acid process that Ostwald invented.[14]

Crystallization

Ostwald studied the crystallization behavior of solids, especially those solids that are capable of crystallizing in different forms, in the phenomenon known as polymorphism. He discovered that solids do not necessarily crystallize in their most thermodynamically stable form but instead sometimes crystallize preferentially in other forms dependent on the relative rates of crystallization of each polymorphic form. Ostwald found that the relative rates were dependent on the surface tension between the solid polymorph and the liquid form. Many common materials exhibit this type of behavior, including minerals and various organic compounds. This finding came to be known as Ostwald's rule.[16]

Ostwald realized that solid or liquid solutions can continue to evolve over time. While the a non-thermodynamically preferred polymorph may crystallize first, more thermodynamically stable forms can continue to develop as the solution ages. Often this results in large crystals forming, since they are more thermodynamically stable than are large numbers of small crystals. This phenomenon came to be known as Ostwald Ripening and is observed in many situations. An everyday example is the gritty texture that ice cream develops as it ages. On a geologic timescale, many minerals exhibit Ostwald Ripening as their crystal forms evolve as the mineral ages.[17]

Related to solubility and crystallization was Ostwald's finding that dissolution of a solid depends on the size of the crystal. When the crystals are small, typically less than a micron, the solubility of the solid in the solution phase is increased. Ostwald quantified this effect mathematically in a relationship that became known as the Ostwald-Freundlich equation. Ostwald first published his finding in 1900, and his mathematical equation was refined by German chemist Herbert Freundlich in 1909. This mathematical relationship also applies to the partial pressure of substance in the system. The Ostwald-Freundlich equation takes into account the surface tension of the particle in the system, in addition to curvature and temperature. The size dependence of solubility is sometimes utilized is the formulation of pharmaceuticals that have low solubility so as to enhance their uptake by the patient. The size dependence also has a role in Ostwald Ripening.[18]

Liesegang rings Saginaw Hill, Arizona, USA

Collaborating with German chemist Raphael E. Liesegang, Ostwald recognized that substances can crystallize in a periodic fashion wherein the crystallization behavior follows a spatial or temporal pattern. In certain circumstances, the result of this periodic crystallization behavior is easily visually observed, for example, in various geologic formations. Liesegang had previously investigated this phenomenon in specific laboratory experiments, showing his results to Ostwald. Ostwald then developed a mathematical model for the phenomenon that served to explain the observations and realized how widespread is the periodic crystallization behavior. These observations came to be known as Liesegang rings.[19]

Atomic theory

Ostwald viscometer

The word mole was introduced into the lexicon of chemistry around 1900 by Ostwald. Ostwald defined one mole as the molecular weight of a substance in units of mass grams. The concept was linked to the ideal gas, according to Ostwald. Ironically, Ostwald's development of the mole concept was directly related to his philosophical opposition to atomic theory, against which he (along with Ernst Mach) was one of the last holdouts. He explained in a conversation with Arnold Sommerfeld that he was convinced by Jean Perrin's experiments on Brownian Motion.[20][21]

In 1906 Ostwald was elected a member of the International Committee on Atomic Weights. As a consequence of World War I, this membership ended in 1917 and was not resumed after the war. The 1917 Annual Report of the committee ended with the unusual note: "Because of the European war the Committee has had much difficulty in the way of correspondence. The German member, Professor Ostwald, has not been heard from in connection with this report. Possibly the censorship of letters, either in Germany or en route, has led to a miscarriage".[22]

Scientific measurements

As part of Ostwald's investigations in to chemical equilibria, chemical affinity, and acid-base interactions, he recognized that many established analytical methods disturb the chemical systems under investigation. He therefore turned to physical measurements as surrogate methods to understand these important basic phenomena. One such physical measurement is the measurement of the viscosity, or resistance to flow, of a liquid. Ostwald invented a device for this purpose consisting of bulbs that act as reservoirs for a liquid with a capillary, or thin tube, in between the reservoirs. The time that it takes for the liquid to flow through the capillary from one reservoir to the other is an indication of the viscosity of the liquid. Using a reference solution, the viscosity of the liquid can be quantified. Ostwald typically used this device to study the behavior of solutes in water solutions. These devices came to be known as Ostwald viscometers and are in widespread use in contemporary times for research and quality control purposes.[23]

Ostwald designed a pipette that could be used to transfer and measure liquids, especially serous fluids. This design was later improved by Otto Folin. This type of pipette has a bulb at the lower end as a particular design feature. It became known as the Ostwald-Folin pipette and is widely used in contemporary times.[24]

Color science

Following his 1906 retirement from academia, Ostwald became interested in the systematization of colors, which could be useful both scientifically and in the arts. He published "The Color Primer" and also "The Color Atlas" during the period of 1916-8. These publications established relationships between the various visual colors.[4] Ostwald represented these as a three dimensional representation of color space that is a topological solid consisting of two cones. One apex of the cone is pure white while the other is pure black. The eight primary colors are represented along the sides of the two cones. In this representation, each color is a mixture of white, black, and the eight primary colors. In this way, there are three degrees of freedom that represent each color. This representation of colors was an important early step toward their systematization, replacing color perception by the human eye with an objective system. Over time, Ostwald's advances in color science became part of the HSL and HSV color system.[25] Much of Ostwald's work on systematization of color was done in collaboration with Deutscher Werkbund, which was an association of painters and architects.[3]

Scholarly journals and societies

In 1887, Ostwald founded the peer-reviewed scientific journal Zeitschrift für Physikalische Chemie, specializing in original research in the field of physical chemistry. He served as its editor-in-chief until 1922. In 1894, Ostwald formed the German Electrochemical Society which ultimately became the Deutsche Bunsen-Gesellschaft für angewandte physikalische Chemie [German Bunsen-Society for Applied Physical Chemistry]. He created the journal Klassiker der exakten Wissenschaften in 1889, of which more than 250 volumes have been published.[1]

As part of his interest in philosophy, in 1902 Ostwald started the journal Annalen der Naturphilosophie (Annales of Natural Philosophy). In 1927, he initiated the journal Die Farbe (Colour).[4]

Ostwald was one of the directors of the Die Brücke institute in Munich. The institute was sponsored, significantly, from Ostwald's Nobel Prize money. Through the institute, Ostwald's intention was to develop a standardized system for scholarly publications.[26]

Scholarly works in the humanities and politics

Ostwald color solid

In addition to his work in chemistry, Wilhelm Ostwald was productive in an broad range of fields. His published work, which includes numerous philosophical writings, contains about forty thousand pages. Ostwald was also engaged in the peace movement of Berta von Suttner.

Among his other interests, Ostwald was a passionate amateur painter who made his own pigments, and who developed a strong interest in color theory in the later decades of his life. He wrote several publications in the field, such as his Malerbriefe (Letters to a Painter, 1904) and Die Farbenfibel (The Color Primer, 1916). His work in color theory was influenced by that of Albert Henry Munsell, and in turn influenced Paul Klee and members of De Stijl, including Piet Mondrian.[27] He was also interested in the international language movement, first learning Esperanto, then later supporting Ido and had become member of Committee of the Delegation for the Adoption of an International Auxiliary Language.[28][29][30] Ostwald donated half the proceedings of his 1909 Nobel prize to the Ido movement,[31] funding the Ido magazine Progreso which he had proposed in 1908.[32]

Ostwald adopted the philosophy of Monism as advanced by Ernst Haeckel and became President of the Monistic Alliance in 1911. He used the Alliance's forum to promote Social Darwinism, eugenics and euthanasia. Ostwald's Monism influenced Carl G. Jung's identification of psychological types.[33]

Honours and awards

Nobel Prize certificate for Wilhelm Ostwald

Ostwald received the 1909 Nobel Prize for Chemistry for his contributions to understanding catalysis and for his investigations of the fundamental principles underlying chemical equilibria and reaction rates.[6] He was nominated for the Nobel Prize 20 times beginning in 1914, and he submitted nine nominations of other scientists for the Nobel Prize following his own award. This included two nominations of Albert Einstein.[8] Ostwald, donated more than USD40,000 of his Nobel Prize award money to advance the cause of the Ido language.[34]

In 1923, Ostwald was awarded the Wilhelm Exner Medal, which recognized the economic impact of Ostwald's scientific contributions.[35]

In 1904 he was elected a foreign member of the Royal Netherlands Academy of Arts and Sciences.[36] He became an honorary member of scientific societies in Germany, Sweden, Norway, the Netherlands, Russia, Great Britain, and the United States. Ostwald received honorary doctorates from various universities in Germany, Great Britain and the United States. In 1899 he was made a Geheimrat by the King of Saxony, which by that time was a recognition of Ostwald's scholarly contributions.[1]

There is a Wilhelm Ostwald Park and Museum in Grimma, Germany, at the site of Ostwald's vacation home.[4]

Ostwald crater, which is on the far side of the Earth's moon, was named in honor of Wilhelm Ostwald.[37]

Personal life

On 24 April 1880 Ostwald married Helene von Reyher (1854–1946), with whom he had five children. These were: Grete, (1882 - 1960) born in Riga and died in Großbothen; Wolfgang (1883 - 1943) born 1883 in Riga and died in Dresden; Elisabeth (1884- 1968) born in Riga and died in Großbothen; Walter (1886 - 1958) born in Riga and died in Freiburg im Breisgau; and Carl Otto (1890 - 1958) born in Leipzig and died in Leipzig. Wolfgang Ostwald also became a notable scientist.

Ostwald was initiated to the Scottish Rite Masonry and became Grand Master of the Grand Lodge "Zur Aufgehenden Sonne" in Bayreuth[38][39].

In 1887, he moved to Leipzig where he worked for the rest of his life. On his religious views, Ostwald was an atheist.[40] Ostwald died in a hospital in Leipzig on 4 April 1932, and was buried at his country estate in Großbothen, near Leipzig, and then re-interred in the Great Cemetery of Riga.

In fiction

Ostwald appears as a character in Joseph Skibell's 2010 novel, A Curable Romantic.

He is also mentioned in Italo Svevo's 1923 novel, Zeno's Conscience.

Representative publications

  • Ostwald, W. (1900). Grundriss der allgemeinen Chemie. Leipzig: Engelmann.
  • Ostwald, W. (1906). Process of manufacturing nitric acid. Patent.
  • Ostwald, W. (1909). Energetische Grundlagen der Kulturwissenschaft (1st ed.). Leipzig.
  • Couturat, L.; Jespersen O.; Lorenz R.; Ostwald W.; Pfaundler L. (1910). International language and science: Considerations on the introduction of an international language into science. London: Constable and Company Limited.
  • Ostwald, W. (1917). Grundriss der allgemeinen Chemie (5th ed.). Dresden: Steinkopff.

Books

  • Leitlinien der Chemie : 7 gemeinverständliche Vorträge aus der Geschichte der Chemie. Leipzig : Akad. Verl.-Ges., 1906. Digital edition of the University and State Library Düsseldorf.
  • The Scientific foundations of analytical chemistry London: Macmillan, 1908. OCLC 35430378
  • Colour science, London : Winsor & Newton, 1933. OCLC 499690961
  • The color primer : a basic treatise on the color system of Wilhelm Ostwald, New York, N.Y. : Van Nostrand Reinhold, 1969. OCLC 760593331
  • Electrochemistry : history and theory : Elektrochemie: Ihre Geschichte und Lehre. New Delhi : Amerind Publishing Co. 1980. OCLC 702695546

See also

References

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  2. "Svante August Arrhenius". sciencehistory.org. Science History Institute. Retrieved 17 June 2020.
  3. Kim, Mi Gyung (2006). "Wilhelm Ostwald (1853-1932)". International Journal for Philsophy of Chemistry. 12 (1): 141. Retrieved 8 August 2020.
  4. "Physical Chemist, Nobel Laureate, and Polymath". wilhelm-ostwald-park.de. Gerda and Klaus Tschira Foundation. Retrieved 8 August 2020.
  5. Rajasekharan, P.T.; Tiwari, Arun, eds. (2016). "Ostwald, Wilhelm". Profiles in Excellence Nobel Laureates All: 1901-2015. Bangalore, India: Panther Publishers.
  6. "Wilhelm Ostwald Facts". softschools.com. Soft Schools. Retrieved 19 June 2020.
  7. Isaacson, Walter (5 April 2007). "20 Things You Need to Know About Einstein". Time USA, LLC. Time Magazine. Retrieved 8 August 2020.
  8. "Wilhelm Ostwald - Nominations". nobelprize.org. The Nobel Foundation. Retrieved 8 August 2020.
  9. Stewart, Doug. "Wilhelm Ostwald". famousscientists.org. Retrieved 14 August 2020.
  10. W. Ostwald, "Process for Manufacturing Nitric Acid, US858904, July 2, 1907.
  11. Note:
    • Frédéric Kuhlmann, "Pour la fabrication de l'acide nitrique et des nitrates," French patent no. 11,331 (filed: October 1838 ; issued: 22 December 1838). Supplemental patent issued: 7 June 1839. See: Description des machines et procédés consignés dans les brevets d'invention, … [Description of machines and methods recorded in the patents of invention, … ] (Paris, France: Madame Veuve Bouchard-Huzard, 1854), 82 : 160.
    • Fréd. Kuhlmann (1838) "Note sur plusieurs réactions nouvelles déterminées par l'éponge de platine, et considérations sur les services que cette substance est appelée à rendre à la science" (Note on several new reactions caused by platinum sponge, and reflections on the services that this substance is called to render to science), Comptes rendus, 7 : 1107–1110. From page 1109: "1°. L'ammoniaque mêlée d'air en passant à une température de 300° environ sur de l'éponge de platine, est décomposée, et l'azote qu'il renferme est complétement transformé en acide nitrique, aux dépens de l'oxigène de l'air." (1. Ammonia mixed with air, upon passing at a temperature of about 300° over platinum sponge, is decomposed and the nitrogen that it contains is completely transformed into nitric acid, at the expense of the oxygen of the air.)
    • John Graham Smith (1988) "Frédéric Kuhlmann: Pioneer of platinum as an industrial catalyst," Platinum Metals Review, 32 (2) : 84–90.
  12. Louchheim, Justin. "Fertilizer History: The Haber-Bosch Process". tfi.org. The Fertilizer Institute. Retrieved 16 June 2020.
  13. Sutton, Mike. "Chemists at War". chemistryworld.org. Royal Society of Chemistry. Retrieved 16 June 2020.
  14. Van Houten, J. (2002). "A Century of Chemical Dynamics Traced through the Nobel Prizes". Journal of Chemical Education. 79 (2): 146. Retrieved 7 August 2020.
  15. "Ostwald's Dilution Law". sciencehq.com. Rod Pierce DipCE BEng. Retrieved 3 August 2020.
  16. Wang, Tingting. "Breakdown of the Ostwald Step Rule--The Precipitation of Calcite and Dolomite from Seawater at 25 and 40°C" (PDF). semanticscholar.org. Semantic Scholar. Retrieved 5 August 2020.
  17. Jahren, J.S. (1991). "Evidence of Ostwald Ripening Related Recrystallization of Diagenetic Chlorites From Reservoir Rocks Offshore Norway". Clay Minerals. 26: 169. Retrieved 7 August 2020.
  18. Eslami, Fatemeh; Elliott, Janet A. W. (2014). "Role of Precipitating Solute Curvature on Microdrops and Nanodrops during Concentrating Processes: The Nonideal Ostwald–Freundlich Equation". Journal of Physical Chemistry B. 118 (50): 14675. doi:10.1021/jp5063786. Retrieved 7 August 2020.
  19. "A Short History of "Liesegang Rings"". insilico.hu. In Silico, Ltd. Retrieved 7 August 2020.
  20. Nye, M., 1972, Molecular Reality: A Perspective on the Scientific Work of Jean Perrin, London: MacDonald.
  21. Gorin, George (February 1994). "Mole and Chemical Amount: A Discussion of the Fundamental Measurements of Chemistry". Journal of Chemical Education. 71 (2): 114. Bibcode:1994JChEd..71..114G. doi:10.1021/ed071p114.
  22. Clark, F.W. (1916). "Annual report of the international committee on atomic weights". J. Am. Chem. Soc. 38 (11): 2219–2221. doi:10.1021/ja02268a001.
  23. Sella, Andrea. "Classic Kit: Ostwald's viscometer". chemistryworld.com. Royal Society of Chemistry. Retrieved 5 August 2020.
  24. "Serological pipets" (PDF). eppendorf.com. Eppendorf AG. Retrieved 11 August 2020.
  25. Nichols, Kara. "The Chemistry of Color". cooperhewitt.org. Smithsonian Design Museum. Retrieved 9 August 2020.
  26. Michael Keeble Buckland (April 2006). Emanuel Goldberg and his knowledge machine: information, invention, and political forces. Greenwood Publishing Group. p. 64. ISBN 978-0-313-31332-5. Retrieved 26 May 2011.
  27. John Gage, Color and Culture: Practice and Meaning from Antiquity to Abstraction, Boston, Little, Brown and Co., 1993; pp. 247– 8, 257– 60.
  28. Nye, Mary Jo (2016). "Speaking in Tongues: Science's centuries-long hunt for a common language". Distillations. 2 (1): 40–43. Retrieved 22 March 2018.
  29. Gordin, Michael D. (2015). Scientific Babel: How Science Was Done Before and After Global English. Chicago, Illinois: University of Chicago Press. ISBN 9780226000299.
  30. Forster, Peter Glover (1982). The Esperanto Movement. Walter de Gruyter. ISBN 9789027933997.
  31. Wall, F. E. (1948). "Wilhelm Ostwald". Journal of Chemical Education. 25 (1): 2–10. Bibcode:1948JChEd..25....2W. doi:10.1021/ed025p2.
  32. Anton, Günter (June 2003). "L'agado di profesoro Wilhelm Ostwald por la LINGUO INTERNACIONA IDO" (in Ido). Retrieved 12 February 2012.
  33. Noll, Richard, The Jung Cult. Princeton University Press, 1994, p. 50
  34. Gordin, Michael D. (2015). Scientific Babel: How Science Was Done Before and After Global English. University of Chicago Press. p. 151. ISBN 9780226000329.
  35. "WIlhelm Ostwald". wilhelmexner.org. Österreichischer Gewerbeverein. Retrieved 18 June 2020.
  36. "Friedrich Wilhelm Ostwald (1853 - 1932)". Royal Netherlands Academy of Arts and Sciences. Retrieved 13 June 2020.
  37. "Ostwald". Gazetteer of Planetary Nomenclature. International Astronomical Union. Retrieved 17 June 2020.
  38. "Ostwald Wilhelm, in the "Masonic Encyclopedia"". freimaurer-wiki.de (in German). Archived from the original on 6 April 2014.
  39. "Celebrating more than 100 years of the Freemasonry: famous Freemasons in the history". Mathawan Lodge No 192 F.A. & A.M., New Jersey. Archived from the original on 10 May 2008.
  40. Jürgen Kocka (2010). Jürgen Kocka (ed.). Work in a Modern Society: The German Historical Experience in Comparative Perspective. Berghahn Books. p. 45. ISBN 978-1-84545-575-0. Even Wilhelm Ostwald, who was the most radical atheist among these scholars, uses the instrument of the 'Monistic Sunday Sermons' to spread his ideas on rationality.
  • Wilhelm Ostwald on Nobelprize.org including the Nobel Lecture*, December 12, 1909 On Catalysis
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