Xylidine

Xylidine can refer to any of the six isomers of xylene amine, or any mixture of them.

The chemical formula of xylidines is C8H11N or, more descriptively, (CH3)2C6H3NH2. The CAS number for the isomer mixture is 1300-73-8. They are colorless solids or liquids, although commercial samples can appear yellow or darker. They are miscible with ethanol and diethyl ether and slightly soluble in water. Xylidines are used in production of pigments and dyestuffs, and various antioxidants, agrochemicals, pharmaceuticals, hypergolic propellants, and many other organic chemicals.[1]

Isomers of xylidine
  • 2,3-xylidine
  • 2,4-xylidine
  • 2,5-xylidine
  • 2,6-xylidine
  • 3,4-xylidine
  • 3,5-xylidine

2,3-xylidine
Main article: 2,3-Xylidine

2,3-xylidine, also called o-xylidine, 2,3-dimethylaniline, 2,3-xylylamine, or 2,3-dimethylphenylamine, is a liquid with melting point 2.5 °C and boiling point 222 °C, and flash point at 96 °C. Its CAS number is 87-59-2 and its SMILES structure is Nc1cccc(C)c1C. It is used in production of mefenamic acid, dyes, and pesticides.

2,4-xylidine
Main article: 2,4-Xylidine

2,4-xylidine, also called 2-methyl-p-toluidine, 2,4-dimethylaniline, 2,4-xylylamine, or 2,4-dimethylphenylamine, is a liquid with melting point 16 °C, boiling point 217 °C, and flash point at 90 °C. Its CAS number is 95-68-1 and its SMILES structure is Nc1ccc(C)cc1C. It is used for production of pesticides, dyes, and other chemicals.

2,5-xylidine
Main article: 2,5-Xylidine

2,5-xylidine, also called p-xylidine, 2,5-dimethylaniline, 2,5-xylylamine, or 2,5-dimethylphenylamine, is a liquid with melting point 11.5 °C and boiling point 215 °C. Its CAS number is 95-78-3 and its SMILES structure is Nc1cc(C)ccc1C. It is used for production of dyes and other chemicals.

2,6-xylidine
Main article: 2,6-Xylidine

2,6-Xylidine, also called 2,6-dimethylaniline, 2,6-xylylamine, or 2,6-dimethylphenylamine, is a liquid with melting point 8.4 °C and boiling point 216 °C. Its CAS number is 87-62-7 and its SMILES structure is Nc1c(C)cccc1C. It is used in production of some anesthetics and other chemicals.

3,4-xylidine
Main article: 3,4-Xylidine

3,4-xylidine, also called 3,4-dimethylaniline, 3,4-xylylamine, or 3,4-dimethylphenylamine, is a crystalline solid with melting point 51 °C and boiling point 226 °C. Its CAS number is 95-64-7 and its SMILES structure is Nc1ccc(C)c(C)c1. It is used as a raw material for production of vitamin B2, dyes, pesticides, and other chemicals.

3,5-xylidine
Main article: 3,5-Xylidine

3,5-xylidine, also called 3,5-dimethylaniline, 3,5-xylylamine, or 3,5-dimethylphenylamine, is a liquid with melting point 9.8 °C and boiling point 220–221 °C. Its CAS number is 108-69-0 and its SMILES structure is Nc1cc(C)cc(C)c1. It is used for production of pesticides, dyes, and other chemicals.

Safety

The U.S. Occupational Safety and Health Administration (OSHA) has set the legal limit (Permissible exposure limit) for xylidine exposure in the workplace as 5 ppm (25 mg/m3) skin exposure over an eight-hour workday. The U.S. National Institute for Occupational Safety and Health (NIOSH) has set a Recommended exposure limit (REL) of 2 ppm (10 mg/m3) skin exposure over an eight-hour workday. At levels of 50 ppm, xylidine is immediately dangerous to life and health.[2]

Their risk and safety phrases are R20 R22 R36 R37 R38.

gollark: In the US you can't transmit encrypted signals over amateur bands IIRC.
gollark: There are lots of legal things involved and you need an amateur license.
gollark: cloud blockchain with artificial intelligence aspects
gollark: 🌵🌵🌵
gollark: I actually assumed you meant the Dell tower server.

References
  1. M. Meyer (2012). "Xylidines". Ullmann's Encylclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a28_455.
  2. "CDC - NIOSH Pocket Guide to Chemical Hazards - Xylidine". www.cdc.gov. Retrieved 2015-11-28.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.