Thermodynamic beta

In statistical thermodynamics, thermodynamic beta, also known as coldness, is the reciprocal of the thermodynamic temperature of a system:

${\displaystyle \beta ={\frac {1}{k_{\rm {B}}T}}}$ (where T is the temperature and k_B is Boltzmann constant).[1]

"Coldness" redirects here. For the abstract noun, see Cold.

SI temperature/coldness conversion scale: Temperatures in Kelvin scale are shown in blue (Celsius scale in green, Fahrenheit scale in red), coldness values in gigabyte per nanojoule are shown in black. Infinite temperature (coldness zero) is shown at the top of the diagram; positive values of coldness/temperature are on the right-hand side, negative values on the left-hand side.

It was originally introduced in 1971 (as Kältefunktion "coldness function") by Ingo Müller, one of the proponents of the rational thermodynamics school of thought,[2] based on earlier proposals for a "reciprocal temperature" function.[3][4]

Thermodynamic beta has units reciprocal to that of energy (in SI units, ${\displaystyle [\beta ]={\textrm {J}}^{-1}}$). In non-thermal units, it can also be measured in byte per joule, or more conveniently, gigabyte per nanojoule;[5] 1 K⁻¹ is equivalent to about 13,062 gigabytes per nanojoule; at room temperature: T = 300K, β ≈ 44 GB/nJ ≈ 39 eV⁻¹ ≈ 2.4×10²⁰ J⁻¹.

Description

Thermodynamic beta is essentially the connection between the information theory and statistical mechanics interpretation of a physical system through its entropy and the thermodynamics associated with its energy. It expresses the response of entropy to an increase in energy. If a system is challenged with a small amount of energy, then β describes the amount the system will randomize.

Via the statistical definition of temperature as a function of entropy, the coldness function can be calculated in the microcanonical ensemble from the formula

${\displaystyle \beta ={\frac {1}{k_{\rm {B}}T}}\,={\frac {1}{k_{\rm {B}}}}\left({\frac {\partial S}{\partial E}}\right)_{V,N}}$

(i.e., the partial derivative of the entropy S with respect to the energy E at constant volume V and particle number N).

Advantages

Though completely equivalent in conceptual content to temperature, β is generally considered a more fundamental quantity than temperature owing to the phenomenon of negative temperature, in which β is continuous as it crosses zero whereas T has a singularity.[6]

Statistical interpretation

From the statistical point of view, β is a numerical quantity relating two macroscopic systems in equilibrium. The exact formulation is as follows. Consider two systems, 1 and 2, in thermal contact, with respective energies E₁ and E₂. We assume E₁ + E₂ = some constant E. The number of microstates of each system will be denoted by Ω₁ and Ω₂. Under our assumptions Ω_i depends only on E_i. Thus the number of microstates for the combined system is

${\displaystyle \Omega =\Omega _{1}(E_{1})\Omega _{2}(E_{2})=\Omega _{1}(E_{1})\Omega _{2}(E-E_{1}).\,}$

We will derive β from the fundamental assumption of statistical mechanics:

When the combined system reaches equilibrium, the number Ω is maximized.

(In other words, the system naturally seeks the maximum number of microstates.) Therefore, at equilibrium,

${\displaystyle {\frac {d}{dE_{1}}}\Omega =\Omega _{2}(E_{2}){\frac {d}{dE_{1}}}\Omega _{1}(E_{1})+\Omega _{1}(E_{1}){\frac {d}{dE_{2}}}\Omega _{2}(E_{2})\cdot {\frac {dE_{2}}{dE_{1}}}=0.}$

But E₁ + E₂ = E implies

${\displaystyle {\frac {dE_{2}}{dE_{1}}}=-1.}$

So

${\displaystyle \Omega _{2}(E_{2}){\frac {d}{dE_{1}}}\Omega _{1}(E_{1})-\Omega _{1}(E_{1}){\frac {d}{dE_{2}}}\Omega _{2}(E_{2})=0}$

i.e.

${\displaystyle {\frac {d}{dE_{1}}}\ln \Omega _{1}={\frac {d}{dE_{2}}}\ln \Omega _{2}\quad {\mbox{at equilibrium.}}}$

The above relation motivates a definition of β:

${\displaystyle \beta ={\frac {d\ln \Omega }{dE}}.}$

Connection of statistical view with thermodynamic view

When two systems are in equilibrium, they have the same thermodynamic temperature T. Thus intuitively, one would expect β (as defined via microstates) to be related to T in some way. This link is provided by Boltzmann's fundamental assumption written as

${\displaystyle S=k_{\rm {B}}\ln \Omega ,\,}$

where k_B is the Boltzmann constant, S is the classical thermodynamic entropy, and Ω is the number of microstates. So

${\displaystyle d\ln \Omega ={\frac {1}{k_{\rm {B}}}}dS.}$

Substituting into the definition of β from the statistical definition above gives

${\displaystyle \beta ={\frac {1}{k_{\rm {B}}}}{\frac {dS}{dE}}.}$

Comparing with thermodynamic formula

${\displaystyle {\frac {dS}{dE}}={\frac {1}{T}},}$

we have

${\displaystyle \beta ={\frac {1}{k_{\rm {B}}T}}={\frac {1}{\tau }}}$

where ${\displaystyle \tau }$ is called the fundamental temperature of the system, and has units of energy.

See also

• Boltzmann distribution
• Canonical ensemble
• Ising model

References

1. J. Meixner (1975) "Coldness and Temperature", Archive for Rational Mechanics and Analysis 57:3, 281-290 abstract.
2. Müller, I., "Die Kältefunktion, eine universelle Funktion in der Thermodynamik wärmeleitender Flüssigkeiten". Archive for Rational Mechanics and Analysis 40 (1971), 1–36 ("The coldness, a universal function in thermoelastic bodies", Archive for Rational Mechanics and Analysis 41:5, 319-332).
3. Day, W.A. and Gurtin, Morton E. (1969) "On the symmetry of the conductivity tensor and other restrictions in the nonlinear theory of heat conduction", Archive for Rational Mechanics and Analysis 33:1, 26-32 (Springer-Verlag) abstract.
4. J. Castle, W. Emmenish, R. Henkes, R. Miller, and J. Rayne (1965) Science by Degrees: Temperature from Zero to Zero (Westinghouse Search Book Series, Walker and Company, New York).
5. P. Fraundorf (2003) "Heat capacity in bits", Amer. J. Phys. 71:11, 1142-1151.
6. Kittel, Charles; Kroemer, Herbert (1980), Thermal Physics (2 ed.), United States of America: W. H. Freeman and Company, ISBN 978-0471490302