Ethyl 3-bromopropionate

Ethyl 3-bromopropionate
Names
	Other names Ethyl β-Bromopropionate, Ethyl 2-bromopropanoate
Identifiers
CAS Number	539-74-2;
3D model (JSmol)	Interactive image;
ChemSpider	61615;
EC Number	208-724-0;
PubChem CID	68320;
UNII	9B28G9S1JV;
	InChI InChI=1S/C5H9BrO2/c1-2-8-5(7)3-4-6/h2-4H2,1H3 Key: FQTIYMRSUOADDK-UHFFFAOYSA-N;
	SMILES CCOC(=O)CCBr;
Properties
Chemical formula	C5H9BrO2
Molar mass	181.029 g·mol−1
Appearance	colorless liquid
Density	1.4409 g/cm3
Boiling point	135–136 °C (275–277 °F; 408–409 K) 50 mmHg
Hazards
GHS pictograms
GHS Signal word	Warning
GHS hazard statements	H315, H319, H335
GHS precautionary statements	P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Ethyl 3-bromopropionate is the organobromine compound with the formula BrCH₂CH₂CO₂C₂H₅. It is a colorless liquid and an alkylating agent. It is prepared by the esterification of 3-bromopropionic acid.[1] Alternatively, it can be prepared by hydrobromination of ethyl acrylate, a reaction that proceeds in an anti-Markovnikov sense.[2]

References

Kendall, E. C.; McKenzie, B. (1923). "Ethyl β-Bromopropionate". Organic Syntheses. 3: 51. doi:10.15227/orgsyn.003.0051.
Mozingo, Ralph; Patterson, L. A. (1940). "Methyl β-Bromopropionate". Organic Syntheses. 20: 64. doi:10.15227/orgsyn.020.0064.

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[1] Kendall, E. C.; McKenzie, B. (1923). "Ethyl β-Bromopropionate". Organic Syntheses. 3: 51. doi:10.15227/orgsyn.003.0051.

[2] Mozingo, Ralph; Patterson, L. A. (1940). "Methyl β-Bromopropionate". Organic Syntheses. 20: 64. doi:10.15227/orgsyn.020.0064.