Descaling agent

A descaling agent or chemical descaler is a liquid chemical substance used to remove limescale from metal surfaces in contact with hot water, such as in boilers, water heaters, and kettles. Limescale is either white or brown in colour due to the presence of iron compounds. Glass surfaces may also exhibit scaling stains, as can many ceramic surfaces present in bathrooms and kitchen, and descaling agents can be used safely to remove those stains without affecting the substrate since both ceramics and glass are unreactive to most acids.[1]

Limescale build-up inside a pipe reduces both liquid flow and thermal conduction from the pipe, so will reduce thermal efficiency when used as a heat exchanger.

Action

Descaling agents are typically acidic compounds such as hydrochloric acid that react with the calcium carbonate and magnesium carbonate compounds present in the scale, producing carbon dioxide gas and a soluble salt.[2]

CaCO3(s) + 2 H+(aq) → Ca2+(aq) + CO2(g) + H2O(l)

MgCO3(s) + 2 H+(aq) → Mg2+(aq) + CO2(g) + H2O(l)

Strongly acidic descaling agents are usually corrosive to the eyes and skin, and can also attack and degrade clothing fibres, so appropriate protection such as rubber gloves and plastic aprons should be used in cleaning operations.

Acids used

Notable descaling agents include acetic acid, citric acid, glycolic acid, formic acid, lactic acid, phosphoric acid, sulfamic acid and hydrochloric acid. The calcium salts are soluble and thus washed away during dissolution or Solvation. The speed of the descaling action depends on the concentration and acidity or pH of the solution provided. Hydrochloric acid is much stronger than acetic acid for example, so tends to remove scale faster. Weak acids such as acetic or citric acids may be preferred however, where damage to the substrate is to be minimised.

There are many companies offering inhibited or "buffered" acids that inhibit the corrosive effect of the acids on various materials. Typically about a 10% concentration of hydrochloric acid with a corrosion inhibitor and some added penetrating and wetting agents added. This allows for a better cleaning of machinery and especially heat exchangers because often the scale is mixed up with silica and other contaminants. These additives reduce the corrosion on the metals and cut through and loosen up these other materials mixed with the scale for faster and more thorough cleaning.

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See also

References
  1. "Descaler", Wiktionary, Accessed January 14, 2014
  2. Stanga, Mario (2010). Sanitation: Cleaning and Disinfection in the Food Industry. John Wiley & Sons. pp. 571–572.
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