Caesium-137

Caesium-137 (137
55Cs
), or radiocaesium, is a radioactive isotope of caesium which is formed as one of the more common fission products by the nuclear fission of uranium-235 and other fissionable isotopes in nuclear reactors and nuclear weapons. Trace quantities also originate from natural fission of uranium-238. It is among the most problematic of the short-to-medium-lifetime fission products because it easily moves and spreads in nature due to the high water solubility of caesium's most common chemical compounds, which are salts.

"Cesium 137" redirects here. For the band, see Cesium 137 (band).

Caesium-137, 137Cs
A sealed caesium-137 radioactive source
General
Symbol137Cs
Namescaesium-137, Cs-137
Protons55
Neutrons82
Nuclide data
Natural abundance0 (trace)
Half-life30.17 y ± 0.03 y[1]
Parent isotopes137Xe (β−)
Decay products137mBa
137Ba
Isotope mass136.907 u
Spin​7⁄2+
Decay modes
Decay modeDecay energy (MeV)
β- (beta decay)0.5120[2]
γ (gamma-rays)0.6617
Isotopes of caesium
Complete table of nuclides

Decay
137Cs decay scheme showing half-lives, daughter nuclides, and types and proportion of radiation emitted.
137Cs gamma spectrum. The characteristic 662 keV peak does not originate directly from 137Cs, but from the decay of 137mBa to its stable state.

Caesium-137 has a half-life of about 30.17 years.[1] About 94.6% decays by beta emission to a metastable nuclear isomer of barium: barium-137m (137mBa, Ba-137m). The remainder directly populates the ground state of barium-137, which is stable. Metastable barium has a half-life of about 153 seconds, and is responsible for all of the gamma ray emissions in samples of caesium-137. 137mBa decays to the ground state by emission of photons having energy 0.6617 MeV.[3] A total of 85.1% of 137Cs decays lead to gamma ray emission in this way. One gram of caesium-137 has an activity of 3.215 terabecquerel (TBq).[4]

Uses

Caesium-137 has a number of practical uses. In small amounts, it is used to calibrate radiation-detection equipment.[5] In medicine, it is used in radiation therapy.[5] In industry, it is used in flow meters, thickness gauges,[5] moisture-density gauges (for density readings, with americium-241/beryllium providing the moisture reading),[6] and in gamma ray well logging devices.[6]

Caesium-137 is not widely used for industrial radiography because it is hard to obtain a very high specific activity material with a well defined (and small shape) as cesium from used nuclear fuel contains stable cesium and also long lived Cs-135. Also the higher specific activity cesium sources tend to be made from cesium chloride, as a result if a radiography source was damaged it would increase the spread of the contamination. It is possible to make water insoluble cesium sources but their specific activity will be much lower. A large emitting volume will harm the image quality in radiography. Iridium-192 and Cobalt-60, 60
27Co
, are preferred for radiography, since these are chemically nonreactive metals and can be obtained with much higher specific activities by the activation of stable cobalt or iridium in high flux reactors.

As an almost purely man-made isotope, caesium-137 has been used to date wine and detect counterfeits[7] and as a relative-dating material for assessing the age of sedimentation occurring after 1945.[8]

Caesium-137 is also used as a radioactive tracer in geologic research to measure soil erosion and deposition.[9]

Health risk of radioactive caesium

Caesium-137 reacts with water, producing a water-soluble compound (caesium hydroxide). The biological behaviour of caesium is similar to that of potassium[10] and rubidium. After entering the body, caesium gets more or less uniformly distributed throughout the body, with the highest concentrations in soft tissue.[11]:114 The biological half-life of caesium is about 70 days.[12]

A 1961 experiment showed that mice dosed with 21.5 μCi/g had a 50% fatality within 30 days (implying an LD50 of 245 µg/kg).[13]

A similar experiment in 1972 showed that when dogs are subjected to a whole body burden of 3800 μCi/kg (140 MBq/kg, or approximately 44 μg/kg) of caesium-137 (and 950 to 1400 rads), they die within 33 days, while animals with half of that burden all survived for a year.[14]

Accidental ingestion of caesium-137 can be treated with Prussian blue, which binds to it chemically and reduces the biological half-life to 30 days.[15]

Radioactive caesium in the environment
The ten highest deposits of caesium-137 from U.S. nuclear testing at the Nevada Test Site. Test explosions "Simon" and "Harry" were both from Operation Upshot–Knothole in 1953, while the test explosions "George" and "How" were from Operation Tumbler–Snapper in 1952.
Medium-lived
fission products
Prop:
Unit:		 t½
(a)		 Yield
(%)		 Q *
(keV)		 βγ *
155Eu 4.76 0.0803 252 βγ
85Kr 10.76 0.2180 687 βγ
113mCd 14.1 0.0008 316 β
90Sr 28.9 4.505 2826 β
137Cs 30.23 6.337 1176 βγ
121mSn 43.9 0.00005 390 βγ
151Sm 88.8 0.5314 77 β

Caesium-137, along with other radioactive isotopes caesium-134, iodine-131, xenon-133, and strontium-90, were released into the environment during nearly all nuclear weapon tests and some nuclear accidents, most notably the Chernobyl disaster and the Fukushima Daiichi disaster.

Chernobyl disaster
Main article: Chernobyl disaster

As of today and for the next few hundred years, caesium-137 and strontium-90 continue to be the principal source of radiation in the zone of alienation around the Chernobyl nuclear power plant, and pose the greatest risk to health, owing to their approximately 30 year half-life and biological uptake. The mean contamination of caesium-137 in Germany following the Chernobyl disaster was 2000 to 4000 Bq/m². This corresponds to a contamination of 1 mg/km² of caesium-137, totaling about 500 grams deposited over all of Germany. In Scandinavia, some reindeer and sheep exceeded the Norwegian legal limit (3000 Bq/kg) 26 years after Chernobyl.[16] As of 2016, the Chernobyl caesium-137 has decayed by half, but could have been locally concentrated by much larger factors.

Fukushima Daiichi disaster
Main article: Fukushima Daiichi nuclear disaster
Calculated caesium-137 concentration in the air after the Fukushima nuclear disaster, 25 March 2011.

In April 2011, elevated levels of caesium-137 were also being found in the environment after the Fukushima Daiichi nuclear disasters in Japan. In July 2011, meat from 11 cows shipped to Tokyo from Fukushima Prefecture was found to have 1,530 to 3,200 becquerels per kilogram of 137Cs, considerably exceeding the Japanese legal limit of 500 becquerels per kilogram at that time.[17] In March 2013, a fish caught near the plant had a record 740,000 becquerels per kilogram of radioactive caesium, above the 100 becquerels per kilogram government limit.[18] A 2013 paper in Scientific Reports found that for a forest site 50 km from the stricken plant, 137Cs concentrations were high in leaf litter, fungi and detritivores, but low in herbivores.[19] By the end of 2014, "Fukushima-derived radiocaesium had spread into the whole western North Pacific Ocean", transported by the North Pacific current from Japan to the Gulf of Alaska. It has been measured in the surface layer down to 200 meters and south of the current area down to 400 meters.[20]

Caesium-137 is reported to be the major health concern in Fukushima. A number of techniques are being considered that will be able to strip out 80% to 95% of the caesium from contaminated soil and other materials efficiently and without destroying the organic material in the soil. These include hydrothermal blasting. The caesium precipitated with ferric ferrocyanide (Prussian blue) would be the only waste requiring special burial sites.[21] The aim is to get annual exposure from the contaminated environment down to 1 mSv above background. The most contaminated area where radiation doses are greater than 50 mSv/year must remain off limits, but some areas that are currently less than 5 mSv/year may be decontaminated, allowing 22,000 residents to return.

Caesium-137 in the environment is substantially anthropogenic (human-made). Caesium-137 is produced from the nuclear fission of plutonium and uranium, and decays into barium-137.[22] Before the construction of the first artificial nuclear reactor in late 1942 (the Chicago Pile-1), caesium-137 had not occurred on Earth in significant amounts for about 1.7 billion years. By observing the characteristic gamma rays emitted by this isotope, one can determine whether the contents of a given sealed container were made before or after the first atomic bomb explosion (Trinity test, 16 July 1945), which spread some of it into the atmosphere, quickly distributing trace amounts of it around the globe. This procedure has been used by researchers to check the authenticity of certain rare wines, most notably the purported "Jefferson bottles".[23] Surface soils and sediments are also dated by measuring the activity of 137Cs.

Incidents and accidents

Caesium-137 gamma sources have been involved in several radiological accidents and incidents.

1987 Goiânia, Goiás, Brazil

In the Goiânia accident of 1987, an improperly disposed of radiation therapy system from an abandoned clinic in Goiânia, Brazil, was removed then cracked to be sold in junkyards, and the glowing caesium salt sold to curious, unadvised buyers. This led to four confirmed deaths and several serious injuries from radiation contamination.[24][25] Caesium gamma-ray sources that have been encased in metallic housings can be mixed in with scrap metal on its way to smelters, resulting in production of steel contaminated with radioactivity.[26]

1989 Kramatorsk, Donetsk, Ukraine

The Kramatorsk radiological accident happened in 1989 when a small capsule containing highly radioactive caesium-137 was found inside the concrete wall of an apartment building in Kramatorsk, Ukrainian SSR. It is believed that the capsule, originally a part of a measurement device, was lost in the late 1970s and ended up mixed with gravel used to construct the building in 1980. Over 9 years, two families had lived in the apartment. By the time the capsule was discovered, 6 residents of the building had died from leukemia and 17 more had received varying doses of radiation.

1997, Georgia

In 1997, several Georgian soldiers suffered radiation poisoning and burns. They were eventually traced back to training sources abandoned, forgotten, and unlabeled after the dissolution of the Soviet Union. One was a caesium-137 pellet in a pocket of a shared jacket which put out about 130,000 times the level of background radiation at 1 meter distance.[27]

1998, Los Barrios, Cádiz, Spain

In the Acerinox accident of 1998, the Spanish recycling company Acerinox accidentally melted down a mass of radioactive caesium-137 that came from a gamma-ray generator.[28]

2009 Tongchuan, Shaanxi, China

In 2009, a Chinese cement company (in Tongchuan, Shaanxi Province) was demolishing an old, unused cement plant and did not follow standards for handling radioactive materials. This caused some caesium-137 from a measuring instrument to be included with eight truckloads of scrap metal on its way to a steel mill, where the radioactive caesium was melted down into the steel.[29]

March 2015, University of Tromsø, Norway

In March 2015, the Norwegian University of Tromsø lost 8 radioactive samples including samples of caesium-137, americium-241, and strontium-90. The samples were moved out of a secure location to be used for education. When the samples were supposed to be returned the university was unable to find them. As of 4 November 2015 the samples are still missing.[30][31]

March 2016 Helsinki, Uusimaa, Finland

On 3 and 4 March 2016, unusually high levels of caesium-137 were detected in the air in Helsinki, Finland. According to STUK, the country's nuclear regulator, measurements showed 4,000 μBq/m³ — about 1,000 times the usual level. An investigation by the agency traced the source to a building from which STUK and a radioactive waste treatment company operate.[32][33]

May 2019 Seattle, Washington, US

Thirteen people were exposed to caesium-137 in May 2019 at the Research and Training building in the Harborview Medical Center complex. A contract crew was transferring the caesium from the lab to a truck when the powder was spilled. Five people were decontaminated and released, but 8 who were more directly exposed were taken to the hospital while the research building was evacuated.[34]

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See also

References
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  2. "137
    55    Cs
    82"    . WWW Table of Radioactive Isotopes. LBNL Isotopes Project - LUNDS Universitet. Archived from the original on 22 May 2015. Retrieved 14 March 2009.
  3. Delacroix, D.; Guerre, J. P.; Leblanc, P.; Hickman, C. (2002). Radionuclide and Radiation Protection Handbook. Nuclear Technology Publishing. ISBN 978-1870965873.
  4. Bunting, R. L. (1975). "Nuclear Data Sheets for A=137". Nuclear Data Sheets 15. 335.
  5. "CDC Radiation Emergencies | Radioisotope Brief: Cesium-137 (Cs-137)". CDC. Retrieved 5 November 2013.
  6. "Cesium | Radiation Protection | US EPA". EPA. 3 June 2012. Archived from the original on 6 September 2015. Retrieved 4 March 2015.
  7. "How Atomic Particles Helped Solve A Wine Fraud Mystery". NPR. 3 June 2014. Retrieved 4 March 2015.
  8. Williams, H. F. L. (1995). "Assessing the impact of weir construction on recent sedimentation using cesium-137". Environmental Geology. 26 (3): 166–171. Bibcode:1995EnGeo..26..166W. doi:10.1007/BF00768738. ISSN 0943-0105.
  9. Loughran, Robert (1 June 1989). "The measurement of soil erosion". Progress in Physical Geography. 221 (2): 216–233. doi:10.1177/030913338901300203.
  10. Avery, Simon V. (1995). "Caesium accumulation by microorganisms: uptake mechanisms, cation competition, compartmentalization and toxicity". Journal of Industrial Microbiology. 14 (2): 76–84. doi:10.1007/BF01569888. ISSN 0169-4146. PMID 7766213.
  11. Delacroix, D.; Guerre, J. P.; Leblanc, P.; Hickman, C. (2002). Radionuclide and Radiation Protection Data Handbook 2002 (2nd ed.). Nuclear Technology Publishing. ISBN 978-1-870965-87-3.
  12. R. Nave. "Biological Half-life". Hyperphysics.
  13. Moskalev, Yu. I. (1961). "Biological Effects of Cesium-137". In Lebedinskiĭ, A. V.; Moskalev, Yu. I. (eds.). Distribution, Biological Effects, and Migration of Radioactive Isotopes. Translation Series. United States Atomic Energy Commission (published April 1974). p. 220. AEC-tr-7512.
  14. H.C. Redman; et al. (1972). "Toxicity of 137-CsCl in the Beagle. Early Biological Effects". Radiation Research. 50 (3): 629–648. Bibcode:1972RadR...50..629R. doi:10.2307/3573559. JSTOR 3573559. PMID 5030090.
  15. "CDC Radiation Emergencies | Facts About Prussian Blue". CDC. Archived from the original on 20 October 2013. Retrieved 5 November 2013.
  16. Sandelson, Michael; Smith, Lyndsey (21 May 2012). "Higher radiation in Jotunheimen than first believed". The Foreigner. Archived from the original on 2 October 2018. Retrieved 21 May 2012.
  17. "High levels of caesium in Fukushima beef". Independent Online. 9 July 2011.
  18. "Fish near Fukushima reportedly contains high Cesium level". Huffington Post. 17 March 2013.
  19. Murakami, Masashi; Ohte, Nobuhito; Suzuki, Takahiro; Ishii, Nobuyoshi; Igarashi, Yoshiaki; Tanoi, Keitaro (2014). "Biological proliferation of cesium-137 through the detrital food chain in a forest ecosystem in Japan". Scientific Reports. 4: 3599. Bibcode:2014NatSR...4E3599M. doi:10.1038/srep03599. ISSN 2045-2322. PMC 3884222. PMID 24398571.
  20. Kumamoto, Yuichiro; et al. (2017). "Radiation and analytical chemistry – Five years since the Fukushima Daiichi nuclear power plant accident". Special Articles. Bunseki Kagaku (in Japanese and English). 66 (3): 137–148. doi:10.2116/bunsekikagaku.66.137.
  21. Normile, Dennis (1 March 2013). "Cooling a hot zone". Science. 339 (6123): 1028–1029. Bibcode:2013Sci...339.1028N. doi:10.1126/science.339.6123.1028. PMID 23449572.
  22. Takeshi Okumura (21 October 2003). "The material flow of radioactive cesium-137 in the U.S. 2000" (PDF). epa.gov/. US Environmental Protection Agency.
  23. Peter Hellman; Mitch Frank (1 April 2010). "News Analysis: Christie's Is Counterfeit Crusader's Biggest Target". Wine Spectator. Retrieved 5 November 2013.
  24. The Radiological Accident in Goiânia (PDF). IAEA. 1988. ISBN 92-0-129088-8.
  25. "Vítima do césio-137 lembra depressão e preconceito após acidente". BBC Brasil. 26 April 2011.
  26. "Radioactive Scrap Metal". Nuclear Free Local Authorities. October 2000. Archived from the original on 21 March 2007.
  27. Lluma, Diego (May–June 2000). "Former Soviet Union: What the Russians left behind". Bulletin of the Atomic Scientists. 56 (3): 14–17. doi:10.2968/056003005.
  28. J.M. LaForge (1999). "Radioactive Caesium Spill Cooks Europe". Earth Island Journal. 14 (1). Archived from the original on 5 September 2008. Retrieved 28 March 2009.
  29. "Chinese 'find' radioactive ball". BBC News. 27 March 2009.
  30. "UiT har mistet radioaktivt stoff – kan ha blitt kastet". iTromsø. 4 November 2015.
  31. "Stort metallskap sporløst forsvunnet. Inneholder radioaktive stoffer". Dagbladet. 4 November 2015.
  32. "Cesium 137 now traced back to the property's garage and parts of its basement premises - Tiedote-en - STUK". www.stuk.fi. Retrieved 10 March 2016.
  33. Hannele Aaltonen. "Cesium-137 contamination at STUK's premises in March 2016" (PDF). IAEA. Retrieved 13 October 2018.
  34. Casey Martin (3 May 2019). "13 exposed to radioactivity". KUOW.

Bibliography
  • Olsen, Rolf A. (1994). "4.2. The Transfer of Radiocaesium from Soil to Plants and Fungi in Seminatural Ecosystems". Nordic Radioecology - the Transfer of Radionuclides through Nordic Ecosystems to Man. Studies in Environmental Science. 62. pp. 265–286. doi:10.1016/S0166-1116(08)71715-1. ISBN 9780444816177.
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