Burn rate (chemistry)

In chemistry, the burn rate (or burning rate) is a measure of the linear combustion rate of a compound or substance such as a candle or a solid propellant. It is measured in length over time, such as "mm/second" or "inches/second". Among the variables affecting burn rate are pressure and temperature. Burn rate is an important parameter especially in the area of propellants because it determines the rate at which exhaust gases are generated from the burning propellant which in turn decides the rate of flow through the nozzle. The thrust generated in the rocket of missile depends on this rate of flow. Thus Knowing quantitatively the burning rate of a propellant, and how it changes under various conditions, is of fundamental importance in the successful design of a solid rocket motor.[1] The concept of Burning rate is also relevant in case of liquid propellants.[2]

Measurement

One device for measuring burning rate is a V shaped metal channel about 1–2 feet long wherein a sample is placed, with a cross-sectional dimension of approximately 6 mm or 1/4". The sample is ignited on one end and time is measured until the flame front gets to the other end. Burn rate (typically expressed in 'mm/s' or 'in/s') is the sample length over time at a given pressure and temperature. For solid fuel propellant, the most common method of measuring burn rate is the Crawford Type Strand Burning Rate Bomb System[3] (also known as the Crawford Burner or Strand Burner), as described in MIL-STD-286C.[4]

Characterisation

A substance is characterised through burn rate vs pressure chart and burn rate vs temperature chart.

  • Higher burn rate than the speed of sound in the material (usually several km/s): "detonation"
  • A few meters per second: "deflagration"
  • A few centimeters per second: "burn" or "smoulder"
  • 0.01 mm/s to 100 mm/s: "decomposing rapidly" to characterise it.

However, there is difference in opinion in differentiating the three in absence of firm numbers at given pressure or temperature.

References
  1. "Rocket Propulsion". www.braeuing.us. Retrieved 20 September 2015.
  2. Wang, Shiqing; Thynell, Stefan (January 1, 2012). Decomposition and Combustion of Ionic Liquid Compound Synthesized from N,N,N′,N′-Tetramethylethylenediamine and Nitric Acid. ACS Symposium Series. 1117. p. 51–66. doi:10.1021/bk-2012-1117. ISBN 978-0-8412-2763-7.
  3. http://www.ditusa.com/strand_burner.php Crawford Burner System (Strand Burner) for Testing Burn Rate
  4. http://www.everyspec.com/MIL-STD/MIL-STD-0100-0299/MIL-STD-286C_8618/
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