Vinyl bromide
Vinyl bromide is a simple vinyl halide. It is a colorless liquid. It is produced from ethylene dibromide. It is mainly used as a comonomer to confer fire retardant properties to acrylate polymers.[2]
Names | |
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Preferred IUPAC name
Bromoethene | |
Other names
Vinyl bromide 1-Bromoethene Bromoethylene 1-Bromoethylene Monobromoethene Monobromoethylene | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.008.911 |
EC Number |
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KEGG | |
PubChem CID |
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RTECS number |
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UNII | |
CompTox Dashboard (EPA) |
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Properties | |
C2H3Br | |
Molar mass | 106.95 g/mol |
Appearance | Colorless gas |
Odor | pleasant[1] |
Density | 1.525 g/cm3 at boiling point (liquid)
1.4933 g/cm3 at 20 °C |
Melting point | −137.8 °C (−216.0 °F; 135.3 K) |
Boiling point | 15.8 °C (60.4 °F; 288.9 K) |
Insoluble | |
log P | 1.57 |
Vapor pressure | 206.8 kPa at 37.8 °C |
Hazards | |
Main hazards | Toxic (T), Highly flammable (F+) |
Safety data sheet | See: data page |
R-phrases (outdated) | R12, R20/21/22, R36/37/38, R45 |
S-phrases (outdated) | S45, S53 |
NFPA 704 (fire diamond) | |
Flash point | 5 °C (41 °F; 278 K) |
530 °C (986 °F; 803 K) | |
Explosive limits | 9%-15%[1] |
NIOSH (US health exposure limits): | |
PEL (Permissible) |
none[1] |
REL (Recommended) |
Ca[1] |
IDLH (Immediate danger) |
N.D.[1] |
Supplementary data page | |
Refractive index (n), Dielectric constant (εr), etc. | |
Thermodynamic data |
Phase behaviour solid–liquid–gas |
UV, IR, NMR, MS | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Reactions and applications
It reacts with magnesium to give the corresponding Grignard reagent.[3]
Safety precautions
Vinyl bromide is listed in List of IARC Group 2A carcinogens as a suspected human carcinogen.
gollark: The incident report system does actually work, by the way. All incidents are logged in SPUDNET. The only ones I know of are the test ones I triggered to test the system and various incident triggers. Incidents are reported when:- one known sandbox escape is detected- banned programs (Webicity) are executed- potatOS is uninstalled- invalid disk signing key
gollark: You can't make a program to fully autonomously uninstall potatOS from within it - ignoring sandbox escapes - because while sandboxed processes can use queueEvent to fake keypresses they cannot read the output of the uninstaller. The best they can do is, I don't know, guess what the random seed was when it was generating two primes, figure out what the primes were, and queue the key/char events accordingly.
gollark: <@184468521042968577> `is_valid_lua` isn't deliberately bad, but it's also IIRC not actually used anywhere.Also, that person was bundling potatOS with some other project but wanted people to be able to remove it even more easily if they don't like it. This feature does actually work but must be enabled before installation. Weirdly enough factorizing small semiprimes is beyond many users.
gollark: You could say that.
gollark: Disclaimer:```We are not responsible for- headaches- rashes- persistent/non-persistent coughs- scalp psoriasis- seborrhoeic dermatitis- virii/viros/virorum/viriis- backdoors- lack of backdoors- actually writing documentation- this project's horrible code- spinal cord sclerosis- hypertension- cardiac arrest- regular arrest, by police or whatever- angry mobs with or without pitchforks- fourteenth plane politics- Nvidia's Linux drivers- death- catsplosions- unicorn instability- the Problem of Evil- computronic discombobulation- loss of data- gain of data- frogsor any other issue caused directly or indirectly due to use of this product.```
See also
References
- NIOSH Pocket Guide to Chemical Hazards. "#0657". National Institute for Occupational Safety and Health (NIOSH).
- Dagani, M. J.; Barda, H. J.; Benya, T. J.; Sanders, D. C. "Bromine Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a04_405.
- Dietmar Seyferth (1959). "Di-n-butyldivinyltin". Org. Synth. 39: 10. doi:10.15227/orgsyn.039.0010.
External links
- International Chemical Safety Card 0597
- NIOSH Pocket Guide to Chemical Hazards. "#0657". National Institute for Occupational Safety and Health (NIOSH).
- MSDS at Oxford University
- MSDS at mathesontrigas.com
- Vinyl bromide at IRIS
- Vinyl bromide at osha.gov
- IARC Summary & Evaluation of vinyl bromide
- Report on Carcinogens Background Document for Vinyl Bromide
- Synthesis of vinyl bromides
- The Kinetics of Pyrolysis of Vinyl Bromide
- UV absorption spectra
- UV Spectrum and Cross Sections
- 1H NMR spectrum
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