In my experience, detach/attach is the fastest method. The bottleneck would probably be how quickly you could copy the files across the network.
Assuming the two databases have identical Windows accounts (if you're using SQL accounts you may have to update SIDs), you could probably use something like this script that I have laying around from before I started rewriting everything in PowerShell. :) It's intended to be run on the source server, and uses a file with a list of databases to move.
@ECHO ON
set newipmdf=\\newserver\g$
set newipldf=\\newserver\e$
set controlfile=control.txt
set oldserver=oldserver\instance
set oldmdfpath=d:\instance
set newmdfpath=g:\instance
set copymdfpath="m:\instance"
set newserver=newserver\instance
set oldlogpath=e:\instance
set newlogpath=e:\instance
set copylogpath="l:\instance"
set movedmdfpath=%oldmdfpath%\moved
set movedldfpath=%oldlogpath%\moved
mkdir %movedmdfpath%
mkdir %movedldfpath%
net use m: %newipmdf%
net use l: %newipldf%
SETLOCAL DISABLEDELAYEDEXPANSION
FOR /F %%L IN (%controlfile%%) DO (
SET "line=%%L"
SETLOCAL ENABLEDELAYEDEXPANSION
ECHO !line!
sqlcmd -E -S!oldserver! -Q"EXEC master.dbo.sp_detach_db @dbname = N'!line!'"
copy "!oldmdfpath!\!line!.mdf" !copymdfpath!
copy "!oldlogpath!\!line!_log.ldf" !copylogpath!
sqlcmd -E -S!newserver! -Q"CREATE DATABASE [!line!] ON ( FILENAME = '!newmdfpath!\!line!.mdf' ),( FILENAME = N'!newlogpath!\!line!_log.ldf' ) FOR ATTACH"
move "!oldmdfpath!\!line!.mdf" !movedmdfpath!
move "!oldlogpath!\!line!_log.ldf" !movedldfpath!
ENDLOCAL
)
ENDLOCAL
net use m: /z
net use l: /z
If you can't be down long enough to copy your 140GB file across the network, I've had good luck with the copy database wizard. I would still use detach/attach if possible, though.
Good luck!