I assume you mean DNS round-robin. In that case the basic way I can think of is to just edit your /etc/hosts to point to whatever backend you want to try in a particular moment:
1.2.3.4 servername
You may have to restart your browser afterwards to make sure it isn't used a cached DNS answer.
Also you could add additional entries in your DNS like servername-001, -002, etc. and configure your backends to accept those names as a ServerAlias for the VirtualHost you're aiming for. Of course you could also just set the VirtualHost as default so it works using the IP and omit this last step, assuming your App doesn't assume it's running with a particular name.
Edit: This may be useful - it's a Firefox extension that lets you modify request headers. You could arguably modify Host
to visit the backends directly specifying a ServerName. I haven't tried it though.
https://addons.mozilla.org/en-us/firefox/addon/modify-headers/