trans,cis-2,6-Nonadienal
trans,cis-2,6-Nonadienal is an organic compound that is classified as a doubly unsaturated derivative of nonanal. The molecule consists of a α,β-unsaturated aldehyde with an isolated alkene group. The compound has attracted attention as the essence of cucumbers,[1][2] but it is also found in bread crust[3] and freshly cut watermelon.
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Names | |
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IUPAC name
(E,Z)-Nona-2,6-dienal | |
Other names
(E,Z)-2,6-Nonadienal Violet leaf aldehyde Cucumber aldehyde | |
Identifiers | |
3D model (JSmol) |
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ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.008.345 |
PubChem CID |
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UNII | |
CompTox Dashboard (EPA) |
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Properties | |
C9H14O | |
Molar mass | 138.210 g·mol−1 |
Appearance | Colorless oil |
Hazards | |
GHS pictograms | ![]() |
GHS Signal word | Warning |
GHS hazard statements |
H315, H317 |
P261, P264, P272, P280, P302+352, P321, P332+313, P333+313, P362, P363, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Biosynthesis
Isotopic labeling has indicated that nonadienal is formed from alpha-linolenic acid.[4] Such reactions are typically catalyzed by hydroperoxide lyases.
gollark: A thought: if rarity really were mostly userdefined, would other BSAs not also be roughly aeonrare?
gollark: Okay, sure.
gollark: I think it's reasonable to assume that encyclopaedia entries match up 1:1 to internal species.
gollark: Are they not internally alts or something?
gollark: Did TJ09 say that each nebula color is a different species?
See also
- 2-Nonenal - another potent odorant in cucumber
References
- Kula, Jozef; Sadowska, Halina (1993). "Unsaturated aliphatic C9-aldehydes as natural flavorants: (E,Z)-2,6-nonadienal". Perfumer & Flavorist. 18: 23–5.CS1 maint: uses authors parameter (link)
- Schieberle, P.; Ofner, S.; Grosch, W. (January 1990). "Evaluation of Potent Odorants in Cucumbers (Cucumis sativus) and Muskmelons (Cucumis melo) by Aroma Extract Dilution Analysis". Journal of Food Science. 55 (1): 193–195. doi:10.1111/j.1365-2621.1990.tb06050.x.
- Cho, In Hee; Peterson, Devin G. (2010). "Chemistry of Bread Aroma: A Review". Food Science and Biotechnology. 19: 575–582. doi:10.1007/s10068-013-0240-4.CS1 maint: uses authors parameter (link)
- Grosch, Werner; Schwarz, Jorg M. (May 1971). "Linoleic and linolenic acid as precursors of the cucumber flavor". Lipids. 6 (5): 351–352. doi:10.1007/BF02531828.
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