Tetrabenzylzirconium

Tetrabenzylzirconium
Identifiers
CAS Number	24356-01-2;
3D model (JSmol)	Interactive image;
ChemSpider	10254475;
PubChem CID	520121;
CompTox Dashboard (EPA)	DTXSID80334254 ;
	InChI InChI=1S/4C7H7.Zr/c41-7-5-3-2-4-6-7;/h42-6H,1H2;/q4*-1;+4 Key: QSLMQGXOMLSFAW-UHFFFAOYSA-N;
	SMILES [CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[Zr+4];
Properties
Chemical formula	C28H28Zr
Molar mass	455.756 g·mol−1
Appearance	yellow solid
Melting point	133–134 °C (271–273 °F; 406–407 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Tetrabenzylzirconium is an organozirconium compound with the formula Zr(CH₂C₆H₅)₄. The molecule features diamagnetic Zr(IV) bonded to four benzyl ligands. It is a yellow air- and photo-sensitive solid, which is soluble in hydrocarbon solvents. The compound is a precursor to catalysts for the polymerization of olefins.[1] [2]

Structure, synthesis, reactions

Structure of tetrabenzylzirconium as determined by X-ray crystallography, with H atoms omitted for clarity.[3]

X-ray crystallography demonstrates that the benzyl ligands are highly flexible: one polymorph features four η²-ligands, whereas another has two η¹- and two η²-benzyl ligands.[3]

The compound is prepared by combining benzylmagnesium chloride and zirconium tetrachloride in diethyl ether. It readily undergoes protonolysis, e.g. with hydrogen chloride:

Zr(CH₂C₆H₅)₄ + HCl → Zr(CH₂C₆H₅)₃Cl + CH₃C₆H₅

gollark: Oh, and there seems to be an issue storing preferences so Edge will ask you to set it up again on every login.

gollark: Even when you actually log in it's unusable for a while more because Windows spends a while using 100% CPU for no apparent reason. You can hear the NUCs VRRRRRRRRing as loudly as they can.

gollark: In the last few years, instead of the reasonably functional setup where people's stuff was stored on a big on-premise fileserver, someone clearly decided to cloud™, and now everyone's files are on OneDrive and login takes several minutes and often breaks randomly.

gollark: The policy on using computers which people are meant to sign forbids you from "creating, running, downloading or [some other verb] executable files (programs)".

gollark: One person in my class found out at some point that the security camera control thing was on the internal network with the default password set.

References

Tshuva, Edit Y.; Goldberg, Israel; Kol, Moshe (2000). "Isospecific Living Polymerization of 1-Hexene by a Readily Available Nonmetallocene C₂-Symmetrical Zirconium Catalyst". Journal of the American Chemical Society. 122 (43): 10706–10707. doi:10.1021/ja001219g.
Zucchini, U.; Albizzati, E.; Giannini, U. (1971). "Synthesis and Properties of Some Titanium and Zirconium Benzyl Derivatives". Journal of Organometallic Chemistry. 26: 357–372. doi:10.1016/S0022-328X(00)82618-2.
Rong, Yi; Al-Harbi, Ahmed; Parkin, Gerard (2012). "Highly Variable Zr–CH₂–Ph Bond Angles in Tetrabenzylzirconium: Analysis of Benzyl Ligand Coordination Modes". Organometallics. 31 (23): 8208–8217. doi:10.1021/om300820b.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.

[1] Tshuva, Edit Y.; Goldberg, Israel; Kol, Moshe (2000). "Isospecific Living Polymerization of 1-Hexene by a Readily Available Nonmetallocene C₂-Symmetrical Zirconium Catalyst". Journal of the American Chemical Society. 122 (43): 10706–10707. doi:10.1021/ja001219g.

[2] Zucchini, U.; Albizzati, E.; Giannini, U. (1971). "Synthesis and Properties of Some Titanium and Zirconium Benzyl Derivatives". Journal of Organometallic Chemistry. 26: 357–372. doi:10.1016/S0022-328X(00)82618-2.

[Parkin-3] Rong, Yi; Al-Harbi, Ahmed; Parkin, Gerard (2012). "Highly Variable Zr–CH₂–Ph Bond Angles in Tetrabenzylzirconium: Analysis of Benzyl Ligand Coordination Modes". Organometallics. 31 (23): 8208–8217. doi:10.1021/om300820b.