Rabi cycle

In physics, the Rabi cycle (or Rabi flop) is the cyclic behaviour of a two-level quantum system in the presence of an oscillatory driving field. A great variety of physical processes belonging to the areas of quantum computing, condensed matter, atomic and molecular physics, and nuclear and particle physics can be conveniently studied in terms of two-level quantum mechanical systems, and exhibit Rabi flopping when coupled to an oscillatory driving field. The effect is important in quantum optics, magnetic resonance and quantum computing, and is named after Isidor Isaac Rabi.

Rabi oscillations, showing the probability of a two-level system initially in to end up in at different detunings Δ.

A two-level system has two possible levels, and if they are not degenerate (i.e. not equal energy), the system can become "excited" when it absorbs a quantum of energy. When an atom (or some other two-level system) is illuminated by a coherent beam of photons, it will cyclically absorb photons and re-emit them by stimulated emission. One such cycle is called a Rabi cycle and the inverse of its duration the Rabi frequency of the photon beam. The effect can be modeled using the Jaynes–Cummings model and the Bloch vector formalism.

Mathematical treatment

A detailed mathematical description of the effect can be found on the page for the Rabi problem. For example, for a two-state atom (an atom in which an electron can either be in the excited or ground state) in an electromagnetic field with frequency tuned to the excitation energy, the probability of finding the atom in the excited state is found from the Bloch equations to be:

,

where is the Rabi frequency.

More generally, one can consider a system where the two levels under consideration are not energy eigenstates. Therefore, if the system is initialized in one of these levels, time evolution will make the population of each of the levels oscillate with some characteristic frequency, whose angular frequency[1] is also known as the Rabi frequency. The state of a two-state quantum system can be represented as vectors of a two-dimensional complex Hilbert space, which means every state vector is represented by good complex coordinates.

where and are the coordinates.[2]

If the vectors are normalized, and are related by . The basis vectors will be represented as and

All observable physical quantities associated with this systems are 2 2 Hermitian matrices, which means the Hamiltonian of the system is also a similar matrix.

How to prepare an oscillation experiment in a quantum system

One can construct an oscillation experiment through the following steps:[3]

  1. Prepare the system in a fixed state; for example,
  2. Let the state evolve freely, under a Hamiltonian H for time t
  3. Find the probability P(t), that the state is in

If is an eigenstate of H, P(t)=1 and there will be no oscillations. Also if the two states and are degenerate, every state including is an eigenstate of H. As a result, there will be no oscillations.

On the other hand, if H has no degenerate eigenstates, and the initial state is not an eigenstate, then there will be oscillations. The most general form of the Hamiltonian of a two-state system is given

here, and are real numbers. This matrix can be decomposed as,

The matrix is the 2 2 identity matrix and the matrices are the Pauli matrices. This decomposition simplifies the analysis of the system especially in the time-independent case where the values of and are constants. Consider the case of a spin-1/2 particle in a magnetic field . The interaction Hamiltonian for this system is

, ,

where is the magnitude of the particle's magnetic moment, is the Gyromagnetic ratio and is the vector of Pauli matrices. Here the eigenstates of Hamiltonian are eigenstates of , that is and , with corresponding eigenvalues of . The probability that a system in the state can be found in the arbitrary state is given by .

Let the system be prepared in state at time . Note that is an eigenstate of :

.

Here the Hamiltonian is time independent. Thus by solving the stationary Schrödinger equation, the state after time t is given by , with total energy of the system . So the state after time t is given by:

.

Now suppose the spin is measured in x-direction at time t. The probability of finding spin-up is given by:

where is a characteristic angular frequency given by , where it has been assumed that .[4] So in this case the probability of finding spin-up in x-direction is oscillatory in time when the system's spin is initially in the direction. Similarly, if we measure the spin in the -direction, the probability of measuring spin as of the system is . In the degenerate case where , the characteristic frequency is 0 and there is no oscillation.

Notice that if a system is in an eigenstate of a given Hamiltonian, the system remains in that state.

This is true even for time dependent Hamiltonians. Taking for example ; if the system's initial spin state is , then the probability that a measurement of the spin in the y-direction results in at time is .[5]

Derivation of Rabi formula in a nonperturbative procedure by means of the Pauli matrices

Consider a Hamiltonian of the form

The eigenvalues of this matrix are given by

and
,

where and , so we can take .

Now, eigenvectors for can be found from equation

.

So

.

Applying the normalization condition on the eigenvectors, . So

.

Let and . So .

So we get . That is . Taking arbitrary phase angle ,we can write . Similarly .

So the eigenvector for the eigenvalue is given by

.

As overall phase is immaterial, we can write

.

Similarly, the eigenvector for eigenenergy

is .

From these two equations, we can write

and .

Suppose the system starts in state at time ; that is,

.

After time t, the state evolves as

.

If system is in one of the eigenstates or , it will remain the same state. However, for a general initial state as shown above, the time evolution is non trivial.

The probability amplitude of finding the system at time t in the state is given by .

Now the probability that a system in the state will be found to be in the arbitrary state

is given by

This can be simplified to

.........(1).

This shows that there is a finite probability of finding the system in state when the system is originally in the state . The probability is oscillatory with angular frequency , which is simply unique Bohr frequency of the system and also called Rabi frequency. The formula(1) is known as Rabi formula. Now after time t the probability that the system in state is given by, which is also oscillatory.

These types of oscillations of two-level systems are called Rabi oscillations, which arise in many problems such as Neutrino oscillation, the ionized Hydrogen molecule, Quantum computing, Ammonia maser etc.

Rabi oscillation in quantum computing

Any two-state quantum system can be used to model a qubit. Consider a spin- system with magnetic moment placed in a classical magnetic field . Let be the gyromagnetic ratio for the system. The magnetic moment is thus . The Hamiltonian of this system is then given by where and . One can find the eigenvalues and eigenvectors of this Hamiltonian by the above-mentioned procedure. Now, let the qubit be in state at time . Then, at time , the probability of it being found in state is given by where . This phenomenon is called Rabi oscillation. Thus, the qubit oscillates between the and states. The maximum amplitude for oscillation is achieved at , which is the condition for resonance. At resonance, the transition probability is given by . To go from state to state it is sufficient to adjust the time during which the rotating field acts such that or . This is called a pulse. If a time intermediate between 0 and is chosen, we obtain a superposition of and . In particular for , we have a pulse, which acts as: . This operation has crucial importance in quantum computing. The equations are essentially identical in the case of a two level atom in the field of a laser when the generally well satisfied rotating wave approximation is made. Then is the energy difference between the two atomic levels, is the frequency of laser wave and Rabi frequency is proportional to the product of the transition electric dipole moment of atom and electric field of the laser wave that is . In summary, Rabi oscillations are the basic process used to manipulate qubits. These oscillations are obtained by exposing qubits to periodic electric or magnetic fields during suitably adjusted time intervals.[6]

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See also

References

  1. Encyclopedia of Laser Physics and Technology - Rabi oscillations, Rabi frequency, stimulated emission
  2. Griffiths, David (2005). Introduction to Quantum Mechanics (2nd ed.). p. 341.
  3. Sourendu Gupta (27 August 2013). "The physics of 2-state systems" (PDF). Tata Institute of Fundamental Research.
  4. Griffiths, David (2012). Introduction to Quantum Mechanics (2nd ed.) p. 191.
  5. Griffiths, David (2012). Introduction to Quantum Mechanics (2nd ed.) p. 196 ISBN 978-8177582307
  6. A Short Introduction to Quantum Information and Quantum Computation by Michel Le Bellac, ISBN 978-0521860567
  • Quantum Mechanics Volume 1 by C. Cohen-Tannoudji, Bernard Diu, Frank Laloe, ISBN 9780471164333
  • A Short Introduction to Quantum Information and Quantum Computation by Michel Le Bellac, ISBN 978-0521860567
  • The Feynman Lectures on Physics Vol 3 by Richard P. Feynman & R.B. Leighton, ISBN 978-8185015842
  • Modern Approach To Quantum Mechanics by John S Townsend, ISBN 9788130913148
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