Plexciton

Plexcitons are polaritonic modes[1][2] that result from coherently coupled plasmons and excitons.[1] Plexcitons aid direct energy flows in exciton energy transfer (EET). Plexcitons travel for 20 μm, similar to the width of a human hair.[3]

History

Plasmons are a quantity of collective electron oscillations. Excitons are excited electrons bound to the hole produced by their excitation.[3]

Molecular crystal excitons were combined with the collective excitations within metals to create plexcitons. This allowed EET to reach distances of around 20,000 nanometers, an enormous increase over the some 10 nanometers possible previously. However, the transfer direction was uncontrolled.[3]

Topological insulators (TI) act as insulators below their surface, but have conductive surfaces, constraining electrons to move only along that surface. Even materials with moderately flawed surfaces do not impede current flow.[3] Topological plexcitons make use of the properties of TIs to achieve similar control over the direction of current flow.[3]

Plexcitons were found to emerge from an organic molecular layer (excitons) and a metallic film (plasmons). Dirac cones appeared in the plexcitons' two-dimensional band-structure. An external magnetic field created a gap between the cones when the system was interfaced to a magneto-optical layer. The resulting energy gap became populated with topologically protected one-way modes, which traveled only at the system interface.[2]

Potential applications

Plexcitons potentially offer an appealing platform for exploring exotic matter phases and for controlling nanoscale energy flows.[2]

gollark: Sadly, no, only OpenComputers can.
gollark: CC can only really send HTTP requests, do websockets, that sort of thing.
gollark: Technically, yes, with much work, but that wouldn't give it access to more I/O.
gollark: Sadly, it can't.
gollark: (It's running in an emulator because I can't be bothered to actually open the game)

References
  1. Fofang, Nche T.; Grady, Nathaniel K.; Fan, Zhiyuan; Govorov, Alexander O.; Halas, Naomi J. (2011-04-13). "Plexciton Dynamics: Exciton−Plasmon Coupling in a J-Aggregate−Au Nanoshell Complex Provides a Mechanism for Nonlinearity". Nano Letters. 11 (4): 1556–1560. Bibcode:2011NanoL..11.1556F. doi:10.1021/nl104352j. ISSN 1530-6984. PMID 21417362.
  2. Yuen-Zhou, Joel; Saikin, Semion K.; Zhu, Tony; Onbasli, Mehmet C.; Ross, Caroline A.; Bulovic, Vladimir; Baldo, Marc A. (2016-06-09). "Plexciton Dirac points and topological modes". Nature Communications. 7: 11783. arXiv:1509.03687. Bibcode:2016NatCo...711783Y. doi:10.1038/ncomms11783. ISSN 2041-1723. PMC 4906226. PMID 27278258.
  3. "Scientists design and build new energy-carrying particles". newatlas.com. Retrieved 2016-12-31.
  • Ozel, Tuncay; Hernandez-Martinez, Pedro Ludwig; Mutlugun, Evren; Akin, Onur; Nizamoglu, Sedat; Ozel, Ilkem Ozge; Zhang, Qing; Xiong, Qihua; Demir, Hilmi Volkan (2013-07-10). "Observation of Selective Plasmon-Exciton Coupling in Nonradiative Energy Transfer: Donor-Selective versus Acceptor-Selective Plexcitons". Nano Letters. 13 (7): 3065–3072. Bibcode:2013NanoL..13.3065O. doi:10.1021/nl4009106. hdl:11693/12141. ISSN 1530-6984. PMID 23755992.
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