Pio (surname)
Pio is the surname of:
- Angelo Piò (1690-1770), Italian sculptor
- Domenico Piò (1715-1801), Italian sculptor, son of Angelo Piò
- Emmanuel Pío (born 1988), Argentine footballer
- Louis Pio (1841–1894), one of the founders of the organized worker's movement in Denmark and principal founder of the Danish Social Democratic Party
- Teodoro Pio (died 1561), Italian Roman Catholic bishop
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