Enthalpy of neutralization

The enthalpy of neutralization (ΔHn) is the change in enthalpy that occurs when one equivalent of an acid and one equivalent of a base undergo a neutralization reaction to form water and a salt. It is a special case of the enthalpy of reaction. It is defined as the energy released with the formation of 1 mole of water.

When a reaction is carried out under standard conditions at the temperature of 298 K (25 degrees Celsius) and 1 atm of pressure and one mole of water is formed it is called the standard enthalpy of neutralization (ΔHn⊖).

The heat (Q) released during a reaction is

where m is the mass of the solution, cp is the specific heat capacity of the solution, and ∆T is the temperature change observed during the reaction. From this, the standard enthalpy change (∆H) is obtained by division with the amount of substance (in moles) involved.

When a strong acid, HA, reacts with a strong base, BOH, the reaction that occurs is

as the acid and the base are fully dissociated and neither the cation B+ nor the anion A− are involved in the neutralization reaction.[1] The enthalpy change for this reaction is -57.62 kJ/mol at 25 °C.

For weak acids or bases, the heat of neutralization is pH dependent.[1] In the absence of any added mineral acid or alkali some heat is required for complete dissociation. The total heat evolved during neutralization will be smaller.

e.g. at 25°C

The heat of ionization for this reaction is equal to (–12 + 57.3) = 45.3 kJ/mol at 25 °C.[2]

References
  1. Clark, Jim (July 2013). "Enthalpy Change of Neutralization". chemguide.co.uk. Retrieved 4 September 2019.
  2. "Enthalpy of Neutralization" (PDF). Community College of Rhode Island. Archived from the original (PDF) on 13 December 2016. Retrieved 24 February 2014.
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