Einstein–Brillouin–Keller method

The Einstein–Brillouin–Keller method (EBK) is a semiclassical method (named after Albert Einstein, Léon Brillouin, and Joseph B. Keller) used to compute eigenvalues in quantum-mechanical systems. EBK quantization is an improvement from Bohr-Sommerfeld quantization which did not consider the caustic phase jumps at classical turning points.[1] This procedure is able to reproduce exactly the spectrum of the 3D harmonic oscillator, particle in a box, and even the relativistic fine structure of the hydrogen atom.[2]

In 1976–1977, Berry and Tabor derived an extension to Gutzwiller trace formula for the density of states of an integrable system starting from EBK quantization.[3][4]

There have been a number of recent results on computational issues related to this topic, for example, the work of Eric J. Heller and Emmanuel David Tannenbaum using a partial differential equation gradient descent approach.[5]

Procedure

Given a separable classical system defined by coordinates ${\displaystyle (q_{i},p_{i});i\in \{1,2,\cdots ,d\}}$, in which every pair ${\displaystyle (q_{i},p_{i})}$ describes a closed function or a periodic function in ${\displaystyle q_{i}}$, the EBK procedure involves quantizing the path integrals of ${\displaystyle p_{i}}$ over the closed orbit of ${\displaystyle q_{i}}$:

${\displaystyle I_{i}={\frac {1}{2\pi }}\oint p_{i}dq_{i}=\hbar \left(n_{i}+{\frac {\mu _{i}}{4}}+{\frac {b_{i}}{2}}\right)}$

where ${\displaystyle I_{i}}$ is the action-angle coordinate, ${\displaystyle n_{i}}$ is a positive integer, and ${\displaystyle \mu _{i}}$ and ${\displaystyle b_{i}}$ are Maslov indexes. ${\displaystyle \mu _{i}}$ corresponds to the number of classical turning points in the trajectory of ${\displaystyle q_{i}}$ (Dirichlet boundary condition), and ${\displaystyle b_{i}}$ corresponds to the number of reflections with a hard wall (Neumann boundary condition).[6]

Example: 2D hydrogen atom

The Hamiltonian for a non-relativistic electron (electric charge ${\displaystyle e}$) in a hydrogen atom is:

${\displaystyle H={\frac {p_{r}^{2}}{2m}}+{\frac {p_{\varphi }^{2}}{2mr^{2}}}-{\frac {e^{2}}{4\pi \epsilon _{0}r}}}$

where ${\displaystyle p_{r}}$ is the canonical momentum to the radial distance ${\displaystyle r}$, and ${\displaystyle p_{\varphi }}$ is the canonical momentum of the azimuthal angle ${\displaystyle \varphi }$. Take the action-angle coordinates:

${\displaystyle I_{\varphi }={\text{constant}}=L}$

For the radial coordinate ${\displaystyle r}$:

${\displaystyle p_{r}={\sqrt {2mE-{\frac {L^{2}}{r^{2}}}-{\frac {e^{2}}{4\pi \epsilon _{0}r}}}}}$

${\displaystyle I_{r}={\frac {1}{\pi }}\int _{r_{1}}^{r_{2}}p_{r}dr={\frac {me^{2}}{4\pi \epsilon _{0}{\sqrt {-2mE}}}}-|L|}$

where we are integrating between the two classical turning points ${\displaystyle r_{1},r_{2}}$ (${\displaystyle \mu _{r}=2}$)

${\displaystyle E=-{\frac {me^{4}}{32\pi ^{2}\epsilon _{0}^{2}(I_{r}+L)^{2}}}}$

Using EBK quantization ${\displaystyle b_{r}=\mu _{\varphi }=b_{\varphi }=0,n_{\varphi }=m}$ :

${\displaystyle L=\hbar m\quad$ ;\quad m=0,1,2,\cdots }

${\displaystyle I_{r}=\hbar (n_{r}+1/2)\quad$ ;\quad n_{r}=0,1,2,\cdots }

${\displaystyle E=-{\frac {me^{4}}{32\pi ^{2}\epsilon _{0}^{2}\hbar ^{2}(n_{r}+m+1/2)^{2}}}}$

and by making ${\displaystyle n=n_{r}+m+1}$ the spectrum of the 2D hydrogen atom [7] is recovered :

${\displaystyle E_{n}=-{\frac {me^{4}}{32\pi ^{2}\epsilon _{0}^{2}\hbar ^{2}(n-1/2)^{2}}}\quad$ ;\quad n=1,2,3,\cdots }

Note that for this case ${\displaystyle L}$ almost coincides with the usual quantization of the angular momentum operator on the plane ${\displaystyle L_{z}}$. For the 3D case, the EBK method for the total angular momentum is equivalent to the Langer correction.

See also

• Hamilton–Jacobi equation
• WKB approximation
• Quantum chaos

References

1. Stone, A.D. (August 2005). "Einstein's unknown insight and the problem of quantizing chaos" (PDF). Physics Today. 58 (8): 37–43. Bibcode:2005PhT....58h..37S. doi:10.1063/1.2062917.
2. Curtis, L.G.; Ellis, D.G. (2004). "Use of the Einstein–Brillouin–Keller action quantization". American Journal of Physics. 72: 1521–1523. Bibcode:2004AmJPh..72.1521C. doi:10.1119/1.1768554.
3. Berry, M.V.; Tabor, M. (1976). "Closed orbits and the regular bound spectrum". Proceedings of the Royal Society A. 349: 101–123. Bibcode:1976RSPSA.349..101B. doi:10.1098/rspa.1976.0062.
4. Berry, M.V.; Tabor, M. (1977). "Calculating the bound spectrum by path summation in action-angle variables". Journal of Physics A. 10.
5. Tannenbaum, E.D.; Heller, E. (2001). "Semiclassical Quantization Using Invariant Tori: A Gradient-Descent Approach". Journal of Physical Chemistry A. 105: 2801–2813.
6. Brack, M.; Bhaduri, R.K. (1997). Semiclassical Physics. Adison-Weasly Publishing.
7. Basu, P.K. (1997). Theory of Optical Processes in Semiconductors: Bulk and Microstructures. Oxford University Press.