Dihydroquinine

Dihydroquinine, also known as hydroquinine,[1] is an organic compound and as a cinchona alkaloid closely related to quinine. The specific rotation is −148° in ethanol. A derivative of this molecule is used as chiral ligand in the AD-mix for Sharpless dihydroxylation.

Dihydroquinine
Names
IUPAC name
(R)-[(2S,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methanol
Other names
(8α,9R)-10,11-Dihydro-6'-methoxycinchonan-9-ol
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.578
UNII
Properties
C20H26N2O2
Molar mass 326.440 g·mol−1
Melting point 173–175 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

See also

References

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