Alan Brisdon

Alan K. Brisdon is a British chemist and a Senior Lecturer in the Department of Chemistry at The University of Manchester.[1] His research in general is based on fluorine chemistry, including on HCFCs, fluorine-containing organometallic systems, fluorophosphines and fluorine-containing materials, such as ionic liquids and fluorographenes.[2]

Alan Brisdon
Born	Alan K. Brisdon
Alma mater	University of Southampton[1] (BSc., PhD)
Known for	Fluorine Chemistry Inorganic Synthesis
Scientific career
Fields	Inorganic chemistry Organometallic chemistry
Institutions	The University of Manchester
Thesis	Matrix isolation infra-red and mass spectrometric studies of some arsenic and selenium oxides (1988)
Website	fluorine.ch.man.ac.uk

Education

Brisdon completed his Bachelor of Science at University of Southampton. Upon graduation, he continued to read for his Doctor of Philosophy degree on Matrix isolation infra-red and mass spectrometric studies of some arsenic and selenium oxides and successfully gained his PhD in 1988.[3]

Research and career

Upon completing his PhD, Brisdon worked for one year on a UKEA (Winfrith) funded project investigating on design, construction and testing of systems for sampling directly from a reaction chamber at or above atmospheric pressures and at high temperatures.[4] He then completed his postdoctoral research at University of Leicester where he worked on synthesis of high oxidation-state transition metal fluorides and oxide-fluorides via high pressure and liquid fluorine syntheses and on the fluorination of the fullerene's, C₆₀and C₇₀.[1][4] He then joined the University of Manchester as a Lecturer and was later on promoted to the position of Senior Lecturer.[4]

Brisdon's research in general is based on fluorine chemistry, including on HCFCs, fluorine-containing organometallic systems, fluorophosphines and fluorine-containing materials, such as ionic liquids and fluorographenes.[2][5]

Brisdon is the current Director of Teaching and Learning at Apart from research and lecturing in the Department of Chemistry at The University of Manchester.[1] He also is a highly regarded member[4] of the Fluorine Groups in the Royal Society of Chemistry[6] as well as the American Chemical Society[7] and is also part of the editorial board in the Journal of Fluorine Chemistry.[8]

Notable work

Brisdon is the author of Inorganic Spectroscopic Methods, a book which elaborates and discusses several spectroscopic techniques that can be used in inorganic chemistry,including vibrational spectroscopy, resonance spectroscopy, UV/Vis Spectroscopy and mass spectrometry.[9]

In 2014, Brisdon also participated in a research which showed how the use of 2,2,2-trifluoroethanol as solvent would be able to improve the efficiency of gold catalyzed A³-reactions.[10] The research also showed that the rate of the reaction can be accelerated by the use of a microwave reactor.

In 2001, Brisdon also reported on the synthesis of new fluorovinyl-containing organometallic complexes and fluorovinyl-containing phosphine ligands of the type R_nP(CX=CF₂)_3-n(n =1, 2; X = Cl, F) and their complexes.[11] The research showed how HFC-134a and HCFC-133a with two equivalents of butyllithium can form fluorovinyllithium reagents (CF₂=CFLi and CF₂=CClLi). These reagents were then used to synthesize these new novel fluorovinyl-containing transition metal and main-group compounds.

Major Publications

• Brisdon, Alan K.; Price, Gregory A.; Flower, Kevin R.; Pritchard, Robin G.; Quayle, Peter (2014). "Solvent effects in gold-catalysed A³-coupling reactions". Tetrahedron Letters. 55 (1): 151–154. doi:10.1016/j.tetlet.2013.10.141.
• Brisdon, Alan K.; Goudarziafshar, Hamid; Keypour, Hassan; Pritchard, Robin G.; Rezaeivala, Majid (2008). "New macrocyclic Schiff-base complexes incorporating a phenanthroline unit. Part 2: Template synthesis of some manganese^(II) complexes and crystal structure studies". Inorganica Chimica Acta. 361 (5): 1415–1420. doi:10.1016/j.ica.2007.09.018.
• Brisdon, Alan K.; Barnes, N.A.; Ellis, M.J.; Pritchard, R.G. (2001). "Recent advances in fluorovinyl-containing compounds". Journal of Fluorine Chemistry. 112 (1): 35–45. doi:10.1016/S0022-1139(01)00479-1.
• Brisdon, Alan K. (18 June 1998). Inorganic Spectroscopic Methods. United Kingdom: Oxford University Press. ISBN 9780198559498.
• Brisdon, Alan K.; Bishop, Peter; Brisdon, Brian J.; Marsh, Patsy; Mahon, Mary F. (1998). "X-Ray crystallographic and extended X-ray absorption fine structure studies of gold^(I) complexes containing weak intermolecular interactions". J. Chem. Soc., Dalton Trans. (4): 675–682. doi:10.1039/A707650I.

References

1. University of Manchester. "Dr Alan Brisdon". Retrieved 16 June 2020.
2. "Alan K. Brisdon (Publications)". Retrieved 16 June 2020.
3. Brisdon, Alan K. (1988). Matrix isolation infra-red and mass spectrometric studies of some arsenic and selenium oxides (PhD thesis). (subscription required)
4. "Brisdon, Alan". Retrieved 16 June 2020.
5. Sanderson, Katherine (11 July 2012). "Stinky rocks hide Earth's only haven for natural fluorine". Nature International Weekly Journal of Science. United Kingdom. Retrieved 18 June 2020.
6. Royal Society of Chemistry. "Fluorine Chemistry Group at Royal Society of Chemistry". Retrieved 16 June 2020.
7. American Chemical Society. "Division of Fluorine Chemistry". Retrieved 16 June 2020.
8. Journal of Fluorine Chemistry. "Journal of Fluorine Chemistry - Editorial Board". Retrieved 16 June 2020.
9. Brisdon, Alan K. (18 June 1998). Inorganic Spectroscopic Methods. United Kingdom: Oxford University Press. ISBN 9780198559498.
10. Brisdon, Alan K.; Price, Gregory A.; Flower, Kevin R.; Pritchard, Robin G.; Quayle, Peter (2014). "Solvent effects in gold-catalysed A³-coupling reactions". Tetrahedron Letters. 55 (1): 151–154. doi:10.1016/j.tetlet.2013.10.141.
11. Brisdon, Alan K.; Barnes, N.A.; Ellis, M.J.; Pritchard, R.G. (2001). "Recent advances in fluorovinyl-containing compounds". Journal of Fluorine Chemistry. 112 (1): 35–45. doi:10.1016/S0022-1139(01)00479-1.

External links

• at University of Manchester