Actinium(III) oxide
Actinium(III) oxide is a chemical compound containing the rare radioactive element actinium. It has the formula Ac2O3. It is similar to its corresponding lanthanum compound, lanthanum(III) oxide, and contains actinium in the oxidation state +3.[1][2] Actinium oxide is not to be confused with Ac2O (acetic anhydride), where Ac is an abbreviation for acetyl instead of the symbol of the element actinium.
Names | |
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IUPAC name
Actinium(III) oxide | |
Systematic IUPAC name
Actinium(3+) oxide | |
Other names
Actinium sesquioxide | |
Identifiers | |
3D model (JSmol) |
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ECHA InfoCard | 100.031.275 |
EC Number |
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PubChem CID |
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Properties | |
Ac2O3 | |
Molar mass | 502 g·mol−1 |
Appearance | white |
Density | 502.053 g/mol |
Structure | |
Trigonal, hP5 | |
P-3m1, No. 164 | |
Related compounds | |
Other cations |
Scandium(III) oxide Yttrium(III) oxide Lanthanum(III) oxide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Reactions
- Ac2O3 + 6HF → 2AcF3 + 3H2O
- Ac2O3 + 6HCl → 2AcCl3 + 3H2O
- 4Ac(NO3)3 → 2Ac2O3 + 12NO2 + 3O2
- 4Ac + 3O2 → 2Ac2O3
- Ac2O3 + 2AlBr3 → 2AcBr3 + Al2O3
- 2Ac(OH)3 → Ac2O3 + 3H2O
- Ac2(C2O4)3 → Ac2O3 + 3CO2 + 3CO
- Ac2O3 + 3H2S → Ac2S3 + 3H2O
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References
- Actinium, Great Soviet Encyclopedia (in Russian)
- Sherman, Fried; Hagemann, French; Zachariasen, W. H. (1950). "The Preparation and Identification of Some Pure Actinium Compounds". Journal of the American Chemical Society. 72 (2): 771–775. doi:10.1021/ja01158a034.
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