2,2'-Dipyridylamine

2,2'-Dipyridylamine
Names
	IUPAC name N-pyridin-2-ylpyridin-2-amine
	Other names 2,2'-iminodipyridine
Identifiers
CAS Number	1202-34-2;
3D model (JSmol)	Interactive image;
ChEMBL	ChEMBL1735909;
ChemSpider	13888;
ECHA InfoCard	100.013.513
EC Number	214-864-3;
PubChem CID	14547;
UNII	X9BF664YAK;
CompTox Dashboard (EPA)	DTXSID5061619;
	InChI InChI=1S/C10H9N3/c1-3-7-11-9(5-1)13-10-6-2-4-8-12-10/h1-8H,(H,11,12,13) Key: HMMPCBAWTWYFLR-UHFFFAOYSA-N;
	SMILES C1=CC=NC(=C1)NC2=CC=CC=N2;
Properties
Chemical formula	C10H9N3
Molar mass	171.203 g·mol−1
Appearance	white solid
Melting point	90.5 °C (194.9 °F; 363.6 K)
Boiling point	307.5 °C (585.5 °F; 580.6 K)
Hazards
GHS pictograms
GHS Signal word	Warning
GHS hazard statements	H315, H319, H335
GHS precautionary statements	P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

2,2'-Dipyridylamine is an organic compound with the formula (C₅H₄N)₂NH. It consists of a pair of 2-pyridyl groups (C₅H₄N) linked to a secondary amine. The compound forms a range of coordination complexes.[1] Its conjugate base, 2,2'-dipyridylamide, forms extended metal atom chains.[2]

Formation

2,2'-Dipyridylamine can be formed by heating pyridine with sodium amide. Alternatively, 2-aminopyridine can be heated with 2-chloropyridine over barium oxide.[3]

gollark: Oh, you should use `os.pullEvent` and not `coroutine.yield` too, right.

gollark: Your thing will be running in a CraftOS environment instead of the BIOS one, so presumably you can use the `keys` library and make it easier.

gollark: This is adapted slightly from the keyboard shortcuts daemon in potatOS.

gollark: ```lualocal keys_down = {}local keyboard_commands = { -- whatever}local function keyboard_shortcuts() while true do local ev = {coroutine.yield()} if ev[1] == "key" then keys_down[ev[2]] = true if keyboard_commands[ev[2]] and keys_down[157] then -- right ctrl keyboard_commands[ev[2]]() end elseif ev[1] == "key_up" then keys_down[ev[2]] = false end endend```

gollark: Oh, right. I'll pull up the PotatoBIOS code for that.

References

Wang, Suning (2001). "Luminescence and electroluminescence of Al(III), B(III), Be(II) and Zn(II) complexes with nitrogen donors". Coordination Chemistry Reviews. 215: 79–98. doi:10.1016/S0010-8545(00)00403-3.
Cotton, F. Albert; Daniels, Lee M.; Jordan; Murillo, Carlos A. (1997). "Symmetrical and Unsymmetrical Compounds Having a Linear Co₃⁶⁺ Chain Ligated by a Spiral Set of Dipyridyl Anions". Journal of the American Chemical Society. 119 (43): 10377–10381. doi:10.1021/JA971997H.
Brogden, David W.; Berry, John F. (4 September 2015). "Coordination Chemistry of 2,2'-Dipyridylamine: The Gift That Keeps on Giving". Comments on Inorganic Chemistry. 36 (1): 17–37. doi:10.1080/02603594.2015.1079522.

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[1] Wang, Suning (2001). "Luminescence and electroluminescence of Al(III), B(III), Be(II) and Zn(II) complexes with nitrogen donors". Coordination Chemistry Reviews. 215: 79–98. doi:10.1016/S0010-8545(00)00403-3.

[2] Cotton, F. Albert; Daniels, Lee M.; Jordan; Murillo, Carlos A. (1997). "Symmetrical and Unsymmetrical Compounds Having a Linear Co₃⁶⁺ Chain Ligated by a Spiral Set of Dipyridyl Anions". Journal of the American Chemical Society. 119 (43): 10377–10381. doi:10.1021/JA971997H.

[bro-3] Brogden, David W.; Berry, John F. (4 September 2015). "Coordination Chemistry of 2,2'-Dipyridylamine: The Gift That Keeps on Giving". Comments on Inorganic Chemistry. 36 (1): 17–37. doi:10.1080/02603594.2015.1079522.