1,3-Diphenyltriazene
1,3-Diphenyltriazene is the organic compound with the formula PhN=N-N(H)Ph (Ph = C6H5). It is a prototypical triazene, i.e. a compound with the functional group RN=N-NR2. It is a pale yellow solid, prepared by the reaction of phenyldiazonium salts with aniline.[1] It is a planar molecule. The N-N distances are 1.287 and 1.337 Å.[2]
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Other names
Diazoaminobenzene | |
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ChemSpider | |
ECHA InfoCard | 100.004.764 |
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Properties | |
C12H11N3 | |
Molar mass | 197.241 g·mol−1 |
Appearance | Pale yellow solid |
Density | 1.29 g/cm3 |
Melting point | 94–96 °C (201–205 °F; 367–369 K) |
Hazards | |
GHS pictograms | |
GHS Signal word | Warning |
GHS hazard statements |
H302, H312, H315, H319, H332, H335 |
P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P305+351+338, P312, P321, P322, P330, P332+313, P337+313, P362, P363, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
References
- Hartman, W. W.; Dickey, J. B. (1934). "Diazoaminobenzene". Organic Syntheses. 14: 24. doi:10.15227/orgsyn.014.0024.
- Lego, Christian; Neumüller, Bernhard (2011). "Reaktionen von 1,3-Diphenyltriazenid mit Cu+ und Tl+". Zeitschrift für anorganische und allgemeine Chemie. 637: 1784–1789. doi:10.1002/zaac.201100227.
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