To be absolutely safe:
- No, you shouldn't use chargers with different voltages at all and if you do, you will most likely void the warranty of either the laptop, the charger, or both. That also goes for the safety guidelines so if anything exploded in your face, YOU would be responsible. (Except maybe the charger manufacturer could be if they officially stated it's compatible with your model)
If you don't care about warranty and are ready to be responsible for your safety:
1. Voltage: 19.5V and 19V is a relatively small voltage difference. It is most probably safe to use as long as:
2. Current: As explained above, the current rating of the charger should be same or higher higher than that of the laptop. (To understand - Laptops draw current from the charger as needed. Chargers don't push current inside laptops. So if the laptop is fully charged, it takes ~0A from the charger even when connected.)
3. Size: The charger's connector needs to be exactly the same size as the old one (meaning that it needs to fit the laptop connector), otherwise it might either not fit at all, or if it does, you might break the laptop's inside connector and make it unusable even by original chargers.
4. Polarity: The polarity of the charger connector and the laptop connector (or the original charger connector) must be the same. It most probably is, the industry standard is "+" on the inside pin and "-" on the outside. But to be sure, check for polarity on both the charger and the laptop. There should be a picture similar to this - polarity image
possible duplicate of Can I safely charge my laptop with a non-standard, third-party charger?
– Ƭᴇcʜιᴇ007 – 2014-12-01T19:33:07.757You have to look at the bottom of the laptop for the input rating. The 19.5V vs 19V will not matter (it is a small enough difference); as long as the current rating on the charger is at least as much as the current rating printed on the laptop it will be fine. – Andrew Morton – 2014-12-01T20:01:08.343
The chargers are "generic"; the same model is used for various laptops even with the OEM chargers. The 19.5V is close enough to 19V, it won't make a difference. The 4.62A is slightly less than 4.74A, but 4.74A was likely more than the laptop actually required. If your laptop is heavily expanded and was drawing the limit on the old adapter, the replacement will get extremely hot. In that case, return it based on mislabeling that it could actually handle 4.74A. – fixer1234 – 2014-12-01T20:12:57.943