The GPO editor doesn't validate usernames because there are scenarios where it wouldn't be able to validate perfectly valid account names.
Observe that any such validation would take place on the machine where you are editing the policy and then consider the following scenario:
- You configure the
Computer/Preferences/Control Panel Settings/Local Users and Groups/Local Group
policy to add members to the Administrators (built-in)
group.
- The username you specify is a machine local user account that does not exist on the workstation where you're running Group Policy Editor, but does exist on the machines targeted by the policy.
In this case, a username validity check would fail, even though you specify valid account names. For this reason, the GP Editor cannot validate account names.