Yes, if you connect a drive to a computer, the domain admin will be able to see your files. The domain admin is trusted with access to anything the computer currently has access to. If you don't trust the computer administrator, don't trust the computer.
However, I find it unlikely the system administrator will be waiting for you to connect a drive so he can make a copy of all your personal files. As long as you unmount a TrueCrypt volume when you're not using it, you're probably reasonably safe. Once it's unmounted, someone could only access it again if they had your volume's password (perhaps there is a keylogger on the computer).
Why are you worried about this? Assuming this is a computer and network owned by a business you work for, I think the two most common reasons would be:
You do not trust your system administrator. This is a concern perhaps you want to address with management. Since the system administrator often can access nearly anything in the company, if you have reason to believe they are not trustworthy, management should know about it.
You are doing something clandestinely and are afraid of getting caught. You should be! If your workplace does not want you using their time and their resources for some activity, don't do it.
The only way to ensure the system administrator cannot access your files is to access them from a computer outside of his/her control. Perhaps bring a laptop with you and access the files from that machine.
so this is a valid concern? but is there a way that lets the current user only access the files but when the domain admin access the files it will be with domain/admin user so it will be a different user with no access to the saved password or this is not right? – Karim – 2010-10-03T19:51:15.873
2@Karim - An evil admin could have a keylogger installed as far as you know. Then whatever you type is accessible to him, that includes your passwords. You simply can not be 100% sure to keep your files private on a computer you don't have 100% control over. – Nifle – 2010-10-03T20:00:34.600
yeah but i am not talking extreme cases like a key logger, because having a keylogger maybe illegal in my opinion.but getting files from the company pc is not as far as know.of course cracking encrypted files of an employee is not legal too in my opinion. – Karim – 2010-10-03T20:07:15.603
2@Karim: "in my opinion" is not a very valid legal statement. – Hello71 – 2010-10-03T22:21:32.387
@Hello71: that is because i am not a lawyer, anyway i was asking about the technical aspect and not the legal one, because in each country laws are different so we can discuss this topic forever and besides the law aspect of this problem dont belong here, maybe on legaloverflow.com or something :) – Karim – 2010-10-03T22:37:45.103