JoeJablomy
February 13th, 2004, 03:06 AM
I couldn't find anything elsewhere on the synthesis of malodorants. Anyone who's read the patents referred to in the patents thread knows that alkyl mercaptans with some skatole carried in vegetable oil can apparently be used, and I did find this for at least the structure of skatole:
http://www.bris.ac.uk/Depts/Chemistry/MOTM/silly/sillymols.htm
(about 1/4 the way down)
I don't know about KOH and egg whites, and the site is fucking stupid, but hopefully the structure will be useful.
So, for those of you that do know something about chemistry, how would you go about making
n-butyl mercaptan
methyl mercaptan
skatole
putrescine
cadaverine
or, for that matter,
"a malodorant organic sulfur compound; organic nitrogen compound; organic phosphorus compound; substituted or unsubstituted C.sub.3 to C.sub.6 aliphatic or cycloaliphatic carboxylic acid, aldehyde or acid halide; aliphatic diyne; inorganic silane; allyl trifluoro acetate; cis-4-decanal; pentafluoropropionic anhydride; 6,6-dimethylfulvene; methyl 4-methylbenzoate; or a mixture of two or more of the foregoing."?
Ethyl and methyl mercaptans are supposedly the stuff they put in natural gas so it stinks, so they should be pretty cheap; really most of these at least in the first part of the list seem like pretty simple compounds. And I have to say, at least with my sense of humor, I'd bet this kind of chemical warfare, applied to the correct persons who are abandoning their duty to uphold the constitution...
http://www.bris.ac.uk/Depts/Chemistry/MOTM/silly/sillymols.htm
(about 1/4 the way down)
I don't know about KOH and egg whites, and the site is fucking stupid, but hopefully the structure will be useful.
So, for those of you that do know something about chemistry, how would you go about making
n-butyl mercaptan
methyl mercaptan
skatole
putrescine
cadaverine
or, for that matter,
"a malodorant organic sulfur compound; organic nitrogen compound; organic phosphorus compound; substituted or unsubstituted C.sub.3 to C.sub.6 aliphatic or cycloaliphatic carboxylic acid, aldehyde or acid halide; aliphatic diyne; inorganic silane; allyl trifluoro acetate; cis-4-decanal; pentafluoropropionic anhydride; 6,6-dimethylfulvene; methyl 4-methylbenzoate; or a mixture of two or more of the foregoing."?
Ethyl and methyl mercaptans are supposedly the stuff they put in natural gas so it stinks, so they should be pretty cheap; really most of these at least in the first part of the list seem like pretty simple compounds. And I have to say, at least with my sense of humor, I'd bet this kind of chemical warfare, applied to the correct persons who are abandoning their duty to uphold the constitution...